특허와 논문으로 본 PET 폐자원의 화학원료화 및 고부가 활용기술 동향

김태일,강경석,조영주,조봉규,Kim, Tae-Il,Kang, Kyung-Seok,Cho, Young-Ju,Cho, Bong-Gyoo 한국자원리싸이클링학회 2014 資源 리싸이클링 Vol.23 No.5

1990년대에 들어서면서 폐플라스틱을 화학적으로 재활용하여 환경문제나 경제적 문제를 해결해보려는 노력이 증대되었고, 이 추세에 따라 폐 PET를 화학적으로 재활용하여 원료화하려는 시도가 활발해졌다. 본 연구에서는 PET 폐자원의 화학원료화 및 고부가 활용기술에 대한 특허와 논문을 분석하였다. 분석범위는 1974년에서 2013년까지의 미국, 유럽연합, 일본, 한국의 등록/공개된 특허와 SCI 논문으로 제한하였다. 특허와 논문은 키워드를 사용하여 수집하였으며, 기술의 정의에 의해 필터링 하였다. 특허와 논문의 동향은 연도, 국가, 기업, 기술 등에 따라 분석하여 고찰하였다. Since 1990s, efforts to recycle the waste plastics by chemical methods have increased. And in accordance with this trend, attempts have become active to use the waste PET as raw materials of chemical industries. In this article, the patents and papers for development of commercial technology for feedstock recycling and high end products from PET wastes were collected and analyzed. The open patents of USA (US), European Union (EP), Japan (JP), and Korea (KR) and SCI journals from 1974 to 2013 were investigated. The patents and papers were collected using key-words and filtered by the definition of the technology. The patents and papers were analyzed by the years, countries, companies, and technologies and the technical trends were discussed in this paper.

한우의 반추위로부터 섬유소 분해균의 탐색 및 동정

김태일,백순용,주이석,윤용덕,Kim, Tae Il,Baik, Soon yong,Joo, Yi Seok,Yoon, Young Dhuk 한국미생물학회 1998 미생물학회지 Vol.34 No.3

Cellulase producing microorganisms, GPC-1, GPC-2, GNR-1 GNR-2, and GNR-3, were screened from the Rumen fluid of Korean Native Cattle. Isolated GPC-1 and GPC-2 were identified as Ruminococcus sp. according to results of the Gram stain and anaerobic characteristics. Based on morphological and physicochemical identification, the isolate GPC-1 and GPC-2 were identified as strains of Ruminococcus albus and Ruminococcus flavefaciens, respectively. Isolated GNR-1 GNR-2 and GNR-3 were identified as Bacteroides sp., Butyrivibrio sp. and Clostridium sp. according to results of the Gram stain, $H_2S$ producition and spore formation, respectively. Based on morphological and physicochemical identification, the isolate GNR-1 GNR-2 and GNR-3 were identified as strains of Bacteroides succinogenes, Butyrivibrio fibrisolvens and Clostridium cellobioparum, respectively. 한우의 반추위액에서 섬유소를 분해하는 균주 GPC-1, GPC-2, GNR-1, GNR-2, GNR-3를 선별하였다. 분리주 GPC-1과 GPC-2는 Gram 양성구균이며 편성혐기균으로서 Ruminococcus속으로 분류되었다. 분리주 GNR-1, GNR-2 및 GNR-3는 Gram 음성 간균이며 혐기균으로서 내생포자형성 유무에 따라 포자 형성균인 GNR-3는 Clostridium속으로 분류하고 포자를 형성하지 않은 균은 $H_2S$ 생성유무에 따라 Bacteroides 속과 Butyrivibrio 속으로 분류되었다. 종수준의 동정을 위하여 당분해능과 생화학적 조사를 통하여 GPC-1는 Ruminococcus albus로, GPC-2는 Ruminococcus flavefaciens로, GNR-1는 Bacteroides succinogenes로, GNR-2는 Butyrivibrio fibrisolvens로, GNR-3는 Clostridium cellobioparum로 각각 동정하였다.

