논문 : 금속성 응집제와 모노클로라민의 상호작용이 Polyamide계 RO막 성능에 미치는 영향

김경화 ( Kyung Hwa Kim ),홍승관 ( Seung Kwan Hong ),박찬혁 ( Chan Hyuk Park ),윤성로 ( Seong Ro Yoon ),홍성표 ( Seong Pyuo Hong ),이종화 ( Jong Hwa Lee ) 대한상하수도학회 2006 상하수도학회지 Vol.20 No.4

The bench-scale chlorine exposure study was performed to investigate the effect of pretreatment by free chlorine and monochloramine (NH2Cl) on the performance of RO membranes made of polyamide (PA). Feed monochloramination at 2㎎/L did not cause significant productivity loss compared to free chlorine. However, metal coagulants reacted with monochloramine, the PA membrane suffered from a gradual loss of membrane integrity by chlorine oxidation, which was characterized as a decrease in salt rejection. Especially, RO membranes exposed to alum coagulants with monochloramine revealed the salt rejection lower than those exposed to iron coagulants. XPS membrane surface analysis demonstrated that the chlorine uptake on the membrane surface increased and carbon peaks were shifted significantly when exposed to alum coagulants with monochloramine.

Combined Chlorite-Monochloramine Application for Controlling Nitrifying and Heterotrophic Bacteria in Drinking Water Distribution System

박세근,김영관,최성찬,Park, Se-Keun,Kim, Yeong-Kwan,Choi, Sung-Chan The Microbiological Society of Korea 2013 미생물학회지 Vol.49 No.4

In the present work, the reactors that harbor bacterial biofilms including ammonia-oxidizing bacteria (AOB) and heterotrophic bacteria were treated with a continuous dose of chlorite ($0.66{\pm}0.01mg/L$) either with or without monochloramine at $1.77{\pm}0.03mg/L$. Both chlorite alone and combined chlorite-monochloramine applications effectively reduced biofilm and bulk AOB levels to near or below the detection limit ($0.6MPN/cm^2$ and 0.2 MPN/ml). The combined chlorite-monochloramine application exhibited greater AOB inactivation than chlorite alone. Unlike AOB, heterotrophic plate count (HPC) was unaffected by chlorite alone. In contrast to chlorite-only application, a combination of chlorite and monochloramine resulted in a significant reduction in HPC levels with log reductions of 3.1 and 3.0 for biofilm and bulk water, respectively. The results demonstrate that the combined chlorite-monochloramine application can provide an effective treatment for the inhibition of AOB and heterotrophic bacteria in a drinking water distribution system. 본 연구에서는 암모니아 산화세균과 종속영양세균을 포함한 세균 생물막에 대한 chlorite ($0.66{\pm}0.01mg/L$)의 영향을 monochloramine ($1.77{\pm}0.03mg/L$)의 존재 유무에 따른 조건에서 알아보았다. Chlorite 단독 또는 monochloramine과 함께 적용한 경우에서 공히 생물막과 물 시료에 존재하는 암모니아 산화세균은 검출한계($0.6MPN/cm^2$ and 0.2 MPN/ml)에 근접한 수준으로 감소되는 것으로 나타났지만, chlorite/monochloramine으로 함께 첨가했을 때의 저해효과가 더욱 크게 나타났다. 종속영양세균의 경우 암모니아 산화세균과 달리 chlorite에 의한 저해가 거의 나타나지 않았다. 하지만 chlorite/monochloramine으로 적용한 경우 생물막과 물 시료에서 종속영양세균의 개체 수는 대조군 대비 각각 3.1 log와 3.0 log 감소하는 상당한 저해 효과를 보여주었다. 이러한 결과는 상수관망에 형성된 생물막에 존재하는 질산화 세균과 종속영양세균에 대한 효과적 제어방법중의 하나로 chlorite와 monochloramine 혼합사용의 성공적 가능성을 제시해 준다.

