PVP-기반 유기 절연막 형성과 OTFT 제작

장지근,서동균,임용규,Jang, Ji-Geun,Seo, Dong-Gyoon,Lim, Yong-Gyu 한국재료학회 2006 한국재료학회지 Vol.16 No.5

The formation and processing of organic insulators on the device performance have been studied in the fabrication of organic thin film transistors (OTFTs). The series of polyvinyls, poly-4-vinyl phenol(PVP) and polyvinyltoluene (PVT), were used as solutes and propylene glycol monomethyl ether acetate(PGMEA) as a solvent in the formation of organic insulators. The cross-linking of organic insulators was also attempted by adding the thermosetting material, poly (melamine-co-formaldehyde) as a hardener in the compound. The electrical characteristics measured in the metal-insulator-metal (MIM) structures showed that insulating properties of PVP layers were generally superior to those of PVT layers. Among the layers of PVP series: PVP(10 wt%) copolymer, 5 wt% cross-linked PVP(10 wt%), PVP(20 wt%) copolymer, 5 wt% cross-linked PVP(20 wt%) and 10 wt% cross-linked PVP(20 wt%), the 10 wt% cross-linked PVP(20 wt%) layer showed the lowest leakage current characteristics. Finally, inverted staggered OTFTs using the PVP(20 wt%) copolymer, 5 wt% cross-linked PVP(20 wt%) and 10 wt% cross-linked PVP(20 wt%) as gate insulators were fabricated on the polyether sulphone (PES) substrates. In our experiments, we could obtain the maximum field effect mobility of 0.31 $cm^2/Vs$ in the device from 5 wt% cross-linked PVP(20 wt%) and the highest on/off current ratio of $1.92{\times}10^5$ in the device from 10 wt% cross-linked PVP(20 wt%).

Cross-Linked PVP 게이트 유기 박막트랜지스터

장지근,오명환,장호정,김영섭,이준영,공명선,이영관,Jang Ji-Geun,Oh Myung-Hwan,Chang Ho-Jung,Kim Young-Seop,Lee Jun-Young,Gong Myoung-Seon,Lee Young-Kwan 한국마이크로전자및패키징학회 2006 마이크로전자 및 패키징학회지 Vol.13 No.1

유기 박막트랜지스터(OTFTs)제작에서 PVP-게이트 절연막의 형성과 처리가 소자성능에 미치는 영향을 조사하였다. 유기 게이트 용액의 제조에서는 polyvinyl 계열의 PVP(poly-4-vinylphenol)를 용질로, PGMEA (propylene glycol monomethyl ether acetate)를 용매로 사용하였다. 또한 열경화성 수지인 poly(melamine-co-formaldehyde)를 경화제로 사용하여 유기 절연막의 cross-link를 시도하였다. MIM 시료의 전기적 절연 특성을 측정한 결과, PVP-기반 유기 절연막은 용액의 제조에서 PGMEA에 대한 PVP와 poly (melamine-co-formaldehyde)의 농도를 증가시킬수록 낮은 누설전류 특성을 나타내었다. OTFT 제작에서는 PGMEA에 대해 PVP를 20 wt%로 섞은 PVP(20 wt%) copolymer와 5 wt%와 10 wt%의 poly(melamine-co-formaldehyde)를 경화제로 추가한 cross-linked PVP(20 wt%)를 게이트 유전 재료로 사용하였다. 제작된 트랜지스터들에서 전계효과 이동도는 5 wt % cross-linked PVP(20 wt%) 소자에서 $0.31cm^2/Vs$로, 그리고 전류 점멸비는 10 wt% cross-linked PVP(20 wt%) 소자에서 $1.92{\times}10^5$으로 가장 높게 나타났다. The preparation and processing of PVP-gate insulators on the device performance have been studied in the fabrication of organic thin film transistors (OTFTs). One of polyvinyl series, poly-4-vinyl phenol(PVP) was used as a solute and propyleneglycol monomethyl etheracetate(PGMEA) as a solvent in the formation of organic gate solutions. The cross-linking of organic insulators was also attempted by adding the thermosetting material, poly (melamine-co-formaldehyde) as a hardener in the compounds. From the measurements of electrical insulating characteristics of metal-insulator-metal (MIM) samples, PVP-based insulating layers showed lower leakage current according to the increase of concentration of PVP and poly (melamine-co-formaldehyde) to PGMEA in the formation of organic solutions. The PVP(20 wt%) copolymer with composition of 20 wt% PVP to PGMEA and cross-linked PVPs in which 5 wt% and 10 wt% poly (melamine-co-formaldehyde) hardeners had been additional]y mixed into PVP(20 wt%) copolymers were used as gate dielectrics in the fabrication of OTFTs, respectively. In our experiments, the maximum field effect mobility of $0.31cm^2/Vs$ could be obtained in the 5 wt% cross-linked PVP(20 wt%) device and the highest on/off current ratio of $1.92{\times}10^5$ in the 10 wt% cross-linked PVP(20 wt%) device.