삼성종합기술원 광소자 개발현황

김태일,Kim, Tae-Il 한국광학회 1998 광학과 기술 Vol.2 No.1

'05년 하반기 건화물선 해운시황 전망과 시사점

김태일,Kim, Tae-Il 한국사료협회 2005 飼料 Vol.4 No.4

축분뇨 액비 저장조의 운영실태 및 악취 물질 발생량 조사

김태일,송준익,정선,정종원,정의수,유용희,양창범,김민규,Kim T. I.,Song J. I.,Joung S.,Jeong J. W.,Chung E. S.,Barroga A. J.,Yoo Y. H.,Yang C. B.,Kim M. K. 한국축산환경학회 2005 축산시설환경학회지 Vol.11 No.3

본 연구는 국내에 설치되어 있는 액비저장조의 운영실태를 조사하고, 액비저장조에서 발생되는 악취물질을 구명하고자 수행하였다. 1. 국내에 200톤 규모의 액비저장조를 설치한 60 농가를 대상으로 한 본 조사에서 약 $93\%$가 액비저장조를 제대로 가동을 하고 있었으며 이중 $57\%$가 액비제조시 폭기 처리하고 있었다. 2. 조사 농가 중 년간 액비의 활용 횟수는 2회가 $50\%$로 나타났고 액비의 부숙 효과를 높이고 악취를 저감시키기 위한 목적으로 $64\%$가 미생물제제를 첨가하고 있었다. 반면에 액비 이용시 인력 장비의 비용 및 악취물질 발생 저감을 위한 첨가제 비용이 $43\%$로 조사되어 액비이용 시 문제점으로 지적되었다. 3. 액비 제조 형태별 악취물질 발현양상으로 호기 제조시 액비저장조내에서는 iso-valeric acid가 0.012에서 0.07ppm, Propionic acid가 $0.17\~2.85ppm$의 범위로 검지되었으며 혐기 제조시에는 n-Butyric acid가 1.5에서 2.3ppm, n-valeric acid가 $1.3\~1.8ppm$, acetaldehyde가 0.8에서 2.1ppm로 검지되어 호기 제조방법과 혐기 제조방법 모두 휘발성 지방산의 농도는 악취방지법의 규제농도 이상이었다. 부지경계선에서의 악취물질을 보면 호기시에는 미검출로 나타났고 혐기 제조시에는 Acetaldehyde가 $0.4\~0.9ppm$ 수준으로 검지되어 악취방지법의 규제농도를 초과였다. This study was carried out to determine the acceptability of liquid manure bin among livestock farmers and agricultural farmers, and quantify its malodorous compounds. The results were as follows; 1. The size of the manure bins owned by $93\%$ of 60 farmers surveyed was 200 M/T and were all in normal operation. Around $57\%$ of the normally operated bins were processed under aerobic condition. 2. Filly percent of the respondents utilized their liquid manure bin twice a year while $64\%$ used commercial microbial products to enhance maturity of their liquid manure and abatement of malodorous emissions. On the other hand, $43\%$ mentioned problems on the labor requirement, mechanical maintenance and lending cost of liquid manure processing and utilization, and the price of the commercial microbial products. 3. Malodorants emitted from livestock liquid manure bins and their boundary bin depended upon the livestock liquid manure processing condition. Within bin under the aerobic processing condition, Iso-valeric and propionic acid were ranged 0.012 to 0.07ppm and 0.17 to 2.85ppm, respectively. Within bin under the anoxic processing condition, n-butyric, n-valeric acid, and acetaldehyde were ranged 1.5 to 2.3ppm, 1.3 to 1.8ppm, and 0.8 to 2.1ppm, respectively. Malodorants emitted from the boundary of livestock liquid manure bins under the anoxic processing condition were detected the range of 0.4 to 0.9 ppm, more than the concentration of law regulation, as an acetaldehyde, but under the aerobic processing condition, they did not any detection.

