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      • KCI등재

        용융전로(熔融轉爐)슬래그와 $C_3A(3CaO{\cdot}Al_2O_3)$ 펠렛사이의 계면반응(界面反應)

        김영환,고인용,Kim, Young-Hwan,Ko, In-Yong 한국자원리싸이클링학회 2005 資源 리싸이클링 Vol.14 No.5

        As a basic study for recycling molten converter slag as an ordinary portland cement (OPC) by a conversion process, the reaction mechanism and the rate of the formation of $C_4AF$ which is one of the main components of OPC were investigated. The converter slag whose basicity was controlled by adding reagent grade $SiO_2$ was melted and hold for 30 minutes in MgO crucible at $1300^{\circ}C{\sim}1350^{\circ}C$. Then, the sintered CaO pellet heated at the same temperature was dipped into the molten slag and hold for $10{\sim}30$minutes. After the reaction, the crucible was cooled in air and the specimen was cut off to the horizontal direction of the crucible. The dissolution rate of $C_3A$ pellet was measured by the change of radius of the sintered $C_3A$ pellet, and the formed phase of $C_4AF$ was observed by SEM/EDX. As a result, the dissolution rate of $C_3A$ pellet into molten slag was increased from $0.75{\times}10^{-4}(cm/sec)$ at $1300^{\circ}C$ to $1.67{\times}10^{-4}(cm/sec)$ at $1350^{\circ}C$, and the mixed layer of $C_4AF$ and $C_{12}A_7$ was found between slag and $C_3A$ pellet. 용융전로슬래그를 일반 포틀랜드 시멘트로 활용하기 위하여, 용융슬래그와 $C_3A(3CaO{\cdot}Al_2O_3)$가 반응하여 시멘트의 구성상인 $C_4AF$가 생성되는 기구와 생성속도를 조사하고자 한다. 전로슬래그에 소정의 $SiO_2$를 첨가하여 MgO도가니에 넣고 $1300^{\circ}C{\sim}1350^{\circ}C$에서 30분간 가열 용해하여 균질화 한 후, 같은 온도로 가열해 둔 소결 $C_3A$펠렛을 투입하여 $10{\sim}30$분간 반응시켰다. 반응 후, 급냉한 시편을 도가니의 직경방향으로 절단해서 펠렛 단면의 $C_3A$직경 변화를 측정하여 $C_3A$의 용해속도를 조사하고, 계면반응 생성상을 SEM/EDX로 관찰하였다. 그 결과 $C_3A$ 펠렛의 슬래그로의 용해속도는 $1300^{\circ}C$에서 $0.75{\times}10^{-4}(cm/sec)$으로부터 $1350^{\circ}C$에서 $1.67{\times}10^{-4}(cm/sec)$으로 증가하였으며, 슬래그와 $C_3A$ 펠렛 사이에 $C_4AF$와 $C_{12}A_7$의 혼합층이 생성됨을 알 수 있었다.

      • KCI등재

        전기로 공정에서 슬래그 중 산화철의 환원 회수에 관한 연구

        김영환,유정민,Kim, Young-Hwan,Yoo, Jung-Min 한국자원리싸이클링학회 2016 資源 리싸이클링 Vol.25 No.4

        전기로 공정에서 슬래그는 Fe를 약 20 ~ 35 wt.% 함유한 채로 슬래그 포트로 배출되어 냉각되고 있다. 슬래그 배출 전에 환원하여 용강으로 회수한다면 제강회수율을 향상할 수 있으며, 슬래그 배출량을 감소할 수 있다. 일반적으로 전기로 공정에서는 슬래그 포밍과 (FetO)의 환원제로 카본계의 환원제가 활용되고 있다. 본 실험은 Metal을 유도용해로에 용해한 후 슬래그와 환원제로 흑연분탄과 저가의 Al dross powder를 Pellet으로 투입하여 (FetO)의 환원 회수와 복인(復燐)에 대한 영향성을 조사하였다. 실험결과 Al dross에 의한 환원 회수율은 흑연분탄에 비해 2.5배 이상의 효과를 나타내었으며, 복인(復燐)에 대한 영향은 50 ppm 이하로 크지 않은 것으로 나타났다. EAF processed slag which contains about 20 ~ 35 weight percent FetO is poured to slag pot and cooled. If we recover Fe from molten slag by the reduction, we will improve steel yield rate and reduce slag quantity poured from the furnace. Usually, carbon is used as a reductant and slag foaming agent in the EAF process. In this experiment, after melt the metal in induction furnace and then add slag with carbon and Al dross powder as a reductant, we investigated the reduction of FetO from slag and change of Phophorus content. As the result, when we use Al dross as a reductant, recovery rate is two times more than carbon. Phosphorus pick up is less than 50ppm with reduction of EAF slag.