유기박막 트랜지스터용 PVP (poly-4-vinylphenol) 게이트 절연막의 제작과 특성

백인재,유재헉,임현승,장호정,박형호,Baek, In-Jae,Yoo, Jae-Hyouk,Lim, Hun-Seung,Chang, Ho-Jung,Park, Hyung-Ho 한국마이크로전자및패키징학회 2005 마이크로전자 및 패키징학회지 Vol.12 No.4

유기 박막트랜지스터 (OTFT)를 제작하기 위하여 게이트 절연막으로서 PVP 계통의 유기막을 갖는 MIM(metal-insulator-metal)구조의 유기 절연층 소자를 제작하였다. 유기 절연층의 형은 ITO/Glass 기판위에 polyvinyl 계열의 PVP(poly-4-vinylphenol)를 용질로, PGMEA (propylene glycol monomethyl ether acetate)를 용매로 사용하여 co-polymer PVP를 제조하였다. 또한 열경화성 수지인 poly(melamine-co-formaldehyde)를 경화제로 사용하여 cross-linked PVP 절연막을 합성하였다. 유기 절연층의 전기적 특성은 co-polymer PVP 소자에 비해 cross-link 방식으로 제조된 소자에서 약 300 pA의 낮은 누설전류와 상대적으로 낮은 잡음전류의 특성을 나타내었다. 또한 cross-linked PVP 절연막에서 보다 양호한 표면형상 (거칠기)이 관찰되었으며 정전용량 값은 약 0.11${\~}$0.18 nF의 값을 나타내었다. The organic insulation devices with MIM (metal-insulator-metal) structures as PVP gate insulation films were prepared for the application of organic thin film transistors (OTFT). The co-polymer organic insulation films were synthesized by using PVP(poly-4-vinylphenol) as solute and PGMEA (propylene glycol monomethyl ether acetate) as solvent. The cross-linked PVP insulation films were also prepared by addition of poly (melamine-co-formaldehyde) as thermal hardener. The leakage current of the cross-linked PVP films was found to be about 300 pA with low current noise. and showed better property in electrical properties as compared with the co-polymer PVP insulation films. In addition, cross-linked PVP insulation films showed better surface morphology (roughness), showing about 0.11${\~}$0.18 nF in capacitance for all PVP film samples.

한우 난포란의 체외성숙 시 여러 가지 첨가물이 배 발생과 품질에 미치는 영향

박흠대,장미진,박용수 한국동물생명공학회(구 한국동물번식학회) 2006 Reproductive & developmental biology Vol.30 No.1

본 연구는 체외성숙 배지에 첨가하는 PVP의 농도, EGF, cysteine 및 PVP의 단독 또는 혼합첨가가 한우 체외수정란의 체외발생에 미치는 영향을 검토하였다. 체외성숙 배지에 PVP의 첨가농도(0.1~3.0%)에 따른 분할율은 차이가 없었으나, 배반포 발달율은 0.5% PVP 첨가군이 가장 높았다(P<0.05). PVP, EGF 및 cysteine의 단독 및 혼합 첨가에 따른 분할율은 cysteine 단독첨가군이 높았으나(P<0.05), 배반포 발달율은 차이가 없었다. Inner cell mass 수는 대조군과 cysteine 첨가군이 PVP 첨가군에 비하여 유의하게 높았고(P<0.05), 총 세포수도 cysteine 첨가군에서 가장 높았다. 수정란이식 결과는 대조군, EGF, cysteine 및 EGF+cysteine 군의 임신율은 46.1~63.6%로서 비슷하였으나, PVP 첨가군은 10%로서 다른 군에 비하여 유의하게 낮았다(P<0.05). 본 연구 결과는 체외성숙 배지에 PVP의 첨가로 배 발생은 가능하지만, 세포의 품질에는 악영향을 미치는 것을 보여준다. This study was examined the effects of concentrations of polyvinylpyrrolidone(PVP) and supplementation of EGF, cysteine and PVP during in vitro maturation on the development of bovine embryos. In experiment 1, 0.1 to 3.0% PVP was supplemented to IVM medium before IVF. The development rates to the blastocyst stage was significantly higher in 0.5% PVP group than 3.0% PVP group (P<0.05). In experiment 2, EGF, rysteine and PVP were supplemented to IVM medium. The hight cleavage rate was obtained from cysteine group, but blastocyst formation rates did not differ among groups. The highest total cell number and inner cell mass (ICM) cell number were observed in cysteine group. In PVP group, ICM cell number was significantly low than those of cysteine and control groups (P<0.05). After embryo transfer, pregnancy rate was significantly low in PVP group compared to other groups (P<0.05). These results indicate that the supplementation of PVP in IVM medium support the embryo development, but has a deteriorate effect on the blastocyst quality.

