유리폐기물과 하수슬러지 소각재의 고형화 처리연구

한상목,신대용,윤봉구,김승겸 강원대학교 부설 석재복합신소재 제품연구센터 2002 석재연 논문집 Vol.7 No.-

하수슬러지 소각재, 폐유리분말 및 고로슬래그의 고형화에 의하여 건자재를 제조하였다. 하수슬러지 소각재는 SiO_2와 Al_2O_3가 75 wt%, Fe_2O_3가 8.21 wt%, 폐유리분말은 SiO_2 71.4 wt%, Na_2O 14.43 wt% 및 CaO 9.32 wt%, 고로슬래그는 SiO_2 33.4 wt%, CaO 41 wt% 및 Al_2O_3 14.5 wt%를 함유하여 세라믹스 제조원료로 사용이 가능하였다. 하수슬러지를 800℃에서 2시간 하소한 무기질분말을 분쇄하여 하수슬러지 소각재를 제조하였다. 30∼70 wt%의 하수슬러지 소각재, 30∼70 wt%의 폐유리분말 및 10∼30 wt%의 고로슬래그를 혼함하여 950∼1,100℃에서 2시간 소성하여 시편을 제조하였다. 하수슬러지 소각재 첨가량이 감소하고 폐유리분말의 첨가량과 소성온도가 증가하면 부피비중과 압축강도는 증가하였으나 기공률과 흡수율은 감소하였다. 1,050℃에서 소성한 시편(No. 1, 3, 5 및 7)의 부피비중은 1.70∼1.83, 기공률과 흡수율은 0.3∼2.4% 및 0.1∼1.5%, 압축강도 272∼323 kgf/㎠을 나타내었다. 고로슬래그를 첨가하여 1,100℃로 소성한 시편(No. 8, 9, 및 10)의 부피비중은 1.82∼2.11 및 압축강도는 350∼671 kgf/㎠이었다. 하수슬러지 소각재, 고로슬래그 및 시편의 중금속출량은 매립지 침출수배출 허용기준치보다 낮아, 본 연구에서 제조한 시편은 주변 환경에 해가 없어 건자재로의 이용이 가능하였다. An experimental study for the constructional material by solidification using sewage sludge ash, waste glass powder and blast furnace slag was carried out in the senses of waste materials disposal and utilization. The reusability of sewage sludge ash, waste glass powder and blast furnace slag as a raw material in the manufacturing process of ceramics was highly expected because the chemical compositions of these waste materials were mostly SiO_2 and Al_2O_3. Sewage sludge ash was fabricated by calcined at 800℃ for 2 hours and obtained by the crushing. The mixture of 30∼70wt% of sewage sludge ash, 30∼70 wt% of waste glass powder and 10∼30 wt% of blast furnace slag were heated at 950∼1,100℃ for 2 hours. The density and the compressive strength of specimen increased with increasing the sintering temperature and decreasing the addition amount of sewage sludge ash, No. 1, 3, 5 and 7 specimens showed the bulk density of 1.70∼1.83, porosity of 0.3∼2.4%, water absorption of 0.1∼1.5% and compressive strength of 272∼323kgf/㎠. And, that of the No. 7 specimen heated at 1,100℃ increased with increasing the addition amount of blast furnace slag, and for No. 8, 9 and 10 specimens, bulk density was 1.82∼2.11 and compressive strength was 350∼671 kgf/㎠. An extraction test for specimen to detect toxic materials showed below the permitted standard of land-filling extractable heavy metal contents. It was founded that the specimen were useful for the constructional materials.

남자 조마 경기의 기술 빈도에 관한 연구 : '95년 세계 선수권대회와 '97년 세계 선수권대회를 중심으로

한충식,남승구 韓國體育大學校 1998 論文集 Vol.21 No.-

This paper had the following conclusions through comparing and analysing, by groups, the frequence of jumping techniques of athletes advanced to the finals(the 3rd match) in the 95 world Championships and the 97 world Championships. 1. The Vault Group Ⅱ had a increasing tendency in 1997 comparing with in1995, and the techniques of Hdspr. Fwd. and dbl. Salto fwd. t. was remarkably increased. 2. The Vault Group Ⅲ in both Championships showed about 30% of practice frequence. 3. The Vault Group Ⅴ had high frequence of practice frequence untill 1995, while in 1997, had decreasing tendency. It is expected that to make Korean status as a leading country in Vault much higher thing to do is to learn perfectly the technique of group Ⅱ, and that the 2nd and the 3rd Yoe technique has to be developed as further studies.

