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Ahn, Jungmin,Min Kim, Sung,Hwan Noh, Tae,Jung, Ok-Sang Royal Society of Chemistry 2011 Dalton transactions Vol.40 No.34
<P>An unusual “pseudorotaxaned <I>n</I>-alkane within a metalla-cyclodimer” system, C<SUB><I>n</I></SUB>H<SUB>2<I>n</I>+2</SUB>@[(Me<SUB>4</SUB>en)Pd(L)]<SUB>2</SUB>(CF<SUB>3</SUB>SO<SUB>3</SUB>)<SUB>4</SUB> (<I>n</I> = 5, 6, 7; Me<SUB>4</SUB>en = <I>N</I>,<I>N</I>,<I>N</I>′,<I>N</I>′-tetramethylethylenediamine; L = 1,3-bis(4-pyridyl)tetramethyldisiloxane), was constructed. This system is the first pseudorotaxane-type petroleum container achieved <I>via</I> the appropriate size effect.</P> <P>Graphic Abstract</P><P>An unusual “pseudorotaxaned <I>n</I>-alkane within a metallacyclodimer” system as a petroleum container was constructed <I>via</I> the appropriate size effect. <IMG SRC='http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=c1dt10980d'> </P>
Asymmetric Total Synthesis of (+)-Intricenyne via an Endocyclization Route to Oxocane Skeleton
Ahn, Jungmin,Lim, Changjin,Yun, Hwayoung,Kim, Hyun Su,Kwon, Soonbum,Lee, Jeeyeon,Lee, Seungbeom,An, Hongchan,Park, Hyeong-geun,Suh, Young-Ger American Chemical Society 2017 Organic letters Vol.19 No.24
<P>The first total synthesis of (+)-intricenyne consisting of an oxocane skeleton was achieved via an extremely selective endocyclization strategy. The key features of the synthesis include a regio- and diastereoselective epoxide opening reaction, concise elaboration of oxocane cores via abnormally selective endocyclization ether ring formation, and versatile incorporation of the labile functional groups.</P><P><B>Graphic Abstract</B> <IMG SRC='http://pubs.acs.org/appl/literatum/publisher/achs/journals/content/orlef7/2017/orlef7.2017.19.issue-24/acs.orglett.7b03370/production/images/medium/ol-2017-033705_0007.gif'></P><P><A href='http://pubs.acs.org/doi/suppl/10.1021/ol7b03370'>ACS Electronic Supporting Info</A></P>
Ahn Jungmin,Choi Ji Eun,Kang Ju Yong,Choi Ik Joon,Lee Myung-Chul,Lee Byeong-Cheol,Hong Sung Hwa,Moon Il Joon 대한청각학회 2021 Journal of Audiology & Otology Vol.25 No.2
Background and Objectives: Non-linear frequency compression (NLFC) technology compresses and shifts higher frequencies into a lower frequency area that has better residual hearing. Because consonants are uttered in the high-frequency area, NLFC could provide better speech understanding. The aim of this study was to investigate the clinical effectiveness of NLFC technology on the perception of speech and music in patients with high-frequency hearing loss.Subjects and Methods: Twelve participants with high-frequency hearing loss were tested in a counter-balanced order, and had two weeks of daily experience with NLFC set on/off prior to testing. Performance was repeatedly evaluated with consonant tests in quiet and noise environments, speech perception in noise, music perception and acceptableness of sound quality rating tasks. Additionally, two questionnaires (the Abbreviated Profile of Hearing Aid Benefit and the Korean version of the International Outcome Inventory-Hearing Aids) were administered.Results: Consonant and speech perception improved with hearing aids (NLFC on/off conditions), but there was no significant difference between NLFC on and off states. Music perception performances revealed no notable difference among unaided and NLFC on and off states. The benefits and satisfaction ratings between NLFC on and off conditions were also not significantly different, based on questionnaires, however great individual variability preferences were noted.Conclusions: Speech perception as well as music perception both in quiet and noise environments was similar between NLFC on and off states, indicating that real world benefits from NLFC technology may be limited in Korean adult hearing aid users.
양측 급성 음향외상의 임상양상 및 치료결과의 개인별 이질성
안정민 ( Jungmin Ahn ),한지혁 ( Ji Hyuk Han ),배문정 ( Mun Jung Bae ) 국군의무사령부 2020 대한군진의학학술지 Vol.51 No.1
Objective: To analyze individual heterogeneity in susceptibility to noise using within-subject comparison of hearing outcomes following medical therapy for bilateral acute acoustic trauma (AAT). Method: Twelve patients with bilateral hearing loss after gunshot noise exposure during military training were enrolled. Pure tone audiometry, to measure pure-tone averages (PTA) at 2000, 4.000, and 8000 Hz, was performed in all patients at their initial visit and one month after treatment with oral corticosteroids. Results: The initial mean hearing level was 46.67 ± 12.0 dB for the right ear, 52.92 ± 11.15 dB for the left, and 49.79 ± 11.77 dB for both ears. In the 1-month follow-up, the mean PTA was 35.42 ± 15.19 dB for the right ear, 43.06 ± 15.92 dB for the left, and 39.24 ± 15.71 dB for both ears. The difference in PTA between the right and left ears during the initial visit was markedly correlated with the difference in PTA between both ears during the 1-month follow-up (rho = 0.814, р = 0.001). In addition, the average hearing gain on the right side showed a strong correlation with that on the left side (rho = 0.736, p = 0.006). However, there was no relationship between the initial hearing threshold and the degree of hearing gain when both ears were considered together. Conclusion: We detected the positive effects of steroid treatment for AAT and demonstrated clinical evidence of individual susceptibility to acoustic trauma.