Survival and In Vitro Development of Immature Bovine Oocytes Cryopreserved by Vitrification

Yang, Byoung-Chul,Im, Gi-Sun,Chang, Won-Kyong,Lee, Yun-Keun,Oh, Sung-Jong,Jin, Dong-Il,Im, Kyong-Sun,Lee, Chang-Kyu Asian Australasian Association of Animal Productio 2003 Animal Bioscience Vol.16 No.1

The present study was undertaken to investigate the effects of PVP concentration and exposure temperature to vitrification solution on the post-thaw survival, in vitro maturation and development of immature bovine oocytes (germinal vesicle stage). The vitrification solution (VS) consisted of 40% ethylene glycol (EG)+0.5 M sucrose (S)+10% FBS. PVP was added to VS: 0%, 5% or 10%. The cumulus-oocyte complexes (COCs) were diluted in VS as one step, after 2 min the COCs were loaded in straw and vitrified by direct immersion into liquid nitrogen. For thawing, the straws were plunged into $30^{\circ}C$ water bath for 10s. After thawing, the oocytes were diluted in 0.5 M (in DPBS with 10% FBS) sucrose solution for 5 min. The survival rate (FDA-test and trypan blue) of immature bovine oocytes was measured. The survival rate was higher in 5% PVP (91.5%) than in 0% (64.2%) or in 10% PVP (79.7%). The proportion of metaphase II formation was 69.35% in control (no vitrified COCs), 9.3% in 40% EG+0.5 M S+0% PVP and 21.05% in 40% EG+0.5 M S+5% PVP (p<0.05). The effect of room temperature ($25^{\circ}C$ for 10 min) and cold temperature ($4^{\circ}C$ for 10 min) on COCs were determined in this study. After IVF, the cleavage and blastocysts rate of oocytes exposed to room temperature and cold temperature in VS+5% PVP was significantly different (2 cell: 63.20% vs 37.97%, blastocysts: 18.40% vs 2.53%). The cleavage rates of frozen-thawed oocytes were 20.53% with PVP and 22.13% without PVP (p>0.05). Two out of 151 oocytes (1.32%) developed to blastocyst stage after frozen-thawed with 5% PVP (p>0.05). Development of oocytes after frozen-thawing to the 2 cell were not significantly affected with or without PVP following IVF. However, the vitrification of immature bovine oocytes with PVP maintained the ability to develop to the blastocyst stage after IVM-IVF and IVC, while no blastocysts were obtained from oocytes vitrified without PVP. These results suggested that PVP has a protective role for vitrification of immature bovine oocytes as far as survival is concerned, however, the protection was not sufficient enough to support blastocyst formation.