Layer-by-Layer Doping of Few-Layer Graphene Film

Gü,neş,, Fethullah,Shin, Hyeon-Jin,Biswas, Chandan,Han, Gang Hee,Kim, Eun Sung,Chae, Seung Jin,Choi, Jae-Young,Lee, Young Hee American Chemical Society 2010 ACS NANO Vol.4 No.8

<P>We propose a new method of layer-by-layer (LbL) doping of thin graphene films. Large area monolayer graphene was synthesized on Cu foil by using the chemical vapor deposition method. Each layer was transferred on a polyethylene terephthalate substrate followed by a salt-solution casting, where the whole process was repeated several times to get LbL-doped thin layers. With this method, sheet resistance was significantly decreased up to ∼80% with little sacrifice in transmittance. Unlike samples fabricated by topmost layer doping, our sample shows better environmental stability due to the presence of dominant neutral Au atoms on the surface which was confirmed by angle-resolved X-ray photoelectron spectroscopy. The sheet resistance of the LbL-doped four-layer graphene (11 × 11 cm<SUP>2</SUP>) was 54 Ω/sq at 85% transmittance, which meets the technical target for industrial applications.</P><P><B>Graphic Abstract</B> <IMG SRC='http://pubs.acs.org/appl/literatum/publisher/achs/journals/content/ancac3/2010/ancac3.2010.4.issue-8/nn1008808/production/images/medium/nn-2010-008808_0006.gif'></P><P><A href='http://pubs.acs.org/doi/suppl/10.1021/nn1008808'>ACS Electronic Supporting Info</A></P>

정신과 외래에서 향정신성약물을 복용 중인 환자에서의 하지불편증후군

지구덕,한승희,양명성,양창국 大韓神經精神醫學會 2007 신경정신의학 Vol.46 No.4

Objectives : The purpose ofthis study was to investigate the clinical characteristics and incidence of restless legs syndrome (RLS) in outpatients with psychiatric iltness. Methods : 146 adult patients (male 52, female 94) wcre selected from those who visited a psychiatric outpatient clinic. RLS was evaluated through an interview method using diagnostic criteria and a severity rating scale for RLS developed by the Intemational RLS Study Group (IRLSSG). The authors also applied Beck's Depression Inventory (BDI), Beck's Anxiety Inventory (BAI), the Pittsburgh SleeP Quality Index, Bames Akathisia Rating Scale and neurological examination. Rcsults : Thirty-four (23.3%) among 146 subjects were diagnosed as having RLS. Fifteen (44.1%) among those 34 RLS patients reported to have developed their RLS after starting their psychotropic agents and only 4 patients (11.7%) had Cu-rrently been receiving treatment for their RLS. The RLS group showed higher BDI and BAI scores (p<0.01) and lower sleep quality (p<0.01) compared to those of non-RLS. The RLS group also showed a significantly higher co-morbidity of Pa-rasomnias (χ²=8.5, P<0.01) and peripheral neuropathy (χ²=5.2, P<0.05). Conclusion : The results from this study suggest that a substantial proportion of outpatients with psychiatric illness are suffering RLS. Our data suggest that clinicians should pay attention to the possible presence of RLS among their patients who are taking psychotropic agents.

직장체육 시설의 운영실태에 관한 연구

李漢景,陸調永,南勝久 龍仁大學校 1994 용인대학교 논문집 Vol.10 No.-

The subject were 531 houswives of employees of one company, who answered a questionnair. The main results are as follows ; 1) Sports establishment management in this company encompasses the whole family of employees, especially housewives, club service are synthetically. 2) Subjective conditions such as the urge to do sports, the recognition of the necessity of sports and health conditions, the recognition of the necessity of sports, and Health condition contribute to the sports activities of housewivess, External condition such as the health of the family members, the age of children, and the sports activities of the husbands also are influence. 3) The degree of recognition by housewives, use, and potential use of available sports activities are as follows ; The recognition of Area service was highest, Area users showed the highest degree for this item ; club members showed the highest recognition for program service and club service. Those who seldom participate showed the least recognition for any of the item. The degree of usage was hight for Area service, club members showed the highest degree of usage. 4) Conclusion the degree of recognition was highest followed by the degree of potentional use, and the degree of use, it is left for further study on formulating policies which will improve the of use and the degree of potential use to the level of recognition.