천연유기물과 모노클로라민의 반응시 유기성 클로라민 생성

이원태(Won Tae Lee) 大韓環境工學會 2014 대한환경공학회지 Vol.36 No.9

천연유기물질(NOM)과 모노클로라민이 반응할 때 NOM내 용존유기질소(DON)가 유기성 클로라민의 생성에 미치는 영향에 대하여 조사하였다. 실험에 사용된 16가지 NOM의 용존유기탄소(DOC)에 대한 DON의 비(DOC/DON)는 7~47 mg-C/mg-N이었다. NOM 용액의 모노클로라민 반응시 유기성 클로라민 생성 농도는 24시간 후에 최대치(평균값 0.16 mg-Cl₂/mg-N)로 염소반응에 비하여 유기성 클로라민의 생성량은 적었으나, 분해되어 감소되는 속도는 낮아 반응 120시간 후에 최대치 대비 평균 56% 감소되었다. NOM내 DON의 함유비가 높은 경우(DOC/DON 비가 낮은 경우)에 유기성 클로라민의 생성량이 상대적으로 높게 나타났으나, 소수성, 친수성, 중간성, 콜로이드성 등 NOM의 특성에 따른 유기성 클로라민 생성량의 차이는 크지 않았다. 모노클로라민의 주입량을 증가시킬수록 유기성 클로라민 생성량이 선형적으로 증가하였고(R2 = 0.91), 주입된 모노클로라민 중 6%가 유기성 클로라민으로 전환되어 모노클로라민 소독시 유기성 클로라민 형성에 의한 소독능 저하는 크게 우려할 바는 아닐 수 있다. This study investigated influence of dissolved organic nitrogen (DON) in natural organic matter (NOM) on the formation of organic chloramines upon monochloramination. Ratios of dissolved organic carbon (DOC) to DON of the 16 NOM isolates ranged from 7 to 47 mg-C/mg-N. Levels of organic chloramines maxed in 24 hours at 0.16 mg-Cl₂/mg-N in average. The yields were relatively lower, but decay of organic chloramines were slower than those upon chlorination. Organic chloramines formed upon monochloramination decreased by 56% in average in 120 h. NOM with lower DOC/DON ratios formed more organic chloramines. NOM fractions such as hydrophobic, hydrophilic, transphilic, and colloidal did not significantly impact formation of organic chloramines. As the monochloramine doses increased, more organic chloramines were produced (R2 = 0.91). Overestimation of disinfection capacity due to the formation of organic chloramines may not be concerns for monochloramine systems since only 6% of monochloramine could be converted to organic chloramines upon monochloramination of NOM.

유리잔류염소와 모노클로라민에서의 생물막의 CLPP

이동근,Lee Dong-Geun 한국환경보건학회 2005 한국환경보건학회지 Vol.31 No.2

The disinfection effect of free residual chlorine and monochloramine on biofilm communities were investigated by CLPP (community level physiology profile) using Biolog GN plates. Low concentration of disinfectant, $0.5\;mg/\iota$ free chlorine and $1.0\;mg/\iota$ monochloramine, stimulated the growth of bacteria rather than disinfection. Bacterial concentrations were decreased at more than $1.0\;mg/\iota$ of disinfectants. CLPP was different with the type and concentration of disinfectant and sampling time. Common and different carbon sources were actively used with similar bacterial concentration in free chlorine and monochloramine. This represents the differences of bacterial communities with tap water contact times and disinfectant.

