폴리페닐카보실란을 이용한 SiOC가 코팅된 스테인리스스틸 제조 및 이의 내부식성 특징

김종일,이윤주,김수룡,김영희,김정일,우창현,최두진,Kim, Jong-Il,Lee, Yoon-Joo,Kim, Soo-Ryong,Kim, Young-Hee,Kim, Jung-Il,Woo, Chang-Hyn,Choi, Doo-Jin 한국재료학회 2011 한국재료학회지 Vol.21 No.1

To improve the chemical stability of metal, the ceramic coatings on metallic materials have attracted interest from many researchers due to the chemical inertness of ceramic materials. To endure strong acids, SiOC coating on metal substrate was carried out by dip coating method using 20wt% polyphenylcarbosilane solution; SiC powder was added to the solution at 10wt% and 15wt% to improve the mechanical properties and to prevent cracks of the film. Thermal oxidation as a curing step was carried out at $200^{\circ}C$ for crosslinking of the polyphenylcarbosilane, and the coating samples were pyrolysized at $800^{\circ}C$ under argon to convert the polyphenylcarbosilane to SiOC film. The thicknesses of the SiOC coating films were $2.36{\mu}m$ and $3.16{\mu}m$. The quantities of each element were measured as $SiO_{1.07}C_{6.33}$ by EPMA, and it can be confirmed that the SiOC film from polyphenylcarbosilane was formed in a manner that was carbon rich. The hardness of the SiOC film was found to be 3.2Gpa through nanoindentor measurement. No defect including cracks appeared in the SiOC film. The weight loss of the SiOC coated stainless steel was within 2% after soaking in 10% HCl solution at $80^{\circ}C$ for one week. From these results, SiOC coating shows good potential for application to protect against severe chemical corrosion of stainless steel.

BGO:Eu 섬광체의 방사선 저항

김종일,정중현,도시홍,황해선,김성철,김중환 ( Jong Il Kim,Jung Hyun Jeong,Sih Hong Doh,Hae Sun Hwang,Sung Chuel Kim,Jung Hwan Kim ) 한국센서학회 1997 센서학회지 Vol.6 No.1

Bismuth germanate crystals well known as scintillator were grown by Czochralski method. In order to understand a mechanism of radiation resistance in Eu-doped BGO, we measured radiation induced-absorption spectra, excitation spectra, emission spectra and luminescence lifetimes of BGO crystals. We found that the charge transfer state of Eu^(3+) ion is to play a key role to enhance the radiation resistance in BGO crystal. The ^5D_0 emission of Eu^(3+) ions that is not suitable for the radiation detectors due to a long decay time was found to be increased with increasing europium concentration. In the BGO crystal doped with 0.1 mole%, the density of radiation induced color centers was reduced about twenty times and the light output of ^5D_0 was negligible by comparing to that of BGO.

객체 기반의 임베디드 실물 및 가상 프로토타입 통합 기법

김종일,이정배,양재수,이영란,정영진,한강우,강신관,김대응,Kim, Jong-Il,Lee, Jeong-Bae,Yang, Jae-Soo,Lee, Young-Ran,Jung, Young-Jin,Han, Kang-Woo,Kang, Sin-Kwan,Kim, Dae-Eung 한국정보처리학회 2007 정보처리학회논문지 A Vol.14 No.4

