반암(맥반석)으로 제조한 다공성 펠렛의 Ag 담지 및 항균 메디아로서의 적용

한요셉,김현중,신영섭,박재구,고재철,Han, Yo-Sep,Kim, Hyun-Jung,Shin, Young-Seop,Park, Jai-Koo,Ko, Jae-Churl 한국세라믹학회 2009 한국세라믹학회지 Vol.46 No.1

The porous pellets were prepared from porphyry by slurry foaming method. The effect of sintering temperatures on pore structure of porous porphyry pellets with different extension ratio ($E_R$) was investigated by specific surface area, water absorption and porosity, which changed with sintering temperatures. When the sintering temperatures increased from $975^{\circ}C$ to $1075^{\circ}C$, specific surface area and water absorption of the all samples decreased. In case of the sample with an equal sintering temperature, $E_R=3.0$ pellets had little influence on pore structure compared to the $E_R=2.0$ pellets. As a results, it was shown by SEM that facilitated formation of micro pores at $E_R=2.0$ pellets shrunk increasingly after sintering process. At $E_R=3.0$ and sintering temperature at $1025^{\circ}C$, optimum conditions of the porous porphyry porous pellets was found. Also, Escherichia coli removal efficiency of the silver-containing porphoyry porous pellets was measured for the feasibility as a antibacterial media. The antibacterial activity of prepared silver-containing sample was maintained above 90% for 40 days.

Scaling Up Fabrication of UO2 Porous Pellet With a Simulated Spent Fuel Composition

전상채,이재원,윤주영,조용준 한국방사성폐기물학회 2017 방사성폐기물학회지 Vol.15 No.4

Processing and equipment were tailored for engineering scale fabrication of UO2 porous pellets, a feed material for the electrolytic reduction process in the PRIDE (PyRoprocessing Integrated DEmonstration) facility at KAERI (Korea Atomic Energy Research Institute). The starting materials, UO2 powder and pre-milled surrogate oxide powders, were proportioned to simulate the chemical composition of spent fuel (so-called Simfuel). The Simfuel powders were homogenized by mixing, compacted into a pellet shape, and finally heat treated using a tumbling mixer, rotary press, and sintering furnace. After sintering at 1450℃ for 24 h in 4% H2-Ar, the average bulk density of the UO2 Simfuel pellets was 6.89 g·cm-3, which meets the standard of the following electrolytic reduction process. In addition, the results of a microstructural analysis demonstrated that the sintered Simfuel UO2 porous pellets accurately simulate the properties of spent fuel in terms of the formation of second phases. These results provide essential information for the massive fabrication of UO2 porous pellets for engineering scale pyroprocessing research.

Scaling Up Fabrication of UO2 Porous Pellet With a Simulated Spent Fuel Composition

Sang-Chae Jeon,Jae-Won Lee,Joo-Young Yoon,Yung-Zun Cho 한국방사성폐기물학회 2017 방사성폐기물학회지 Vol.15 No.4

