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Zhihao Chen,Yijie Jin,Wenzhong Yang,Bin Xu,Yun Chen,Xiaoshuang Yin,Ying Liu 한국공업화학회 2019 Journal of Industrial and Engineering Chemistry Vol.75 No.-
Polypyrrole (PPy) coatings were successfully electrosynthesized on the carbon steel by embedding SnO2and Sb-SnO2 nanoparticles (NPs). The associated structural, morphology, hydrophobic, physicalproperties, anti-corrosion and self-healing performance of these coatings were systematically studiedby several tests. XRD results showed that SnO2 had a tetragonal rutile structure and the lattice parametersindicated that Sb ions were successful substituted into SnO2 lattice. The average size of SnO2 NPs wasdecreased by the incorporation of Sb-SnO2 NPs, which were found through TEM images. The contactangle test showed that the hydrophobic of PPy coatings was greatly enhanced by the incorporation of Sb-SnO2 NPs. SEM results revealed that Sb-SnO2/PPy coating exhibited a more compact and uniform surfacethan SnO2/PPy coating, hence the physical barrier effect was significantly strengthened. Theelectrochemical measurements confirmed the excellent anti-corrosion and self-healing ability of Sb-SnO2/PPy coating for a long immersion time in HCl solution. The superior anti-corrosion performance ofSb-SnO2/PPy coating was ascribed to the synergistic effects of the anodic protection combined with theself-healing effect, the excellent physical barrier effect with compact, smooth and hydrophobic coatingsurface as well as the formation of p-n junction with decreased charge transfer.
Xiaoshuang Luo,Haitao Duan,Jian Li,Shengpeng Zhan,Dan Jia,Jiesong Tu,Yinhua Li,Yaping Chen 대한금속·재료학회 2022 METALS AND MATERIALS International Vol.28 No.4
This study emphasizes the effect of ultrasonic surface rolling (USR) on the surface roughness, hardness, and tribologicalproperties of ductile iron under different normal loads. Results revealed that surface roughness was reduced by 96% andsurface hardness increased by 37.8% after USR treatment. By increasing normal load, the average friction coefficient of theUSR-treated specimens decreased, but the wear rate of both USR-treated and untreated specimens increased, mainly becausethe dominant wear mechanism changed. The average friction coefficient of the untreated specimen (~ 0.32) was much higherthan the USR-treated specimen (~ 0.24) when the normal load was 30 N. However, the wear rate of the USR-treated specimenwas larger than that of the untreated specimen when the normal load was greater than 20 N because the higher hardnessabrasive particles on the worn surface of the USR-treated specimen not only accelerated abrasive particle wear, but alsocaused more severe adhesive wear.
Monte Carlo Simulation on Kinetics of Batch and Semi-Batch Free Radical Polymerization
Jing Shao,Peng Chen,Wei Tang,Ru Xia,Xiaoshuang Feng,Jiasheng Qian,Changjiang Song 한국고분자학회 2015 Macromolecular Research Vol.23 No.11
Based on Monte Carlo simulation technology, we proposed a hybrid routine which combines reaction mechanism together with coarse-grained molecular simulation to study the kinetics of free radical polymerization. By comparing with previous experimental and simulation studies, we showed the capability of our Monte Carlo scheme on representing polymerization kinetics in batch and semi-batch processes. Various kinetics information, such as instant monomer conversion, molecular weight, and polydispersity etc. are readily calculated from Monte Carlo simulation. The kinetic constants such as polymerization rate kp is determined in the simulation without of “steady-state” hypothesis. We explored the mechanism for the variation of polymerization kinetics those observed in previous studies, as well as polymerization-induced phase separation. Our Monte Carlo simulation scheme is versatile on studying polymerization kinetics in batch and semi-batch processes.
Xie Tao,Zhang Wei,Chen Chengjie,Wang Xiaoshuang,Zhang Jing,Luan Aiping,He Yehua 한국원예학회 2023 Horticulture, Environment, and Biotechnology Vol.64 No.6
Somatic embryogenesis (SE) is a key regeneration process in plant. AcSERK1 is a gene specifi cally expressed in the early stage of SE in pineapple ( Ananas comosus ), suggesting that the promoter of SERK1 might contain specifi c cis acting element regulating SE. To identify embryonic cell-specifi c element in the SERK1 promoter, a series of binary plant transformation vectors with GUS (β-glucuronidase) reporter gene were systematically analyzed by transient gene expression system in wild-type and transgenic pineapple embryogenic callus. Histochemical and quantitative GUS assays demonstrated that the activity of the AcSERK1 upstream regulatory sequence lacking − 921 to -911 or -910 to -880 was signifi cantly reduced in the embryonic callus of the pineapple, and these two regions were needed for the embryonic cell-specifi c. Besides, a promoter lacking − 943 to -922 was shown to signifi cantly increase GUS activity in embryogenic callus, suggesting repressive elements exist in this region. Our data of stable transformation assays confi rmed again the 5’ upstream regulatory sequence (-921 to -880) of the AcSERK1 gene is an essential functional region. Our fi ndings lay the basis for better understanding of the molecular mechanisms of AcSERK1 gene in the regulation in early stage of SE.