가상 프로토타이핑 환경에서는 다양한 컴포넌트와 라이브러리를 제공함으로써 정밀한 단위까지의 목표 모델의 시뮬레이션이 가능하다. 그리고 실물 프로토타이핑 환경에서는 목표 모델의 임베디드 구동 환경에 가까운 시뮬레이션 환경을 제공한다. 하지만, 가상 프로토타이핑 환경에서는 실제 목표 모델의 구동 환경 요소까지의 시뮬레이션이 어렵고, 실물 프로토타이핑 환경에서는 다양하고 정밀한 제품까지의 시뮬레이션이 어려운 실정이다. 이런 가상과 실물 프로토타이핑 환경의 단점을 보완하기 위한 통합 프로토타이핑 시스템을 위한 연동 기법이 개발되었으며, 본 논문에서는 기존의 실물/가상 프로토타이핑 연동 기법을 개선해서 객체 기반의 임베디드 시스템 통합 프로토타이핑 개발 환경을 구축하였다. 이러한 새로운 임베디드 시스템 개발 환경을 구축함으로써, 재사용성, 유연성, 확장성 그리고 편리성을 가질 수 있다. In the virtual prototyping environment, we can simulate details of a target model using many components and libraries provided in advance on a computer. The real prototyping environment provides the test simulation environment as a real product, but we can't do a detailed simulation of a real product in the virtual prototyping environment, and we can't do various simulations in the real prototyping environment. So, we made a integrated prototyping environment for linkage of the two types of prototyping environments. Also, in this paper, we developed the integrated prototyping environment based on objects. By this kind of embedded system development environment, we can have the advantages as reuse, flexibility, scalability, and more convenient of product making.

광주천의 역사와 문화

김종일,Kim, Jong-Il 한국하천협회 2006 하천과 문화 Vol.2 No.4

광주시는 의향, 예향의 도시특성을 살린 발전전략의 하나로 문화중심도시 조성사업을 추진중에 있고, 구 전남도청부지에 아시아문화의 전당을 건립하고 있다. 한편으로는 무등산, 광주천, 영산강 등 자연환경을 보전하고 쾌적한 도시환경을 조성하기 위해 환경 모범도시 건설에도 역점을 두고 있다.

일반원고 3 - 동물 진료비 원성에 대한 소고

김종일,Kim, Jong-Il 대한수의사회 2017 대한수의사회지 Vol.53 No.5

Rebamipide의 생식기관 내 흡수, 배설 및 항산화제로서 불임치료효과

김종일,박현준,박남철,Kim, Jong Il,Park, Hyun Jun,Park, Nam Cheol 대한생식의학회 2005 Clinical and Experimental Reproductive Medicine Vol.32 No.4

Objective: Rebamipide is a propionic acid derivative that has an action of the inhibition of superoxide production and removal of hydroxyl radical with the sperm incubation and cryopreservation. In the present study, to investigate whether rebamipide is useful to treat male infertility and sterility, the author observed the antioxidative effects in patient with male infertility and also examined its absorption and distribution in rat genital organ. Methods: To measure the distribution of rebamipide in reproductive organ in the rat, carbon indicated rebamipide, $^{14}C-OPC-12759$, was orally administered to 10 Spraque-Dawley rats and its organ concentration in serum, liver, kidney, stomach, duodenum, colon, urinary bladder, seminal vesicle, epididymis and testicle were measured each time after 0.5, 1, 2, 4, 8 and 24 hours by using HPLC fluorescent method. The concentrations in semen were measured by HPLC fluorescent method in a sample of 50 infertile males who took 900 mg of rebamipide daily for 3 months. To measure the antioxidative effect and fertility rate for 3 months, each month before and after the treatment, sperm motility, vitality, the oxygen free radical formation, level of peroxidation, fetilizing capacity of semen sample which were obtained from infertile male patients by masturbation after at least 48 hours abstinence were analyzed by computer assisted semen analyzer, eosin-nigrosin stain, chemiluminescence, thiobarbituric acid method and hypo-osmotic swelling test. Simultaneously in a sample that wanted baby, both pregnancy and delivery were researched. Results: The $^{14}C-OPC-12759$ concentration in the body of white rats was highest in gastrointestinal organ like stomach, smal intestine and duodenum and followed by genital organ like seminal vesicle, testis and epididymis. The rebamipide concentration in semen of infertile males was $220.77{\pm}327.84ng/mL$ (SD) which showed a large deviation but it was higher than serum which was $126{\pm}76ng/mL$ (SD). In the infertile males, after the treatment with rebamipide, the level of seminal reactive oxygen species (ROS) and lipid peroxidation have significantly decreased in duration of the treatment (p<0.05) and sperm vitality and fertilizing capacity except sperm motility significantly improved on post treatment of 2~3 months (p<0.05). Out of the 41 cases who hoped for pregnancy, 15 cases (36.6%) became pregnant and 12 cases had childbrith, 2 cases had miscarriage and one case is ongoing. The side effect was observed in 1 case (2%) which experienced diarrhea but it was lost spontaneously. Conclusions: We conclude from this study that rebamipide showed relatively high tendancy of absorption and excretion in the genital organ. In infertile males who had elevated ROS in semen, by specifically inhibiting the cell damage from the antioxidation, a way to preserve sperm motility, vitality and fertilizing capacity was confirmed.