      • SCIESCOPUSKCI등재

        Evaluation of Environmental Circumstance Within Swine and Chicken Houses in South Korea for the Production of Safe and Hygienic Animal Food Products

        김영환,서형주,김진만,정연훈,문경환,Kim, Young-Hwan,Suh, Hyung-Joo,Kim, Jin-Man,Jung, Yeon-Hoon,Moon, Kyong-Whan Korean Society for Food Science of Animal Resource 2008 한국축산식품학회지 Vol.28 No.5

        This study was undertaken to determine the concentrations of airborne bacteria, fungi, particles, and endotoxin in swine and chicken houses. Six swine buildings and seven chicken houses were randomly selected in southern Gyonggi Province, South Korea. The geometric mean concentrations of airborne bacteria in swine and chicken houses were $2.7{\times}10^5\;CFU/m^3$ and $5.6{\times}10^7\;CFU/m^3$, respectively. The airborne bacteria concentrations in chicken houses were significantly higher than those of swine houses (p<0.05). The geometric mean concentration of airborne fungi in swine houses was $4.9{\times}10^3\;CFU/m^3$, which was higher than the value of $2.1{\times}10^3\;CFU/m^3$ found in chicken houses. The mean concentrations of airborne particles and endotoxin in swine houses were $3.48\;mg/m^3$ and $943.1\;EU/m^3$, and they were $15.43\;mg/m^3$ and $1,430.5\;EU/m^3$ in chicken houses, respectively. A significant difference between swine and chicken houses was found for total dust (p<0.05), but not for endotoxin. In this study, the concentrations of endotoxin in both swine and chicken houses as well as particles in chicken houses were high, and in about 50% of the samples exceeded the worker health safety levels of $614\;EU/m^3$ suggested in previous studies. These results may indicate a considerable respiratory hazard for workers in these environments.

      • KCI등재

        고리원전의 온배수 방출이 주변 해조군집에 미치는 영향

        김영환,안중관,윤희동,장민아,Kim, Young-Hwan,Ahn, Jung-Kwan,Yoon, Hee-Dong,Jang, Min-A 한국조류학회(藻類) 2007 ALGAE Vol.22 No.4

        This study is intended to clarify the effects of heated effluents on intertidal benthic marine algal community in Korea. The species composition and biomass of marine algae at the discharge canal of Gori nuclear power plant on the southeastern coast of Korea were investigated seasonally from February 2001 to October 2006. As a result, 54 species (7 blue-green, 12 green, 9 brown and 26 red algae) of marine algae were found at the discharge canal during the past six years. In general, the number of species observed was abundant during winter to spring and less in autumn. Enteromorpha compressa, E. intestinalis, E. prolifera and Caulacanthus ustulatus were common species found more than 80% frequency during the study period. Seasonal fluctuations of mean biomass were 1-440 g dry wt m?2 and dominant species in biomass were Enteromorpha spp. (contribution to a total biomass proportion 28%), Sargassum horneri (14%) and Amphiroa beauvoisii (14%). It is evident from the floristic composition and biomass data that unique micro-environment of the discharge canal support different communities from those on the intake or control area. Results from the large numbers of surveys before and during plant operation showed that, in the regions influenced by thermal effluents such as the discharge canal of power plants, the process of ecological succession has been proceeded. It is assumed that the uni-directional water flow and the time of overhaul largely affect the development and succession of benthic marine algal communities of the discharge canal.