AISI D2강 위에 다층으로 증착된 WC-Ti_(1-X)Al_(X)N 코팅의 국부부식 거동에 관한 연구

안승호,이정호,김호건,김정구,한전건 대한금속재료학회 2003 대한금속·재료학회지 Vol.41 No.9

Multilayered WC-Ti_(1-x)Al_(x)N coatings are characterized by periodically repeated structures of lamellae of WC-Ti/WC-Ti_(1-x)Al_(x)N. WC-Ti_(1-x)Al_(x)N coatings of changing Al concentration were deposited on AISI D2 steel by high-ionization sputtered plasma vapor deposition (PVD). The Al concentration could be controlled by using evaporation source for Al and fixing the evaporating rate of other metals. Four kinds of WC-Ti_(1-x)Al_(x)N coatings were prepared: WC-Ti_(0.6)Al_(0.4)N, WC-Ti_(0.53)Al_(0.47)N, WC-Ti_(0.5)Al_(0.5)N and WC-Ti_(0.43)Al_(0.57)N. The corrosion behavior of WC-Ti_(1-x)Al_(x)N coatings was investigated using electrochemical techniques in deaerated 3.5% NaCl electrolyte (galvanic corrosion test, potentiodynamic polarization test, electrochemical impedance spectroscopy and Mott-Schottky method) and surface analyses (GDOES, SEM and EDS). Particular attention was paid to the effect of growth defects on the coating properties related to the corrosion behavior. The results of the coating and substrate galvanic corrosion test showed low galvanic current densities. In the potentiodynamic polarization test and EIS measurement, the corrosion current density of WC-Ti_(0.5)Al_(0.5)N was lower than others and presented higher R_(ct) values than others after 240 h immersion time. This could be attributed to the formation of a Ti oxide, which promotes partial closing of the defects. Capacitance values obtained from EIS as a function of different potentials (C^(-2) vs E) showed that the oxide layer exhibited an n-type semiconductor behavior.

알렉시딘과 차아염소산나트륨의 화학적 상호반응 후 mass spectrometry를 이용한 파라클로로아닐린의검출 분석

김현식,한승현,오소람,임상민,구유,금기연 大韓齒科保存學會 2010 Restorative Dentistry & Endodontics Vol.35 No.4

근관세척제인 NaOCl과 CHX를 병행 사용하는 경우 적갈색의 발암물질로 알려진 PCA가 생성된다. 본 연구의 목적은 CHX와 유사한 buigunide 계통의 소독제 인 ALX을 NaOCl 과 흔합 반응 시 PCA가 생성되 는지 여부를 mass spectrometry를 이용하여 평가하고자 하였다. 대조군으로는 4% NaOCl 용액과 2% CHX의 혼합용액, 0.5%PCA 용액, 및 1%ALX 용액을 사용하였고 실험군으로는 5가지 농도(1%, 0.5%, 0.25%, 0.125%, 0.0625%)의 ALX 용액과 4% NaOCl의 흔합용액을 질량분석기를 이용하여 mole-cular peak를 분석한 결과 ALX과 NaOCl의 혼합물에서는 PCA(m/w=128)로 보이는 128 피크가 관찰되지 않았다. 또한 용액의 색 변화에서도 ALX이 농도가 높을수록 열은 노랑색을 띄었으나 농도가 낮아질수록 흰색으로 관찰되었으며 어떠한 침전물의 형성도 보이지 않았다. Recent studies demonstrated that the combination of chlorhexidine (CHX) and sodium hypochlorite (NaOCl) resulted in the formation of a precipitate, para-chloroaniline (PCA). Alexdidine (ALX) is a kind of biguanides like CHX, and has stronger detoxification effect against the bacterial virulence factors such as lipoteichoic acid and lipopolysacchardide compared with CHX. The purpose of this study was to determine whether PCA was formed after chemical interaction between ALX and NaOCl using mass spectrometry. Mass spectrometry was performed for the mixture of five different concentrations of ALX (1, 0.5, 0.25, 0.125, 0.0625%) and 4% NaOCl. Results showed that the peak of PCA was not detected in mixed solu tions of ALX and NaOCl in mass spectrometry analysis. The color of mixed solution of ALX and NaOCl after chemical interaction was light yellow to white, but there wasn't any precipitate found.