돈 분뇨 액비에 미생물 첨가가 배추의 발아지수에 미치는 영향

김태일,유용희,정의수,양창범,김민균,Kim, T. I.,Yoo, Y. H.,Chung, E. S.,Barroga, Antonio J.,Yang, C. B.,Kim, M. K. 한국축산환경학회 2005 축산시설환경학회지 Vol.11 No.2

본 연구는 돈 분뇨 액비에 미생물 첨가가 배추의 발아지수에 미치는 효과를 구명하기 위해서 수행하였다. 돈 분뇨 액비는 107일 동안 폭기와 무폭기 상태로 액상비료를 제조하여 공시하였고 미생물 첨가는 $0.05\%,\;0.1\%,\;0.2\%,\;0.3\%$ 수준으로 하였다. $0.05\%$ 미생물 접종 처리구에서 식물 독성이 낮고 발아지수가 높게 나타났다. 첨가수준별 돈분 액비 이용시험에서 초기 돈 슬러리의 액비성상은 T-N 2,873 ppm, T-P 753 ppm, $NH_4-N$ 1,441.6 ppm, $NO_3-N$ 16.48ppm으로 50일이 되면서 폭기조건에서 T-N 3,672 ppm, T-P 164 ppm, $NH_4-N$ 183.87 ppm, $NO_3-N$ 21.97 ppm로 변화하였으며, 무폭기 조건에서 T-N 1,261 ppm, T-P 68 ppm, $NH_4-N$ 161 ppm, $NO_3-N$ 16.87 ppm로 나타났다. 미생물을 처리하지 않고 107일동안 폭기조건과 무폭기 조건으로 액비화한 시료의 발아지수는 각각 83과 40.4이였다. 돈 분뇨 액비를 무산소 제조시 $40\%$ 이상, 호기제조시 $50\%$ 이상의 발아지수가 개선되었다. 이와 같은 결과는 액비제조 처리가 무산소 제조보다는 호기제조 처리가 작물에 양호한 것으로 판단되어지며 이는 호기처리시 총질소의 함량을 높게 유지할 수 있도록 하는 결과인 것으로 사료된다. This study was carried out to investigate the effect of Synechocystis sp. KACC 91007 when added to a pig slurry or pig liquid fertilizer (PLF) on germination index (GI) of Chinese cabbage. The preliminary experiment involved the screening of inoculant levels which were; 0.05, 0.1, 0.2, and $0.3\%$, respectively. The $0.05\%$ level of inoculant was selected based on low phytotoxicity and high GI.. The PLF underwent a 107 day aerobic and anoxic processing conditions. The T-N, T-P, $NH_4$, and $NO_3-N$ concentrations of the untreated pig slurry were; 2,873, 753, 1,441.6, and 16.48 ppm, respectively. Using aerobic processing treatment, the fertilizer value of the PLF was 3,672, 164, 183.87, and 21.97 ppm, respectively. In contrast, the fertilizer value of the PLF processed under anoxic condition was reduced to 1,261, 68, 161, and 16.87 ppm. The GI value of the untreated PLF under aerobic and anoxic processing condition was 83 and $40.4^{*}\%$, respectively. With the addition of the $0.05\%$ microbial inoculant, the GI improved by more than 40 and $50\%$ respectively, when the PLF was processed under anoxic and aerobic conditions. The above findings proved that the aerobic processing of PLF for 107 days was better than anoxic and yielded higher T-N which is a macro-nutrient fertilizer material. Consequently, the addition of $0.05\%$ microbial inoculant resulted to a higher GI of the Chinese cabbage specifically under aerobic processing condition.

후박 및 은행물 추출물을 함유한 치약의 임상 및 미생물학적 효과에 관한 연구

김태일,염혜리,류인철,배기환,정종평,Kim, Tae-Il,Yeom, Hye-Ri,Ryu, In-Chul,Bae, Ki-Hwan,Chung, Chong-Pyoung 대한치주과학회 1996 Journal of Periodontal & Implant Science Vol.26 No.2