소독제에 따른 생물막 살균효율과 생물막 미생물집단의 탄소이용능 비교

이동근,이재화,이상현,하배진,하종명,Lee, Dong-Geun,Lee, Jae-Hwa,Lee, Sang-Hyeon,Ha, Bae-Jin,Ha, Jong-Myung 한국생명과학회 2006 생명과학회지 Vol.16 No.4

수돗물에서 생성된 탄소강관위의 생물막에 유리잔류염소와 모노클로라민을 처리하여 세균농도 변화와 그에 따른 탄소원 이용능을 조사하였다. 소독제 농도를 단계적으로 올렸을 때 종속영양세균의 농도는 모노클로라민과 유리잔류염소의 농도가 각 1.5, 1.0 mg/l까지는 대조구에 비해 감소가 없었지만 (P = 0.56, ANOVA) 모노클로라민 2.0 mg/l, 유리잔류염소 1.5 mg/l 일때 감소되었다 (P < 0.01, ANOVA). 소독제의 농도를 단계적으로 높일때 세균활성의 증가 후 감소 그리고 세균농도의 감소가 관찰되었다. 세균농도가 유사하더라도 각 탄소원에 대한 정량적, 정성적 이용도가 서로 달라 군집구조가 상이할 것으로 생각되었다. The influence of disinfectant on bacterial concentration and carbon usage patterns by Biolog GN plates were investigated for biofilm on carbon steel pipe. Heterotrophic bacterial concentrations were not different among non-, monochloramine- (1.0, 1.5 mg/l) and free chlorine- (0.5, 1.0 mg/l) treated samples (P = 0.56, ANOVA). However treatment of 1.5 mg/l free chlorine and 2.0 mg/l monochloraime showed significantly lower densities than control (P < 0.01, ANOVA). By the stepwise increasement of disinfectant concentration, the carbon usage activities of biofilm microflora were decreased after increase without the decrease of bacterial concentration, following reduction of cell density. Carbon usage patterns were qualitatively and quantitatively different with similar bacterial concentrations. Principal component analysis suggested that type and concentration of disinfectant were main factors on the usage of carbons. Our result suggest that the differences of bacterial communities were different among the samples and the need of monochloramine for the reduction of biofilm in drinking water.

소독제별 생물막 형성 저해효율과 탄소이용능 비교

이동근 신라대학교 자연과학연구소 2007 自然科學論文集 Vol.16 No.-

생물막이 없는 탄소강관이 유리잔류염소와 모노클로라민의 농도를 단계적으로 높인 수돗물속에 노출되었을 때 일어나는 세균농도 변화와 그에 따른 탄소원 이용능을 조사하였다. 유리잔류염소의 농도를 0.5 mg/l로 처리한 후에 1.0, 1.5 mg/1로 단계적으로 올렸을 때 종속영양세균의 농도는 큰 변화가 없었고 탄소원 이용능은 전반적으로 감소한 후에 증가하였다. 모노클로라민의 1.0 mg/1로 처리한 후에 1.5, 2.0 mg/1로 단계적으로 올렸을 때 종속영앙세균의 농도와 탄소원 이용능 모두 감소 후 큰변화가 없었다. 생물막 형성 저해효과는 모노클로라민이 큰 것으로 나타났다. 세균농도가 유사하더라도 각탄소원에 대한 정량적, 정성적 이용도가 서로 달랐으며 이는 군집구조가 서로 달라서 나타난 결과로 판단하였다. To figure out the influence of disinfectant on bacterial concentration and carbon usage patterns during biofilm development, bacterial concentration and CLPP(community level physiology profile) of biofilm on carbon steel pipe were analyzed. Heterotrophic bacterial concentrations were lower in monochloramine treated samples than free chlorine treated ones. CLPP analysis patterns were different with the stepwise increasement of disinfectant concentration in free chlorine treated tap water. Activities of microflora were decreased and then increased in free chlorine treated samples, while monochloramine treated samples showed no increase after decrease. CLPP was different according to the type and concentration of disinfectant and actively used carbon sources were common and different meaning growth of different microbial population. These results indicate that the bacterial community is variable with the kinds of disinfectants and monochloramine is effective on the reduction of biofilm in drinking water.

