HAp, Zeolite에 여러 금속 Ion 치환시 나타나는 항균효과

김윤종,김택남,김상배,조성백,조건준,이태형,Kim, Yun-Jong,Kim, Taek-Nam,Kim, Sang-Bae,Jo, Seong-Baek,Jo, Geon-Jun,Lee, Tae-Hyeong 한국재료학회 2001 한국재료학회지 Vol.11 No.2

흡착재료에는 hydroxyapatite(HAp), zeolite,, 분자체탄소, 활성탄, 알루미나등의 재료가 많이 사용되고 있다. 이들 흡착재료 중에서 금속이온과 양이온 교환반응이 좋은 HAp, zeolite는 폐수처리과정에서 많이 사용되고 있지만, 피러나 이 폐수처리과정에서 문제되는 것은 유해한 중금속뿐만 아니라 많은 세균들이 이 폐수에 존재하고 있어 수질오염 등의 여러 가지 문제를 야기 시키고 있다. 본 연구는 여러 중금속 흡착재료 중에서 HAp, zeolite에 항균효과가 있다고 알려진 금속이온 (Ag$^{+}$, Cu$^{2+}$, $Zn^{2+}$)들을 이온 치환시켜 항균성을 흡착재료에 부여하고자 한다. HAp, zeolite에 Ag$^{+}$, Cu$^{2+}$, $Zn^{2+}$의 금속이온들을 치환시킨 후, E. Coli로 항균효과를 측정하였다. HAp, zeolite와 여러 금속이온 치환후의 항균효과를 측정한 결과, Ag$^{+}$ 로 이온치환 시킨 HAp, zeolite에서는 1$\times$$10^{-2}$cell/ml 농도의 E. Coli에서 24시간가지 완벽한 항균효과를 보였고, Cu$^{2+}$와 $Zn^{2+}$으로 이온치환 시킨 경우에서는 좋은 항균효과를 보이지 않았다. 이러한 결과는 Feng. et. al.이 발표한 바와 같이1) Ag ion이 cell내부의 DNA에 영향을 기척, 복제능력을 떨어뜨리고 Cell을 비활성화 시키기 때문이다. Generally, hydroxyapatite(HAp), zeolite, carbon molecular sieve , activated carbon and alumina are used as heavy metal ions adsorption materials. Among those adsorption materials, HAp which has good positive ion-exchange ability with metal ion, and zeolite are utilized in wastewater treatment. Most of water pollutions are caused by hazardous heavy metals ions as well as bacteria in waste water. In this study, a adsorption materials (HAP and zeolite) are ion-exchanged with a well known antimicrobial metal ions, such as $Ag^+,\;Cu^{2+},\;and\;Zn^{2+}$, in order to give a adsorption of heavy metal ions and a killing effects of bacteria. The antimicrobial effects of adsorption materials are observed using by E. Coli. The results show that there is a complete antimicrobial effect in the adsorption materials with $Ag^+$ at the concentration of $1{\times}10^{-4}$cell/$m\ell$ of E. Coli until 24 hours. However, there is not good antimicrobial effects in the adsorption materials with $Cu^{2+},\;and\;Zn^{2+}$ substitution. Feng et. al. showed the denaturation effects of silver ions which induces the condensed DNA molecules and losing their replication abilities.

공기 분급한 국내 천연 제올라이트의 수열처리에 관한 연구

김윤종,김택남,김일용,최영준,이승우,Kim, Yun-Jong,Kim, Taek-Nam,Kim, Il-Yong,Choe, Yeong-Jun,Lee, Seung-U 배재대학교 공학연구소 2004 공학논문집 Vol.5 No.1

국내 천연 제올라이트에 포함된 feldspar와 illite의 불순광물을 공기 분급 조작 의하여 정제하였다. 공기 분급된 제올라이트를 XRD로 분석한 결과 공기분급에 의하여 제올라이트와 불순광물을 분리할 수 있었고, 공기 분급을 함으로서 불순광물이 감소된 것을 알 수 있었다. 또한, 공기 분급된 천연 제올라이트를 1N NaOH용액으로 100, 150, $200^{\circ}C$에서 17시간동안 수열처리한 결과 mordenite와 clinoptiolite에서 phillilsite와 analcime의 상변화를 얻을 수 있었다. Korean natural zeolite with feldspar and illite as impurities was purified by an air classification method. X-ray powder diffraction analyses showed that the air classification effectively separated zeolite and impurities, and reduce the amount of impurity of the natural zeolite. The zeolite with air classification was treated with 1N NaOH solutions at temperatures at 100, 150, $200^{\circ}C$ for 17hours. The obtained hydrothermal treatment of phase change to phillilsite and analcime from mordenite and clinoptilolite.