자가가교형 P(GMA-g-PPG)-co-POEM) 분리막의 이산화탄소/질소 분리 성능에 대한 PVP의 영향

김나운,박병주,박민수,김종학 한국막학회 2018 멤브레인 Vol.28 No.2

무분별한 이산화탄소 배출로 인한 지구온난화는 이상기후와 생태계 파괴 등을 초래함으로써 인간의 삶에 심각한 영향을 미치고 있다. 이러한 문제의 근본 원인인 이산화탄소 배출을 저감하는 방법으로 본 연구에서는 자가-가교 성질이 있는 P(GMA-g-PPG)-co-POEM) (SP) 공중합체와 상용 고분자인 polyvinylpyrrolidone (PVP)를 혼합하여 블렌드 고분자 분리막을 제조하는 방법을 제시하였다. PVP 함량에 따른 분리막의 이산화탄소/질소 투과 특성을 확인하였으며, PVP의 함량이 증가 할수록 투과도는 감소하고 선택도는 증가하는 결과를 보였다. 특히 PVP 함량이 30 wt%인 경우, 투과도는 순수 SP 고분자의 CO2 투과도인 72.9 GPU에서 12.6 GPU로 감소하였으나, CO2/N2 선택도는 28.1에서 50.4로 약 79% 증가하였다. 이는 SP 공중합체와 PVP 사이의 수소결합으로 인해 고분자 사슬이 더욱 조밀하게 배열되기 때문인 것으로 볼 수 있으며, 이를 FT-IR, TGA, XRD, SEM을 통해 분석하였다. 따라서, 본 연구에서는 SP/PVP 고분자 블렌드 내 PVP의 함량을 조절함으로써 분리막의 투과도 및 선택도를 손쉽게 조절할 수 있음을 확인하였다. Global warming due to indiscriminate carbon dioxide emissions has a profound impact on human life by causing abnormal climate change and ecosystem destruction. As a way to reduce carbon dioxide emissions, in this study, we presented a polymeric membrane prepared by blending a self-crosslinkable P(GMA-g-PPG)-co-POEM (SP) copolymer and commercial polymer polyvinylpyrrolidone (PVP). As the content of PVP increased, it was observed that the gas permeance decreased and CO2/N2 selectivity increased. At 30 wt% PVP content, the CO2 permeance of the membrane decreased from 72.9 GPU of pure SP polymer to 12.6 GPU, while CO2/N2 selectivity improved by 79% from 28.1 to 50.4. It results from the hydrogen bonding between the SP copolymer and PVP, leading to more compact structure of the polymer chains, which was confirmed by FT-IR, TGA, XRD and SEM analysis. Therefore, we suggest that the permeance and selectivity of the membranes can be easily adjusted as desired by controlling the PVP content in the SP/PVP polymer blend.

은 양이온과 PVP의 상호작용에 대한 연구

이철재,김동엽,남기영,Lee, Chul-Jae,Kim, Dong-Yeub,Nam, Ki-Young 대한화학회 2009 대한화학회지 Vol.53 No.5

The interaction between polyvinylpyrrolidone(PVP) and silver cation has been studied in water at room temperature and atmospheric pressure. The PVP and PVP/Ag composite was observed by transmission electron microscopy (TEM), UV-VIS absorption spectroscopy, Raman spectroscopy and oxygen/carbon dioxide analyzer. We identified silver cations interacting with nonbonding electrons of the oxygen atom in the carbonyl group of PVP. It was shown that PVP/Ag formed stable composites. 폴리비닐피롤리돈(PVP)과 은 양이온과의 상호작용을 상온 및 상압 조건에서 연구하였다. PVP 와 PVP/Ag 복합체는 투과전자현미경(TEM), 자외선/가시선 흡수분광법, 라만분광법, 산소/이산화탄소 분석기를 통하여 관측하였다. 은 양이온은 PVP분자의 카르보닐기 산소원자에 있는 비공유전자쌍과 상호작용하여 안정한 PVP/Ag 복합체를 형성하는 것을 확인할 수 있었다.

흑우에 있어서 PVP-I용액의 자궁 내 주입이 발정발현 및 수태율에 미치는 영향

백광수,우제훈,김남영,신상민,손준규,조인철,장선식,박설화,채현석,박남건 한국수정란이식학회 2016 한국수정란이식학회 학술대회 Vol.2016 No.10