Previous studies have shown that Magnoliae cortex and Ginkgo biloba extracts were showed on the antimicrobial and anti-inflammatory action, in vitro. The purpose of this study was to evaluate on the effect of antimicrobial and anti-inflammatory activity of Magnoliae cortex and Ginkgo biloba extracts containing dentifrice in gingivitis. 70 subjects with gingivitis were divided into an experimental group which performed normal oral hygiene procedure with Magnoliae cortex and Ginkgo biloba extracts containing dentifrice and a control group which also performed normal oral hygiene procedure with the same dentifrice without the natural extracts and completed a doubleblind, cross-over study. At baseline and 3 weeks, subjects were assayed for clinical study by plaque index, gingival index, pocket depth, GCF rate, and microbiological study by subgingival dental plaque bacterial morphotypes by phase contrast microscopy, total anaerobes, total aerobes, Black pigmented bacteroides, A.actionomycetemcomitans, A.viscosus, C.rectus, Ssenguis; P.gingivalis, P.intennedia by bacterial culture and immunofluorescence microscopy. After 3 weeks using their respective dentifrices, reductions in the clinical indices of subjects were similar between the experimental dentifrice group and a control dentifrice group except for statistically significant much reductions in PI, GI, and GCF rate in the experimental dentifrice group as compared to control dentifrice group. Also statistically significant reductions in the motile rods and Spirochetes were found in both experimental group to compare with control group, however statistically much reduction in total anaerobes, Black pigmented bacteroides, and P.gingivalis, P.intennedia were found in the experimental dentifrice group as compared to control dentifrice group. This results indicates that Magnoliae cortex and Ginkgo biloba extracts containing dentifrice might be useful for elimination of gingival inflammation.

무더위 속 늘어나는 목장해충 박멸하자

김태일,Kim, Tae-Il 한국낙농육우협회 2017 낙농·육우 Vol.37 No.7

이달의 사양관리 - 8월 사양관리

김태일,임석기,Kim, Tae-Il,Im, Seok-Gi 한국낙농육우협회 2015 낙농·육우 Vol.35 No.8

자동 영상분석 계기를 이용한 골 유도재생능력의 분석에 관한 조직계측학적 연구

김태일,구영,류인철,정종평,한수부,최상묵,손성희,Kim, T.I.,Ku, Y.,Rhyu, I.C.,Chung, C.P.,Han, S.B.,Choi, S.M.,Son, S.H. 대한치주과학회 1996 Journal of Periodontal & Implant Science Vol.26 No.3

The assessment of alveolar bone changes on dental radiographs to indicate progression of periodontal diseases or healing response to therapy is routine procedure. However, the diagnostic accuracy in detecting small alveolar bone changes is very limited. Recently, guided bone regeneration therapy is popular, but the quantification of new bone is somewhat difficult with conventional evaluation method. To quantificate the amount of new bone, various evaluating methods have been introduced including histomorphometry, radiomorphometry, biochemical analysis, X-ray probe microanalysis, scanning electron microscope backscatter method. In this study, guided bone regeneration using resorbable membrane with & without PDGF-BB is quatificated through histomorphmetry to evaluate the efficacy of histomorphometric analysis. 4 beagle dogs and 8 Sprague-Dawley rats were selected as experimental animals. In beagle dog experiment, $4{\times}4mm$ Class II defects were created in maxillary both second premolars, and biodegradable membrane containing PDGF-BB(experimental group) were covered over one defect, and same membrane without PDGF-BB(control group) were covered over the other defect. At 2 weeks, 5 weeks after surgery, each beagle dogs were sacrificed, and the tissues were treated by undecalcified fixation. In Sprague-Dawley rat experiment, 5mm round defect were created in temporal bone, the same membranes were covered on the defects. At 1 week, 2 weeks after surgery, each rats were sacrificed, and undecalcified fixation were taken. After grinding tissue specimen, we analyse them histomorphometrically using image analysis system. In beagle dog 2 weeks specimens, new bone formation area were $0.03123mm^2$ in experimental group,and $0.03012mm^2$ in control group. At 5 weeks specimens, $0.15324mm^2$ in experimental group, and $0.09123mm^2$ in control group. In Sprague-Dawley rat specimens, new bone fomation area were $0.20448mm^2$ in 1 week experimental group, $0.03604mm^2$ in 1 week control group. At 2 weeks specimens, $0.46349mm^2$ in experimental group, $0.17741mm^2$ in control group. The results indicated that histomorphometric analysis of new bone formation using image analysis system is very effective quantification method to evaluate the efficacy of treatment modalities.