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Cong Mao,Jie Zhang,Meitian Xiao,Yongjun Liu,Xueqin Zhang 한국물리학회 2018 Current Applied Physics Vol.18 No.12
Mesoporous carbon-silica composites supported Pt nanoparticle catalysts (Pt/MCS) were firstly applied to the heterogeneous asymmetric hydrogenation of ethyl 2-oxo-4-phenylbutyrate (EOPB). A series of different silica contents were investigated in the fabrication of this mesoporous material. When the volume of added tetraethyl orthosilicate (TEOS) during the preparation of composites is 8 mL, Pt/MCS-8 holds carbon and silica as the main components and possesses relatively strong acidity, mesoporous structures with micropores, appropriate Pt nanoparticle size and high dispersibility showing by XRD, XPS, TPD, N2 sorption and TEM. These properties cause its good catalytic performance in the heterogeneous asymmetric hydrogenation of EOPB with the enantiomeric excess value and conversion up to 85.6% and 97.8%, respectively.
Cong-hai Zhang,Sheng-jiao Yan,Sheng-qiang Pan,Rong Huang,Jun Lin 대한화학회 2010 Bulletin of the Korean Chemical Society Vol.31 No.4
A series of novel chiral tert-amino alcohols 4a-h derived from enantiomerically pure phenylalanine were synthesized efficiently and used as chiral ligands in the catalytic enantioselective ethylation of aldehydes with diethylzinc (diethylzinc-to-aldehyde addition). The use of 10 mol % of the amino alcohols led to the corresponding sec-alcohols with excellent enantioselectivities (up to 100% ee) and high yields.
Effect of hybrid fibers on flexural performance of reinforced SCC symmetric inclination beams
Cong Zhang,Zhihua Li,Yining Ding 사단법인 한국계산역학회 2018 Computers and Concrete, An International Journal Vol.22 No.2
In order to evaluate the effect of hybrid fibers on the flexural performance of tunnel segment at room temperature, twelve reinforced self-consolidating concrete (SCC) symmetric inclination beams containing steel fiber, macro polypropylene fiber, micro polypropylene fiber, and their hybridizations were studied under combined loading of flexure and axial compression. The results indicate that the addition of mono steel fiber and hybrid fibers can enhance the ultimate bearing capacity and cracking behavior of tested beams. These improvements can be further enhanced along with increasing the content of steel fiber and macro PP fiber, but reduced with the increase of the reinforcement ratio of beams. The hybrid effect of steel fiber and macro PP fiber was the most obvious. However, the addition of micro PP fibers led to a degradation to the flexural performance of reinforced beams at room temperature. Meanwhile, the hybrid use of steel fiber and micro polypropylene fiber didn’t present an obvious improvement to SCC beams. Compared to micro polypropylene fiber, the macro polypropylene fiber plays a more prominent role on affecting the structural behavior of SCC beams. A calculation method for ultimate bearing capacity of flexural SCC symmetric inclination beams at room temperature by taking appropriate effect of hybrid fibers into consideration was proposed. The prediction results using the proposed model are compared with the experimental data in this study and other literature. The results indicate that the proposed model can estimate the ultimate bearing capacity of SCC symmetric inclination beams containing hybrid fibers subjected to combined action of flexure and axial compression at room temperature.