서비스 수요조사와 분류모형을 이용한 수요예측

김윤종,김용철,Kim, Youn-Jong,Kim, Yong-Chul 한국통계학회 2008 응용통계연구 Vol.21 No.1

수요예측은 모든 생산적 활동을 수립하기 위한 기반이 되기 때문에 수요가 어느 정도 발생할 것인가에 대한 방향성에 대하여 파악하려고 일반적으로 설문조사를 이용하지만 무응답 및 불성실한 응답으로 인하여 설문응답 자료만으로 수요를 예측하기에는 부족하다. 따라서 수요와 관련 있는 변수를 이용한 분류모형으로 설문조사의 수요예측을 보정하고자 하였다. 본 논문에서는 설문조사를 통하여 평가 할 수 있는 직접적인 수요와 통계적 모형을 이용한 간접적 수요를 혼합하여 서비스 수요를 예측하는 혼합 모형을 제시하고자 한다. In generally, we use a method of the survey to forecast the economic demands and non-economic demands for a market trend. But we have a difficult problem to estimate the demand for the marketplace objectively because the survey with the non-response and the inadequate understanding on questionnaires did not provided the strong and uniform forecast. Here, we proposed a method compounded of survey and a statistical model to estimate the demand for the marketplace and discussed the mixture model applied to the service demand on an agency.

Cp-Ti 표면의 Hydroxyapatite+TiO₂ 복합 Sol 코팅에 관한 연구

김윤종,김택남,이성호,Kim, Yun-Jong,Kim, Taik-Nam,Lee, Sung-Ho 한국재료학회 2005 한국재료학회지 Vol.15 No.7

In this study, $Hydroxyapatite+TiO_2(HAp+TiO_2)$ composite sol coatings on Cp-Ti substrates were deposited by using a sol-gel derived precursor. Prior to hydroxyapatite coating, the samples were micropolished and divided into three sets. The first set was coated with hydroxyapatite (HAp) directly on Cp-Ti. The second set was first coated with intermediate titania layer and then coated with HAp. The third set samples were coated with $HAp+TiO_2$ (50:50) composite sol. Each samples were predried at $200^{\circ}C$, and heat treated at $600^{\circ}C$. The formation of hydroxyapatite has been confirmed by XRD analyses and the substrate material was found to be oxidized with negligible amount of CaO in the coating. The NaOH treated samples showed the presence of rutile crystal. The SEM studies revealed surface morphologies of each samples. $HAp+TiO_2$ composite sol coating layer was found to be smooth. The bonding strength of each samples were calculated using pull out tests. The bonding strength of the $HAp+TiO_2$ composite sol coating on substrate was 29.35MPa.

도시지역 지하 공간의 침수위험도 평가와 대책 -지하철역사를 대상으로-

김윤종,이창희,여창건,Kim, Yun-Jong,Lee, Chang-Hui,Yeo, Chang-Geon 한국수자원학회 2008 물과 미래(한국수자원학회지) Vol.41 No.3

IGRT를 위한 비침습적인 호흡에 의한 장기 움직임 실시간 추적시스템

김윤종,윤의중,Kim, Yoon-Jong,Yoon, Uei-Joong 대한의용생체공학회 2007 의공학회지 Vol.28 No.5

A non-invasive respiratory gated radiotherapy system like those based on external anatomic motion gives better comfortableness to patients than invasive system on treatment. However, higher correlation between the external and internal anatomic motion is required to increase the effectiveness of non-invasive respiratory gated radiotherapy. Both of invasive and non-invasive methods need to track the internal anatomy with the higher precision and rapid response. Especially, the non-invasive method has more difficulty to track the target position successively because of using only image processing. So we developed the system to track the motion for a non-invasive respiratory gated system to accurately find the dynamic position of internal structures such as the diaphragm and tumor. The respiratory organ motion tracking apparatus consists of an image capture board, a fluoroscopy system and a processing computer. After the image board grabs the motion of internal anatomy through the fluoroscopy system, the computer acquires the organ motion tracking data by image processing without any additional physical markers. The patients breathe freely without any forced breath control and coaching, when this experiment was performed. The developed pattern-recognition software could extract the target motion signal in real-time from the acquired fluoroscopic images. The range of mean deviations between the real and acquired target positions was measured for some sample structures in an anatomical model phantom. The mean and max deviation between the real and acquired positions were less than 1mm and 2mm respectively with the standardized movement using a moving stage and an anatomical model phantom. Under the real human body, the mean and maximum distance of the peak to trough was measured 23.5mm and 55.1mm respectively for 13 patients' diaphragm motion. The acquired respiration profile showed that human expiration period was longer than the inspiration period. The above results could be applied to respiratory-gated radiotherapy.