플라즈마 산화 처리된 65/35황동의 산소 분압별 부식특성에 관한 연구

박창규,안승호,김정구,정윤모,한전건 대한금속재료학회 2005 대한금속·재료학회지 Vol.43 No.4

Brasses are the most widely used copper-based alloys because of the good corrosion resistance, formability, high strength and excellent hot-working properties. However, dezincification occurs when one or more components of an alloy are more susceptible to corrosion than the rest and, as a result, are preferentially dissolved. In order to enhance the corrosion resistance, the oxide film was deposited on the 65/35 brass by pulsed dc plasma oxidation with various pressure. The corrosion behavior of plasma oxidized brasses with various oxygen pressure was investigated by electrochemical methods (potentiodynamic polarization test, potentiostatic test, electrochemical impedance spectroscopy) and surface analyses (x-ray diffraction, scanning electron microscopy, auger electron spectroscopy, electron probe micro analyzer). Particular attention was paid to the effects of oxygen pressure and oxide thickness on the coating properties related to the corrosion behavior. From the results of electrochemical test, it was found that the oxidized brass under condition of 1.5 Torr oxygen pressure was effective in improving corrosion resistance. It was attributed to the protective oxidized layer (ZnO). Finally, an optimized oxidation condition for corrosion protection was found to be 1.5 Torr oxygen pressure and 1 pun thickness. (Received September 3, 2004)

Cu-6Ni-4Sn 합금에서 Cr 첨가에 따른 전기화학적 특성에 관한 연구

박창규,김정구,안승호,한승전 대한금속재료학회 2005 대한금속·재료학회지 Vol.43 No.3

Corrosion characteristics of Cu-6%Ni-4%Sn-x%Cr alloys in a acid-chloride solution (0.1M H₂SO₄+ 0.0056M NaCl) at pH = 6, were studied as a function of chromium addition. Three kinds of Cu-6%Ni-4%Sn-x%Cr alloys were prepared by melting, and casting, followed by thermomechanical treatments. The corrosion behavior of Cu-6%Ni-4%Sn-x%Cr alloys was investigated by electrochemical corrosion tests (potentiodynamic polarization test, electrochemical impedance spectroscopy) and surface analyses (optical microscopy, electron probe micro analysis, scanning electron microscopy). Cr additions were found to prevent the localized corrosion behavior. This is the reason that the small addition of Cr promoted the decomposition behaviors of the supersaturated solid solution a in Cu-6%Ni-4%Sn alloy, i.e., the number of like-Sn-rich carbide impurities (LCI), which increased the galvanic effect between the matrix and the LCI, decreased with increasing the Cr addition. (Received September 8, 2004)

다중 제어루프에 의한 자기부상용 DC-DC 전원장치에 관한 연구

조주현,조정민,전기영,이상집,이승환,오봉환,이훈구,한경희 明知大學校 産業技術硏究所 2004 産業技術硏究所論文集 Vol.23 No.-

The author present a modified multi-loop algorithm including feedforward for controlling a 55kW step down chopper in the power supply of Maglev. The control law for the duty cycle consists of three terms. The first is the feedforward term which compensates for variations in the input voltage. The second term consists of the difference between the slowly moving inductor current and output current. The third term consists of proportional and integral terms involving the perturbation in the output voltage. This perturvation is derived by subtracting the desired output voltage from the actual output voltage. The proportional and integral action stabilizes the system and minimizes output voltage error. In order to verify the validity of the proposed multi-loop controller, simulation study was tried using Matlab simulink.