pH 변화에 따른 클로라민 생성과 분해 특성

조관형,김평청,우달식,조영태 한국환경과학회 2002 한국환경과학회지 Vol.11 No.4

본 연구의 시료는 현재 서울특별시와 수도권 도시들에서 상수원수로 이용하고 있는 한강수를 대상으로 수행되었다. 배·급수계통의 2차 소독을 위한 클로라민소독의 특성에 관하여 고찰하였으며 그 결과는 다음과 같다. 1) 25 ℃, Cl_2 / NH_3-N비 1:1 ~ 14:1에서 pH6, 7, 8의 불연속점은 각각 Cl_2 / NH_3-N비 11:1, 9:1, 10:1이었다. pH6의 경우, Cl_2 / NH_3-N비가 9:1일 때 총 잔류염소량이 최대인 반면, pH7, 8의 경우 Cl_2 / NH_3-N비가 각각 6:1, 5:1일 때 최대가 되었다. 2) pH가 6, 7, 8로 증가함에 따라 모노클로라민이 최대로 생성되는 Cl_2 / NH_3-N비는 7:1에서 5:1로 이동하였으며, pH6 ~ 8 범위에서 pH가 증가함에 따라 모노클로라민의 생성량이 많았다. 3) 클로라민의 분해는 Cl_2 / NH_3-N비가 증가하고 pH가 낮을수록 증가하였다. 클로라민의 잔류성은 유리염소보다 월등히 좋았다. pH6에서 모노클로라민과 디클로라민이 생성된 이후, 접촉시간이 경과함에 따라 디클로라민의 분포비가 증가하였다. This study was conducted to investigate the characteristics of chloramination as a secondary disinfection in a drinking water distribution system. At the range from pH 6 to pH 8, monochloramine was predominant with a trace of dichloramine, and the free chlorine was detected after breakpoint. At 25℃, the breakpoints of pH 6, 7 and 8 appeared when the weight ratios of chlorine to ammonia nitrogen were 11:1, 9:1 and 10:1 respectively, and the peak points on the breakpoint curves at pH 6, 7 and 8 were in the Cl_2 / NH_3-N ratio of 9:1, 6:1 and 5:1 respectively. As pH increased from 6 to 8, maximum point of monochloramine on the breakpoint curve was moved from 7:1 to 5:1 in the weight ratio of chlorine to ammonia nitrogen. The maximum concentration of monochloramine was formed at the pH values of 7~8 and in the Cl_2 / NH_3-N ratio below 5:1. As the Cl_2 / NH_3-N ratio increased and the pH lowered, chloramines decay proceeded at an increased rate, and residual chloramines lasted longer than the residual free chlorine. The monochloramine and the dichloramine were formed at pH 6, and then the dichloramine continued increasing with contact lime.

환경인자가 N-NDMA 발생에 주는 영향

박상천 ( Sung Chun Park ),김종오 ( Jongo Kim ) 한국수처리학회 2016 한국수처리학회지 Vol.24 No.3

N-nitrosodimethylamine (NDMA) formation was broadly studied in terms of pH ratio, monochloramine concentrations, longer contact time, and the ratio of nitrogen content in dimethylamine (DMA) to total nitrogen composition as various environmental factors in water treatment system. The formation of NDMA increased with increasing pH and contact time. The NDMA formation at pH 8 was usually twice that at pH 7 at a DMA of 0.01 mM. At pH 7 and 8, generally more than nine times higher NDMA formation was observed with increasing monochloramine concentrations when the DMA concentration was changed from 0.01 mM to 0.05mM. It is likely that pH and monochloramine was more related to stimulate NDMA formation in water treatment systems.

모노클로라민과 디메틸아민 농도가 NDMA 생성에 미치는 영향

김종오(Jon Go Kim) 大韓環境工學會 2008 대한환경공학회지 Vol.30 No.8

다양한 항목에 따른 N-Nitrosodimethylamine(NDMA) 생성에 관한 비교

김종오(Jong O Kim) 大韓環境工學會 2007 대한환경공학회지 Vol.29 No.2