고농도 염에 의한 Deinococcus radiodurans RecA 단백질의 DNA 비의존성 ATPase 역가의 활성화

김종일,Kim, Jong-Il 한국미생물학회 2010 미생물학회지 Vol.46 No.4

D. radiodurans RecA 단백질은 DNA에 결합한 DNA-단백질 복합체만이 ATPase 활성을 나타내며. 보통의 낮은 염 농도조건에서는 DNA가 존재하지 않으면 RecA 단백질에 의한 ATP 가수분해는 거의 일어나지 않았으나 이러한 ATP 가수분해현상은 높은 농도의 염을 첨가하게 되면 1,000배 활성화 되었으며 1.6 M KCl이 존재할 때 ATP 혹은 dATP를 가수분해 하였다. DNA가 존재하지 않을 때 염에 의해 촉진되는 활성은 RecA 단백질 농도에 비례하였고, 더 높은 염농도에서 더 높은 ATP 가수분해 활성이 나타났다. 이러한 활성화 현상을 다양한 종류의 이온 형태에서 분석하였을 때 1.6 M Cl 음이온이 존재할 때 양이온의 형태에 따른 활성화 정도는 $K^+{\geq}Na^+$> $NH_4^+$의 경향을 보였으며, 1.6 M의 K 양이온 존재할 때 음이온의 형태에 따른 활성화는 glutamate > $Cl^-$ > acetate > $PO_4^-$의 순서로 높게 나타났다. 고농도의 염이 존재하는 조건에서 DNA 비의존성 ATPase의 활성은 비교적 넓은 범위 최적 조건인 pH7과 pH 8 사이에서 최대 활성을 보였고, 기질에 대한 친화도면에서도 외가닥 DNA 의존성 활성보다는 이중가닥 DNA 의존성 활성형태를 보였다. 고농도의 염이 첨가되고 DNA가 존재하지 않을 때 RecA 단백질에 의한 ATP 가수분해를 위한 RecA 단백질의 활성 종 형태는 최소 3개의 RecA 단백질이 결합되어 있는 과량체로 작용하는 것으로 나타났다. Deinococcus radiodurans RecA protein, when bound to DNA, exhibits a DNA-dependent ATPase. In the absence of DNA, the rate of RecA protein-promoted ATP hydrolysis drops 1,000-fold under the physiological concentrations of salt. This DNA-independent activity can be stimulated to levels approximating those observed with DNA by adding high concentrations (approximately 1.6 M) of a wide variety of salts. This effect was characterized by varying salt concentration and comparing the effects of different ion types. The higher concentrations of salt stimulated the ATP hydrolysis by RecA protein in the absence of DNA. At 1.6 M chloride, the observed stimulation showed the following cation trend $K^+{\geq}Na^+$ > $NH_4^+$ and the following anion sequence was observed: $glutamate^- \; > \; C1^- \;> \; acetate^-\; > \;PO_4^-$ at 1.6 M $K^+$. The catalytic properties of the salt-stimulated ATP hydrolysis reaction was optimal between pH 7.0 and 8.0, which was similar to the double stran nded DNA-dependent ATPase activities of Deinococcus radiodurans RecA protein. In the absence of DNA the active species for ATP hydrolysis by RecA protein was shown to be an aggregate of three RecA protein molecules.

빈약한 사회복지, 이대로 좋은가

김종일,Kim, Jong-Il 한국대학교육협의회 1992 大學敎育 Vol.56 No.-

대학교수의 직업복지 : 현실과 이상

김종일,Kim, Jong-Il 한국대학교육협의회 1992 大學敎育 Vol.60 No.-

한국 대학의 해외분교정책 : 전망과 과제

김종일,Kim, Jong-Il 한국대학교육협의회 1990 大學敎育 Vol.47 No.-