Yue Sun,Li Li,Zhihao Chen,Xiaoshuang Yin,Wenzhong Yang,Yun Chen,Ying Liu 한국공업화학회 2022 Journal of Industrial and Engineering Chemistry Vol.115 No.-
The calcium sulfate scale is a common scale in the industrial water system, which is difficult to beremoved by common chemical cleaning methods. In this paper, a new phosphorous free of 1,6-Diaminohexane-contained polyaminoamide dendrimers (PAMAM) scale inhibitor with a threedimensional(3D) branched structure has been developed. The scale inhibition performances of differentgenerations of PAMAM dendrimers (PAMAM-mid, PAMAM-0G, PAMAM-0.5G and PAMAM-1G) are estimatedby the static scale inhibition method. Moreover, the effects of the scale inhibitor concentrationsand solution temperatures on the CaSO4 scale inhibition efficiency are thoroughly discussed. Results indicatethat the PAMAM-mid and PAMAM-0.5G) exhibit excellent inhibition performance on CaSO4 precipitation. Especially, the CaSO4 scale inhibition efficiency of PAMAM-0.5G is above 95% when the dose is10 mg/L, and the corresponding value is almost 100% when the inhibitor dose is 20 mg/L. In addition,the influence of descaling agents on the crystal and morphology of CaSO4 scales are studied by XRDand SEM tests. The results show that the scale inhibition ability of the PAMAM molecules mainly inhibitsthe growth of these crystal planes by adsorption on the surface of the growing crystal. Molecular dynamicssimulation results find that the PAMAM-0.5G dendrimer molecule can energetically interact well withthree crystal planes of calcium sulfate dihydrate. Finally, the simulation results provide a theoreticalguidance to judge the performance of scale inhibitors and synthesize new high-efficiency scale inhibitor.
Yangyang Guo,Bin Xu,Ying Liu,Wenzhong Yang,Xiaoshuang Yin,Yun Chen,Jinxun Le,Zhihao Chen 한국공업화학회 2017 Journal of Industrial and Engineering Chemistry Vol.56 No.-
The ionic liquids, 1-vinyl-3-aminopropylimidazolium hexafluorophosphate ([VAIM][PF6]) and 1-vinyl-3-aminopropylimidazolium tetrafluoroborate ([VAIM][BF4]) acted as the corrosion inhibitors. Weight lossmeasurements showed the corrosion inhibition efficiencies of [VAIM][PF6] and [VAIM][BF4] were 90.53%and 54.01% at 45 C, respectively. The ILs were mix-type inhibitors. Raising the temperature can have adecreased inhibition efficiency of [VAIM][BF4], while [VAIM][PF6] presented an opposite trend. Inaddition, [VAIM][PF6] obeyed Langmuir monolayer adsorption isotherm, while [VAIM][BF4] obeyed EIAwadykinetic-thermodynamic adsorption for blocking active sites. Moreover, Molecular DynamicSimulations showed that [VAIM][PF6] owned a higher adsorption energy, which may be responsible forthe more adsorption groups of [VAIM][PF6].
Influence of Solution Concentrations on Surface Morphology and Wettability of ZnO Thin Films
Jianguo Lv,Changlong Liu,Feng Wang,Zhitao Zhou,Zhenfa Zi,Yuan Feng,Xiaoshuang Chen,Feng Liu,Gang He,Shiwei Shi,Xueping Song,Zhaoqi Sun 대한금속·재료학회 2013 ELECTRONIC MATERIALS LETTERS Vol.9 No.2
ZnO thin films were grown on silicon substrates using a hydrothermal method. The XRD patterns show that all of the peaks can be attributed to the wurtzite structures of ZnO. The TC value of (002) plane and average crystal size increase first and then decrease with the increase of solution concentration. SEM and AFM results show that many dense hexagonal cylinder particles have been observed on the surface of the thin films, which grown at 0.08 and 0.10 mol/L. The surface roughness of the thin films deposited at 0.06,0.08, 0.10, and 0.12 mol/L are 24.5, 38.3, 32.0, and 39.4 nm, respectively. Surface wettability results show that the preferential orientation along c-axis and surface roughness contribute significantly to the hydrophobicity. The reversible switching between hydrophobicity and hydrophilicity is related to the synergy of the transition of wetting model, surface crystal structure, and surface roughness.
Hydroxide MgSn(OH)6: A Promising New Photocatalyst for Methyl Orange Degradation
Jiajia Tao,Zhaoqi Sun,Miao Zhang,Gang He,Xiaoshuang Chen 대한금속·재료학회 2017 ELECTRONIC MATERIALS LETTERS Vol.13 No.4
Highly crystalline hydroxide MgSn(OH)6 (MHS) polyhedral particleswere synthesized by changing reaction time (10, 15 and 20 h) in ahydrothermal process. The structural and morphological poperties ofobtained samples were characterized by X-ray diffraction (XRD),scanning electron microscopy (SEM), and UV-vis diffuse reflectancespectroscopy (DRS). The photocatalytic activity of the MHS wasfurther evaluated by the degradation of methyl orange (MO) underultraviolet (UV) light illumination. Compared with commercial TiO2(Degussa P25), the MHS prepared for 15 h showed similar degradationefficiency of methyl orange (MO), mainly due to its higher specificsurface area (55 m2g−1) and better optical properties.
Facile Synthesis of Zn1-xCuxO Nanorods with a Very Broad Visible Band
Jianguo Lv,Changlong Liu,Wanbing Gong,Zhenfa Zi,Xiaoshuang Chen,Kai Huang,Feng Liu,Tao Wang,Gang He,Xueping Song,Zhaoqi Sun 대한금속·재료학회 2012 ELECTRONIC MATERIALS LETTERS Vol.8 No.5
Zn1-xCuxO nanorods with different Cu concentrations are prepared by a hydrothermal method. Bent and aggregated nanorods are obtained, which is attributed to centripetal surface tension of the evaporation and coagulation processes of the water film on the ZnO nanorods. The broad visible band consists of one violet, three blue,and one green emission. The violet emission is due to the transition of electrons from zinc interstitial (Zni)levels to the valance band. The three blue emissions may be attributed to the transition from extended Zni levels, which are slightly below the simple Zni level, to the valance band. The change of the green emission may be the result of competition between oxygen vacancies (VO) and zinc vacancies (VZn).