Adsorption removal of pefloxacin from water by halloysite nanotubes
Cong-Liang Zhang,Shu-Jie Cui,Yan Wang 한국공업화학회 2015 Journal of Industrial and Engineering Chemistry Vol.23 No.-
Batch adsorption experiments were carried out for the removal of pefloxacin from water using halloysite nanotubes as adsorbent. The effects of various parameters such as contact time, initial solution concentration and temperature on the adsorption system were investigated. The optimum contact time was found to be 100 min. The isotherm adsorption data fit well with Freundlich model, and the kinetic data fit well with the pseudo-second order and the intra-particle diffusion model. Intra-particle diffusion analysis demonstrates that pefloxacin diffuses quickly among the particles at the beginning of the adsorption process, and then the diffusion slows down and stabilizes. Thermodynamic parameters such as DG, DH and DS were also calculated. The negative Gibbs free energy change and the positive enthalpy change indicated the spontaneous and endothermic nature of the adsorption, and the positive entropy change indicated that the adsorption process was aided by increased randomness
Application of Kalman Filter to Cricket based Indoor localization system
Cong-Yi Zhang(장총위),Sung-Ho Kim(김성호) 한국지능시스템학회 2008 한국지능시스템학회 학술발표 논문집 Vol.18 No.1
Kalman Filter is an efficient recursive filter that estimates the state of a dynamic system from a series of incomplete and noisy measurement. The filter is very powerful in the field of autonomous and assisted navigation. In this paper, we carry out comparative stduy to validate the performance of the application of Kalman Filter. We will build personal localization system based on Cricket mote, our system can present the real-time position of person when the man with PDA moves around. The proposed system is composed of cricket sensor networks, PDA and host computer. There is one listener attached to the PDA. The PDA will get the distance data from the listener synchronously. It will calculate the position of the person in the coordinate of the Cricket system with the trilateration method. Furthermore, it sends the real-time position information to the host computer by Bluetooth. The host computer will use Kalman Filter to process data and get the final estimated track of the person.
Cong Zhang,Jiangfei Zhou,Zhixin Liu,Yongqing Liu,Kairui Cai,Tengfei Shen,Cheng-Shui Liao,Chen Wang 대한수의학회 2018 Journal of Veterinary Science Vol.19 No.6
The bursa of Fabricius (BF) is a central humoral immune organ unique to birds. Four bursal peptides (BP-I, BP-II, BP-III, and BP-IV) have been isolated and identified from the BF. In this study, the immunoadjuvant activities of BPs I to IV were examined in mice immunized with H9N2 avian influenza virus (AIV) vaccine. The results suggested that BP-I effectively enhanced cell-mediated immune responses, increased the secretion of Th1 (interferon gamma)- and Th2 (interleukin-4)-type cytokines, and induced an improved cytotoxic T-lymphocyte (CTL) response to the H9N2 virus. BP-II mainly elevated specific antibody production, especially neutralizing antibodies, and increased Th1- and Th2-type cytokine secretion. BP-III had no significant effect on antibody production or cell-mediated immune responses compared to those in the control group. A strong immune response at both the humoral and cellular levels was induced by BP-IV. Furthermore, a virus challenge experiment followed by H&E staining revealed that BP-I and BP-II promoted removal of the virus and conferred protection in mouse lungs. BP-IV significantly reduced viral titers and histopathological changes and contributed to protection against H9N2 AIV challenge in mouse lungs. This study further elucidated the immunoadjuvant activities of BPs I to IV, providing a novel insight into immunoadjuvants for use in vaccine design.
“Circe”: Joycean-Deleuzian Chaosmos
( Cong Zhang ),( Kelin Li ) 한국제임스조이스학회 2021 제임스조이스저널 Vol.27 No.2
James Joyce, as a clinician of his nation, employs symptomatology to expose the problems of the Irish people, thereby attempting to cure the Irish national malady which he calls “spiritual paralysis.” All his works can be regarded as such a remedy for this malady by way of enhancing the virtual power of an impersonal and nonorganic life, a life replacing the world of stagnancy and closure with a chaosmos of difference and becoming, and thus more possibility and vitality. In “Circe,” this is achieved first through the becoming-woman of Bloom, which singularizes Bloom out of the Irish majority. With it, all of “Circe” is involved in a block of becoming, disrupting all established logics and values so that Stephen Dedalus’s denial to his mother becomes a denial to all authoritarian control. The affirmative power endowing on Bloom’s becoming-woman then reconstructs “Circe” as a chaosmos where all possibilities of life occur, in which a true liberation of the Irish people can be imagined.
Zhang, Cong-Hai,Yan, Sheng-Jiao,Pan, Sheng-Qiang,Huang, Rong,Lin, Jun Korean Chemical Society 2010 Bulletin of the Korean Chemical Society Vol.31 No.4
A series of novel chiral tert-amino alcohols 4a-h derived from enantiomerically pure phenylalanine were synthesized efficiently and used as chiral ligands in the catalytic enantioselective ethylation of aldehydes with diethylzinc (diethylzinc-to-aldehyde addition). The use of 10 mol % of the amino alcohols led to the corresponding sec-alcohols with excellent enantioselectivities (up to 100% ee) and high yields.