일라이트에 함유된 Fe 불순물 제거

김윤종,조성백,박현혜,김상배,Kim, Yun-Jong,Cho, Sung-Baek,Park, Hyun-Hae,Kim, Sang-Bae 한국재료학회 2006 한국재료학회지 Vol.16 No.8

Recently, many attention have been focused on illite as a material for the well-being industry. Illite contains various kinds of iron bearing materials and they restrict their usage. In this study, Fe impurities in the illite produced in Yeongdong-gun, Chungcheongbuk-do were characterized and their removal experiments were performed. According to the characterization of illite raw ore, it contained 1.54 wt.%$Fe_2O_3$ due to the existence of iron oxide($Fe_2O_3$) and pyrite($FeS_2$). The raw ore was crushed into 3 mm or less using cone crusher and then ground by rod mill for the liberation of impurity mineral. For the removal of iron bearing minerals, an acid treatment, a flotation, a magnetic separation, and a flotation combined with magnetic separator were performed respectively. When the illite raw ore was treated with magnetic separation and various kinds of acid, 1.54wt.%. $Fe_2O_3$ content was reduced to 0.78 and 1.0 wt.%, respectively. On the other hand $Fe_2O_3$ content was reduced to be 0.52 wt.% after flotation. These results indicate that iron bearing minerals cannot be reduced below 0.3wt.%$Fe_2O_3$. However, combination of magnetic separation and flotation enable us to get 0.24wt.% of illite concentrate. It is concluded that, for the refinement of illite from Yeongdong-gun, the flotation combined with magnetic separation is good for high purity illite.

고객 만족도 조사를 이용한 경영성과 측정 연구-과학기술 콘텐트 웹 사이트를 중심으로

김윤종,Kim, Yun-Jong 한국과학기술정보연구원 2003 지식정보인프라 Vol.12 No.-

정보에 대한 정량적 평가방법으로 조건부 가치평가방법을 응용하여 정량화 하였다. 조건부 가치평가 법은 간단히 말해 직접적으로 사람들에게 비시장 재화에 대해 어느 정도 지불의사가 있는가를 설문지를 통해 사용자들에게 직접 묻는 것이다. 기존의 가치평가 법은 해당 정보 재화와 유사한 재화의 시장수요를 추정하여 평가하는 간접적 가치 평가법이 널리 사용되어 왔다. 그러나 정보는 유사한 재화의 명확한 정의가 곤란하므로 이러한 요인들을 고려하여 설문조사를 통한 정보의 가치평가 방법을 선택하여 정보제공 웹 사이트의 경영성과를 측정하였다.

Effect of Disagglomeration on the Recovery of Abrasives from Waste Sludge

김윤종,Sang-Bae Kim,Hyun-Hye Park,조성백 한국자원공학회 2007 Geosystem engineering Vol.10 No.3

Effect of disagglomeration with different type of mill on recovery of abrasives was investigated. To evaluate an effect of disagglomeration on recovery of abrasive from waste sludge, disagglomerated waste sludge by different mills were air classified and yield of fine particles product were calculated. The results suggested that pin mill and jet mill are effective for disagglomeration of waste sludge. Pumice, garnet and rouge powders were easily recovered by air classification after disagglomeration by pin mill for the recycling of them as a abrasive powders in polishing procedure of CRT glass. Comparing to raw abrasive powders, shapes and mineralogical properties were very similar to those of new ones. These results suggest that the recycled abrasive powders can be used as an abrasive powders.

논문 : 제올라이트의 수열처리에 관한 연구

김윤종 ( Yun Jong Kim ),김택남 ( Taik Nam Kim ),김일용 ( Ill Yong Kim ),최영준 ( Young Jun Kim ),이승우 ( Seung Wo Lee ) 대한지구물리학회 2001 지구물리 Vol.4 No.4