소에서 저수태 발생율은 5∼35%로 지역, 조사방법 및 연구자 등에 따라 다양하게 보고 되고 있다(Purohit, 2008). 저수태의 원인으로서는 비정상적인 번식기관, 자궁 내 감염, 호 르몬 이상, 사양관리 부적합, 복합적 요인 등이 관여하고 있는데(Singh 등, 2008), 이 중에 서도 자궁 내 감염의 요인이 2.4∼20.0%로 비교적 높게 보고되고 있다(Rao, 1981). 자궁질 환을 가진 대부분의 암소들은 황체단계가 연장됨에 따라 무발정형태로 나타나게 되므로 적극적인 대처가 요구된다는 점에서, 호르몬 투여방법을 포함하여 PGF2α나 estradiol의 투 여 그리고 항생물질이나 povidone-iodine(PVP-I)의 자궁 내 주입과 같은 많은 치료방법이 적용되고 있다. 그러나 호르몬 잔류, 항생제 내성균 및 처리 중단시기 등의 문제점들을 가 지고 있다. PVP-I는 처리 중단시기가 필요하지 않고, 과도한 투여의 경우를 제외하고는 우유로 전이되지 않으며, 구입이 쉽고, 저렴하며, 투여하기가 용이하다는 실용성을 가지고 있기 때문에 매우 고무적인 방법이라고 할 수 있다(Rayos 등, 2002). 또한 자궁내막의 환 경을 개선하고, 암소의 자궁수촉을 촉진시키기 때문에 PGF2α를 생산하는 역할이 빨리 회 복된다(Ahmed와 Elsheikh, 2014). 그러나 PVP-I는 농도가 중요한데, 농도가 너무 높으면 자궁벽을 자극할 수 있고 문제를 더 키울 수 있는 반면에, 농도가 너무 약하면 효과가 나 타나지 않거나, 어떤 유형의 미생물이 제거되는 대신에 다른 기회적 미생물이 점유하기에 적합한 환경을 제공할 수가 있다(Rayos 등, 2002). 자궁내막염을 가진 암소의 경우에는 자 궁 내에 존재하는 화농과 유기물의 잔재가 PVP-I 용액의 살균효과를 저해할 수 있다는 부정적인 견해도 있으나(Nakao 등, 1988), 대부분의 연구자들은 1% 및 2% PVP-I 용액이 번식효율을 향상시키는데 매우 효과적이라고 보고하였다(Mido 등, 2016; Ahmed와 Nour, 2015; Ahmed 등, 2013; Knutti 등, 2000; Edwell 등, 2000; Rayos 등, 2002; Koujanz 등, 1996). 본 연구에서는 2% PVP-I 용액을 저수태우의 자궁 내에 주입하여, 발정발현 및 수 태율에 미치는 영향을 구명하고자 수행하였다. 저수태우에 2% PVP-I 용액을 50mL 자궁 내에 주입하여 자연발정 비율, 유기발정(PGF2α)에 의한 발정발현율, 자연 및 유기발정에 의한 수태율, 황체중기 및 황체중기 이외의 단계에 따른 자연발정 발현율을 조사하였다. PVP-I 처리 후 자연발정 비율은 27.3%(3/11두)였고, 유기발정에 의한 발정발현율은 87.5%(7/8두)였으며, 자연 및 유기발정에 의한 수태율은 63.6%(7/11두)였다. 황체중기(발정 주기 5∼10일) PVP-I 처리에 따른 자연발정 발현율은 60%(3/5두)였고, 황체중기 이외에 PVP-I 용액을 처리한 경우의 자연발정 발현율은 0%(0/6두)였다.

Silver Immobilization on Honeycomb-patterned Polyvinypyrrolidone thin Films via an Electroless Process

Kim, Bong-Seong,Kim, Won-Jung,Kim, Young-Do,Huh, Do-Sung Korean Chemical Society 2011 Bulletin of the Korean Chemical Society Vol.32 No.12

Honeycomb-patterned polyvinypyrrolidone (PVP) thin films coated with nanometer-sized silver particles were prepared using honeycomb-patterned polystyrene (PS) template films fabricated by casting a polystyrene solution under humid condition. Silver was first metallized on the patterned PS films via silver nitrate ($AgNO_3$) reduction using tetrathiafulvalene (TTF) and a small amount of PVP as the reductant and dispersing agent, respectively. The effects of $AgNO_3$, TTF, and PVP solution concentrations during the reduction process in acetonitrile were determined to obtain a uniform silver-coated honeycomb-patterned PS film. Second, the silver-metallized patterned porous PS films were filled with high PVP concentration solutions via the spincoating process. Silver-coated patterned PVP films were obtained by peeling off the PVP layer from the template PS film after drying. The results show that the honeycomb-patterned PVP films uniformly coated with silver particles are conveniently obtained using the silver-coated patterned PS template, although the direct fabrication of these films using water droplets under humid conditions was not feasible because of the water solubility of PVP.

Silver Immobilization on Honeycomb-patterned Polyvinypyrrolidone thin Films via an Electroless Process

허도성,Bong Seong Kim,Won Jung Kim,,김영도 대한화학회 2011 Bulletin of the Korean Chemical Society Vol.32 No.12

Honeycomb-patterned polyvinypyrrolidone (PVP) thin films coated with nanometer-sized silver particles were prepared using honeycomb-patterned polystyrene (PS) template films fabricated by casting a polystyrene solution under humid condition. Silver was first metallized on the patterned PS films via silver nitrate (AgNO3)reduction using tetrathiafulvalene (TTF) and a small amount of PVP as the reductant and dispersing agent,respectively. The effects of AgNO3, TTF, and PVP solution concentrations during the reduction process in acetonitrile were determined to obtain a uniform silver-coated honeycomb-patterned PS film. Second, the silver-metallized patterned porous PS films were filled with high PVP concentration solutions via the spincoating process. Silver-coated patterned PVP films were obtained by peeling off the PVP layer from the template PS film after drying. The results show that the honeycomb-patterned PVP films uniformly coated with silver particles are conveniently obtained using the silver-coated patterned PS template, although the direct fabrication of these films using water droplets under humid conditions was not feasible because of the water solubility of PVP.