KAERI의 PRIDE 시설에서 공학규모의 전해환원용 원료물질인 UO2 다공성펠렛 제조를 위해 공정과 장치를 최적화시킨 내 용을 다루었다. UO2 분말과 별도로 attrition 밀링된 대용산화물 분말을 출발분말로, 정밀 칭량을 통해 사용후핵연료 조성을 모사하였다(Simfuel). Simfuel 분말은 각각 tumbling mixer로 혼합하여 균질화 하고, rotary press로 성형하여 furnace를 이 용해 소결하였다. 4% H2-Ar 분위기에서 1450℃ 24시간 고온 열처리하여 제조된 소결펠렛은 6.89 g·cm-3의 벌크밀도를 가 지며 이는 후속 전해환원 공정의 요구에 부합한다. 소결된 다공성펠렛의 미세구조 관찰을 통해 다공성 기지상과 함께 산화/ 금속 석출물이 관찰되어 사용후핵연료의 상이 모사됨을 확인하였다. 본 결과는 향후 공학규모 이상의 파이로 연구를 위한 UO2 다공성펠렛 제조에 중요한 기초자료로 활용 될 것이다. Processing and equipment were tailored for engineering scale fabrication of UO2 porous pellets, a feed material for the electrolytic reduction process in the PRIDE (PyRoprocessing Integrated DEmonstration) facility at KAERI (Korea Atomic Energy Research Institute). The starting materials, UO2 powder and pre-milled surrogate oxide powders, were proportioned to simulate the chemical composition of spent fuel (so-called Simfuel). The Simfuel powders were homogenized by mixing, compacted into a pellet shape, and finally heat treated using a tumbling mixer, rotary press, and sintering furnace. After sintering at 1450℃ for 24 h in 4% H2-Ar, the average bulk density of the UO2 Simfuel pellets was 6.89 g·cm-3, which meets the standard of the following electrolytic reduction process. In addition, the results of a microstructural analysis demonstrated that the sintered Simfuel UO2 porous pellets accurately simulate the properties of spent fuel in terms of the formation of second phases. These results provide essential information for the massive fabrication of UO2 porous pellets for engineering scale pyroprocessing research.

Fabrication of cylindrical-type porous pellets and their gas removal property

이지호,김세희,이학송,한양수 한국공업화학회 2016 한국공업화학회 연구논문 초록집 Vol.2016 No.0

The cylindrical-type porous pellets of copper-manganese oxide mixed with light-weight inorganic fillers were prepared by extrusion method and the gas removal activity depending on the various process variables was systematically compared. In addition, the mechanical properties including pellet hardness, density, and physical properties such as porosity, surface area, etc, were also investigated. It was found that the newly prepared oxide catalyst-loaded pellet type granules exhibited excellent mechanical and physico-chemical properties; high pellet hardness(>4.0 kg/㎠), very low apparent density (<0.7 g/㎤), large pore volume (>1.0 ㎤/g) and specific surface area (>500 ㎡/g), respectively. Furthermore they showed excellent CO removal activity at room temperature.

모의 사용후핵연료 조성의 UO2 다공성펠렛 제조 스케일 업

전상채,이재원,윤주영,조용준 한국방사성폐기물학회 2017 방사성폐기물학회지 Vol.15 No.4

KAERI의 PRIDE 시설에서 공학규모의 전해환원용 원료물질인 UO2 다공성펠렛 제조를 위해 공정과 장치를 최적화시킨 내 용을 다루었다. UO2 분말과 별도로 attrition 밀링된 대용산화물 분말을 출발분말로, 정밀 칭량을 통해 사용후핵연료 조성을 모사하였다(Simfuel). Simfuel 분말은 각각 tumbling mixer로 혼합하여 균질화 하고, rotary press로 성형하여 furnace를 이 용해 소결하였다. 4% H2-Ar 분위기에서 1450℃ 24시간 고온 열처리하여 제조된 소결펠렛은 6.89 g·cm-3의 벌크밀도를 가 지며 이는 후속 전해환원 공정의 요구에 부합한다. 소결된 다공성펠렛의 미세구조 관찰을 통해 다공성 기지상과 함께 산화/ 금속 석출물이 관찰되어 사용후핵연료의 상이 모사됨을 확인하였다. 본 결과는 향후 공학규모 이상의 파이로 연구를 위한 UO2 다공성펠렛 제조에 중요한 기초자료로 활용 될 것이다. Processing and equipment were tailored for engineering scale fabrication of UO2 porous pellets, a feed material for the electrolytic reduction process in the PRIDE (PyRoprocessing Integrated DEmonstration) facility at KAERI (Korea Atomic Energy Research Institute). The starting materials, UO2 powder and pre-milled surrogate oxide powders, were proportioned to simulate the chemical composition of spent fuel (so-called Simfuel). The Simfuel powders were homogenized by mixing, compacted into a pellet shape, and finally heat treated using a tumbling mixer, rotary press, and sintering furnace. After sintering at 1450℃ for 24 h in 4% H2-Ar, the average bulk density of the UO2 Simfuel pellets was 6.89 g·cm-3, which meets the standard of the following electrolytic reduction process. In addition, the results of a microstructural analysis demonstrated that the sintered Simfuel UO2 porous pellets accurately simulate the properties of spent fuel in terms of the formation of second phases. These results provide essential information for the massive fabrication of UO2 porous pellets for engineering scale pyroprocessing research.