      • KCI등재
      • KCI등재

        동해안 울진원전의 온배수 방출이 주변 해조군집에 미치는 영향

        김영환,안중관,이재일,엄희문,Kim, Young-Hwan,Ahn, Jung-Kwan,Lee, Jae-Il,Eum, Hee-Moon 한국조류학회(藻類) 2004 ALGAE Vol.19 No.3

        In order to clarify the structure and seasonal dynamics of warm tolerant benthic marine algal community in Korea, the species composition and biomass of marine algae at the discharge canal of Uljin nuclear power plant on the East Coast of Korea were investigated seasonally from February 1992 to October 2000. 107 species of marine algae were found at the discharge canal during the past nine years. In general, the number of species observed was abundant in spring or summer and less in autumn or winter. 27 species (4 blue-green, 5 green, 6 brown and 12 red algae) of marine algae occurred more than 1/ 6 frequency and thus can be categorized as warm tolerant species. Among these, one brown (Dictyota dichotoma) and four red algae (Gelidium amansii, Anphiroa ephedraea, Hydrolithon sargassi, Marginisporum crassissimum) are recorded as warm tolerant marine algae for the first time in Korea. Padina arborescens, Anphiroa zonata and Corallina pilulifera were common species found more than 75% frequency. Seasonal fluctuations of mean biomass were 0-1,330 g dry wt m^(-2) and dominant species in biomass were Corallina pilulifera (contribution to a total biomass proportion 34%), Anphiroa zonata (23%), Padina arborescens (18%) and Sargassum micracanthum (11%). The red algae appeared as predominant algal group at the discharge canal of Uljin nuclear power plant in the qualitative and quantitative aspects. The green algae such as Enterornorpha compressa appeared rather frequently at the discharge canal, but the biomass proportion was very low, in contrast to Kori nuclear power plant where there was definite green algal dominance. Differences in algal communities developed at the discharge canals of Uljin and Kori nuclear power plant on the East Coast of Korea, particularly biomass proportions of green algae, can probably be related to local environmental factors such as water velocity through the canal and natural seawater temperatures.

      • KCI등재

        UO$_{2}$ 펠릿 산화로의 분말 비산 방지를 위한 최종속도 측정

        김영환,윤지섭,정재후,진재현,홍동희,Kim Young-Hwan,Yoon Ji-Sup,Jung Jae-Hoo,Jin Jae-Hyun,Hong Dong-Hee 한국방사성폐기물학회 2005 방사성폐기물학회지 Vol.3 No.2

        A voloxidizer for a hot cell demonstration, that handles spent fuels of a high radiation level in a limited space should be small and spent fuel powders should not be dispersed out of the equipment involved. In this study a density rate equation as well as the Stokes'equation has been proposed in order to obtain the theoretical terminal velocity of powders. The terminal velocity of U$_{3}$O$_{8}$ has been predicted by using the terminal velocity of SiO$_{2}$, and then determination has been the optimum air flow rate which is able to prevent powders from scattering. An equation which has shown a relationship between theoretical terminal velocities of U$_{3}$O$_{8}$ and SiO$_{2}$ has been derived with the help of the Stokes'equation, and then an experimental verification made for the theoretical Stokes' equation of SiO$_{2}$ by means of an experimental device made of acryl. The theoretical terminal velocity based on the proposed density rate equation has been verified by detecting U$_{3}$O$_{8}$ powders in a filter installed in the mock-up voloxidizer. As the results, the optimum air flow rates seem to be 20 LPM by the Stokes'equation while they are 14.5 L/min by the density rate equation. At the experiments with the mock-up voloxidizer, a trace amount of U$_{3}$O$_{8}$ seems to be detectable at the air flow rate of 14.5 L/min by the density rate equation, but U$_{3}$O$_{8}$ powders of 7$\mu$m diameter seem detectable at the air flow rate of 20 L/min by the Stokes'equation. It is revealed that 14.5 L/min is the optimum air flowe rate which is capable of preventing U$_{3}$O$_{8}$ powders from scattering in the UO$_{2}$ voloxidizer and the proposed density rate equation is proper to calculate the terminal velocity of U$_{3}$O$_{8}$ powders.

      • SCIESCOPUSKCI등재

        전자분무형 질량분석기를 이용한 단백질의 서열분석

        김영환,박은정,장윤석 ( Young Hwan Kim,Eun Jung Park,Yoon Seok Chang ) 생화학분자생물학회 1994 BMB Reports Vol.27 No.6

        After horse heart cytochrome C was digested enzymatically with trypsin, the mixture of digestion solution was separated by gradient reverse-phase HPLC and collected fractionally. Using electrospmy ionization mass spectrometry (ESI-MS), each peptide was analyzed for exact molecular mass. The sequence informations for some tryptic peptides were obtained by cone voltage fragmentation method. These results suggest that mass spectrometry can be used to sequence peptides or proteins, to define N- and C-terminal sequence heterogenity, to locate and to correct errors in DNA- and cDNA-deduced protein sequences, which are not easily handled by conventional techniques.

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