GSTARS모형을 이용한 형산강의 최적 유사량공식 결정
안정민(Ahn Jungmin),류시완(Lyu Siwan),이남주(Lee Nam Joo) 대한토목학회 2012 대한토목학회논문집 B Vol.32 No.1B
본 연구에서는 준 2차원 수치모형인 GSTARS를 이용하여 형산강의 하상변동모의에 적합한 최적 유사량공식을 산정하고자 하였다. 모형의 검보정을 위한 유사량, 하상재료 및 하천지형자료를 현장조사를 통해 취득하였다. 현재까지 널리 적용되는 유사량 공식들에 대하여 장기하상변동 모의결과의 실측치에 대한 평균오차, 상대오차, 평균제곱오차, 상대제곱근오차, 불일치율, 그리고 Nash-Sutcliffe 효율계수를 비교한 결과, Laursen(1968)공식이 형산강의 장기하상 변동을 모의하기 위한 가장 적합한 유사량공식으로 판단되었다. Quasi-two dimensional numerical model (GSTARS) was applied to determine the optimal sediment discharge formula for simulating the sedimentologic characteristics of Hyeongsan river. The field measurements have been conducted to obtain the data, such as sediment discharge, bed material, and channel geometry, for model calibration and verification. The sediment discharge formulas, which have been generally used, have been assessed according to the average error, relative error, RMSE, RRMSE, discrepancy ratio and Nash-Sutcliffe efficiency coefficient for bed changes along the thalweg. From the results, Laursen formula(1968) shows the best performance to simulate the long-term bed change of Hyeongsan river.
백천 유역 토지피복 변경에 따른 비점오염 저감효과 분석
안정민 ( Jungmin Ahn ),양득석 ( Dukseok Yang ),신동석 ( Dongseok Shin ),이인정 ( Injung Lee ) 한국농공학회 2016 한국농공학회 학술대회초록집 Vol.2016 No.-
Baekcheon watershed, which is mostly consists of rice paddies and fields, is expected to be higher non-point source pollution impacts. The effect of the non-point source pollution appears fairly large in the tributaries because tributaries are within close proximity to pollution sources unlike the mainstream and the flow rate of tributaries is insufficient. The developed model based on Fortran was applied using input data derived by ARC-GIS in order to analysis quantitatively for the direct runoff and the non-point source pollution load. As a result of the application, we found the contribution rate and the reduction rate for non-point source loading according to change of landuse.
화학사고 초기대응자를 위한 검지관식 탐지장비의 반응성 연구
Ahn, Seung-Young,Kim, Jungmin,Kim, Sungbum,Chun, Kwangsoo,Lee, Jin-Seon,Park, Choonhwa 한국재난정보학회 2014 한국재난정보학회 논문집 Vol.10 No.1
화학사고 발생 시 현장 초기대응자들은 사고 원인물질과 농도를 신속하고 손쉽게 확인하기 위한 방식으로, 미국 환경청(EPA) 초기대응팀에서도 널리 사용하고 있는 직독식 탐지장비를 이용하고 있다. 환경부에서는 검지관식 가스 탐지장비를 직독식 탐지장비로 이용하여 사고 발생 시 현장에서 이용하고 있고, 검지관식 가스탐지기는 신속한 원인 물질 확인과 정밀한 분석 전에 전략적으로 대략적인 오염물질의 정량과 정성을 확인할 수 있는 유용한 장비이다. 그러나 현장 초기대응자들의 직독식 탐지장비의 사용방법에 대한 이해 부족과 단순 수치로만 확인하려는 방식으로 인해 탐지결과의 정확성에 대한 의문점을 늘 제기해 왔다. 본 논문에서는 사고 현장에서 정확한 탐지 결과를 얻기 위해 환경부에서 사용하고 있는 검지관식 가스탐지기인 Kitagawa와 Draeger 탐지기의 물질 반응성을 확인하여 초기 대응자들의 현장 탐지결과의 정확성을 높이고자 하였다. Chemical accidents are the cause of the accident site during the initial responders to quickly and easily see materials and concentration method for the U.S. Environmental Protection Agency(EPA) is widely used in the initial response team direct reading detection equipment used. Ministry of the tubular gas detection equipment to detect direct reading detection equipment used in the event of an accident scene, and shell-and-tube gas detector for rapid detection and identification and precise analysis of causative pollutants before about strategically can identify the quantitative and qualitative useful equipment. However, those who initially respond to the scene of a direct reading detection equipment and a simple lack of understanding of how to use the numbers only because of the way you want to check the accuracy of detection results have been raising questions about the increase. The scene of the accident in order to obtain an accurate detection results used in this paper, the Ministry of Environment of gas detectors detect tubular Kitagawa and Draeger detector tube to check the reactivity of the material on-site detection of early response of those who were to raise the accuracy of the results.