다공성 철 분말을 이용한 열전지용 열원 적합성 연구

김지연,윤현기,임채남,조장현 한국전기전자재료학회 2022 전기전자재료학회논문지 Vol.35 No.4

Thermal batteries are specialized as primary reserve batteries that operate when the internal heat source is ignited and the produced heat (450~550oC) melts the initially insulating salt into highly conductive eutectic electrolyte. The heat source is composed of Fe powder and KClO4 with different mass ratios and is inserted in-between the cells (stacks) to allow homogeneous heat transfer and ensure complete melting of the electrolyte. An ideal heat source has following criteria to satisfy: sufficient mechanical durability for stacking, appropriate heat calories, ease of combustion by an igniter, stable combustion rate, and modest peak temperature. To satisfy the aforementioned requirements, Fe powder must have high surface area and porosity to increase the reaction rate. Herein, the hydrothermal and spray drying synthesis techniques for Fe powder samples are employed to investigate the physicochemical properties of Fe powder samples and their applicability as a heat source constituent. The direct comparison with the state-of-the-art Fe powder is made to confirm the validity of synthesized products. Finally, the actual batteries were made with the synthesized iron powder samples to examine their performances during the battery operation.

Analysis of Catalytic Reaction Systems under Microwaves to Save Energy

Yeo, Yeong-Koo,Kim, Hee-Young,Kim, In-Woo,Moon, Il,Chung, Yonsoo,Levdansky, V.V. 한국화학공학회 2003 Korean Journal of Chemical Engineering Vol.20 No.1

Effects of microwaves on catalytic reaction systems are analyzed theoretically in this work. Use of microwaves is encouraged to save energy. The effects of microwave heating are analyzed theoretically by assuming that the catalyst pellet is homogeneous. The temperature and concentration profiles within the catalyst pellet were obtained by numerical simulations for the cases of microwave heating and conventional heating. In the modeling the catalyst pellet is regarded as a continuum. When a chemical reaction was conducted in a heterogeneous medium with microwave heating, the reaction rate and the yield were found to be increased compared to conventional heating under the same reaction conditions. This is due to hot spots generated by selective heating of the catalyst pellet, resulting in an increased reaction rate.

다공성 펠렛을 포집재로 사용하는 매연여과장치의 배압 및 재생 특성에 관한 연구

金鎭玄,柳鍾植,文學勳,車京玉 明知大學校 産業技術硏究所 2006 産業技術硏究所論文集 Vol.25 No.-

Diesel particulate trap is a core technology for the reduction of PM from diesel vehicles. This study presents the features and the characteristics of DPF system when using pellet type filters. In comparison with wall-flow filter, the pellet filter has the advantages of cracking free during regeneration and shape flexibility. Experiments are conducted in a test bench simulated as diesel engine exhaust condition. Pressure drop and particle loading rate was compared by using two pellet filters having the porosity of 70% and 0%. Also its regeneration was tested.

니페디핀을 포함한 삼투성펠렛의 제조와 다공성막을 통한 약물방출제어

윤주용(Ju Yong Youn),구정(Jeong Ku),김병수(Byung Soo Kim),김문석(Moon Suk Kim),이봉(Bong Lee),강길선(Gil Son Khang),이해방(Hai Bang Lee) 한국고분자학회 2008 폴리머 Vol.32 No.4