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Magneto-transport Properties of GaMnAs:Si Ferromagnetic Semiconductors
Hyungchan Kim,Hakjoon Lee,정선재,Y. J. Cho,X. Liu,J. K. Furdyna,이상훈 한국물리학회 2009 THE JOURNAL OF THE KOREAN PHYSICAL SOCIETY Vol.55 No.1
The magnetic properties of a series of GaMnAs:Si ferromagnetic semiconductor films, in which the Mn concentration ranges from 7% to 10%, were investigated by using magneto-transport measurements. The temperature dependence of the resistivity revealed a systematic increase in the Curie temperature (Tc) with increasing Mn concentration in the series. Since the Tc of the undoped GaMnAs ferromagnetic semiconductor decreases with increasing Mn concentration above 6%, the observation of a systematic increase of Tc with increasing Mn concentration in our GaMnAs:Si series indicates the effectiveness of our counter doping for the incorporation of a a large amount of 7% Mn in the system. The field scan of the planar Hall effect (PHE) showed a typical two-step switching behavior at low temperatures, indicating the presence of a strong cubic anisotropy. The switching fields, however, systematically decreased with increasing Mn concentration in the series. The angular dependences of the switching fields were fitted by using the magnetic free energy and Cowburn’s model to obtained the domain pinning energy, which showed systematically smaller values as the Mn concentration of the sample was increased. The temperature dependences of the pinning energies indicated a change in the uniaxial anisotropy from the [110] to the [110] direction with increasing Mn concentration in the series.
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ZnO/rutile-$TiO_2$, ZnO, rutile-$TiO_2$, CdS를 이용한 Congo red의 광 촉매 분해반응
김창석,류해일,Kim, Chang Suk,Ryu, Hae-Ill 한국분석과학회 2001 분석과학 Vol.14 No.3
ZnO, CdS, rutile-$TiO_2$ 및 혼합 rutile-$TiO_2$/ZnO와 같은 여러 반도체를 이용하여 Congo Red를 광 촉매 분해시켰다. 연구 결과 ZnO, CdS, rutile-$TiO_2$ 중에서는 CdS의 광 촉매 효과가 제일 컸는데 이것은 CdS가 제일 작은 band gap 에너지를 가지고 있기 때문이었다. 또한 혼합 촉매에서는 ZnO의 함량이 rutile-$TiO_2$에 비하여 상대적으로 높을수록 분해 반응을 촉진하였다. 이것은 $Zn^{2+}$ 가수분해 생성물이 구조적으로 안정한 화합물인 rutile-$TiO_2$의 표면을 덮음으로서 자외선 흡수를 차단하기 때문에 라디칼 생성을 저해하기 때문이었다. Photocatalytic degradation of Congo red was performed using various semiconductors as ZnO, CdS, rutile-$TiO_2$ or mixed rutile-$TiO_2$/ZnO. The change of degradation of the dye was investigated by UV-visible spectrophotometric method. The photocatalytic action of CdS was greater than ZnO and rutile-$TiO_2$ in account of low band gap energy of CdS. The rate of photocatalytic degradation reaction increased drastically in according to increasing ratio of ZnO on mixed rutile-$TiO_2$/ZnO. These photocatalytic effect of rutile-$TiO_2$ was suppressed by more stable rutile-$TiO_2$, doping the hydrolysis product with $Zn^{2+}$ prior to calcination onto the rutile-$TiO_2$ surface.
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