악틴 및 란탄족금속의 거대고리 착물 (제 1 보). 거대고리 리간드의 금속착물의 형성과 성질

정오진,최칠남,윤석진,손연수,Jeong, O Jin,Choe, Chil Nam,Yun, Seok Jin,Son, Yeon Su 대한화학회 1990 대한화학회지 Vol.34 No.2

본 연구에서는 동공의 크기가 다른 5종의 crown ether과 9종의 crownand계와 1종의 cryptand계 거대고리 리간드를 포함하는 우라늄(Ⅵ), 토륨(Ⅳ) 및 네오디뮴(Ⅲ), 사마륨(Ⅲ), 홀뮴(Ⅲ) 등의 희토류 금속착물을 합성 후, 고체착물의 조성식을 결정하고 적외선 스펙트럼에 의하여 구조를 확인한 다음 핵자기공명 분광법에 의하여 착물용액의 조성비와 분자내의 착물형성 site를 결정하고 착물들의 용매화 현상과 리간드 교환반응성을 핵자기공명 분광법으로 고찰하였다. crown ether 거대고리 리간드들은 실험에 사용한 모든 금속이온과 안정한 착물을 형성하므로 OCH2 메틸렌 양성자들은 모두 낮은 자기장 방향으로 화학적 이동을 나타냈으며 같은 금속이온에 대한 화학적 이동값은 12C4<15C5<18C6의 순으로 증가하였고 같은 리간드에 대한 희토류 착물의 화학적 이동값은 원자번호 크기에 반비례하였다. crownand 22는 우라늄(Ⅵ)과 산소 및 질소원자를 배위하는 안정한 착물을 형성하지만 희토류 금속과는 착물을 형성하지 않았다. 반면에 희토류 금속(Ⅲ)이온은 cryptand 221리간드와 모든 산소 및 질소원자를 배위자로 하는 안정한 착물을 형성할 수 있었다. 나머지 질소와 산소원자를 포함한 crownand 계열 거대고리 리간드는 우라늄(Ⅵ)과 역시 모든 산소 및 질소가 배위하는 착물을 형성하지만 희토류 금속(Ⅲ)과는 착물을 형성하지 않음을 확인할 수 가 있었다. 우라늄(Ⅵ)과 희토류(Ⅲ)금속이온은 모든 거대고리 리간드와 1:1착물을 각각 형성하며 토륨(Ⅳ)이온은 12C4와 1:2 나머지 리간드와는 1:1착물을 각각 형성함을 알 수 있었다. 이들 거대고리 리간드 착물들의 안정성은 착물의 양성자 이동결과에 잘 일치하였다. 그리고 18C6와 물을 리간드로 하는 희토류 금속(Ⅲ) 착물은 아세틸아세톤 용매내에서 리간드 교환반응이 일어나지만 우라늄(Ⅵ)착물의 경우에는 교환반응이 일어나지 않았다. Metal complexes were prepared by reacting uranium (Ⅵ), thorium (Ⅳ) and rare earth metal (Ⅲ) ions including Nd (Ⅲ), Sm (Ⅲ) and Ho (Ⅲ) with macrocyclic ligands including five crown ethers, nine crownands and one cryptand ligands, and subjected to NMR studies in order to examine coordination sites of the ligands and compositions of the complexes formed. Among the marcocyclic ligands, crown ethers and crownand ligands have shown down-field shifts of the methylene protons of the lcigands by forming stable complexes with all the metal ions and the differences of chemical shifts were decreased as increasing of the cavity-size of crown ethers for the same metal ions and decreasing of the atomic number of the rare earth metals for the same ligands. It has been found that crownand 22 gave a stable complex with uranium(Ⅵ) ion by the coordination through both oxygen and nitrogen atoms of the ligand whereas no complex was formed with the rare earth metal(Ⅲ) ions, which on the other hand were found to form stable complexes with cryptand 221. The rest of the crowand ligands have also been found to form stable complexes with uranium(Ⅵ) ion by coordinating through all the oxygen and nitrogen atoms of the ligands whereas no complexes were formed with the rare earth metal(Ⅲ) ions. It has also been shown by 1H-NMR study that uranium(Ⅵ), thorium(Ⅳ) and rare earth metal(Ⅲ) ions formed 1:1 complexes with the macrocyclic ligands except for thorium(Ⅳ) complex of 12C4 in which the mole ratio of metal to ligand is 1:2. More stable metal complexes show larger changes in chemical shifts of the coordinated ligand protons. Finally, the rare earth metal(Ⅲ) complexes of 18C6 have shown ligand exchange reaction with the solvent molecules in acetylacetone solution, which was not observed for the uranium (Ⅵ) complexes.

딥러닝 기반 뉴스 추천 시스템

전현식(Hyunsik Jeon),김종진(Jongjin Kim),강유(U Kang) 한국정보과학회 2021 정보과학회지 Vol.39 No.3

Synergistic Effect on the Photocatalytic Degradation of 2-Chlorophenol Using $TiO_2$Thin Films Doped with Some Transition Metals in Water

정오진,Jeong, O Jin Korean Chemical Society 2001 Bulletin of the Korean Chemical Society Vol.22 No.11

The metallorganic chemical vapor deposition (MOCVD) method has been used to prepare TiO2 thin films for the degradation of hazardous organic compounds, such as 2-chlorophenol (2-CP). The effect of supporting materials and metal doping on the photocatalytic activity of TiO2 thin films also has been studied. TiO2 thin films were coated onto various supporting materials, including stainless steel cloth(SS), quartz glass tube (QGT), and silica gel (SG). Transition metals, such as Pd(II), Pt(IV), Nd(III) and Fe(III), were doped onto TiO2 thin film. The results indicate that Nd(Ⅲ) doping improves the photodegradation of 2-CP. Among all supporting materials studied, SS(37 ${\mu}m)$ appears to be the best support. An optimal amount of doping material at 1.0 percent (w/w) of TiO2-substrate thin film gives the best photodegration of 2-CP.

희토류금속 분리 및 회수를 위한 분석화학적 연구 (제1보) : 우라늄(VI)의 분리회수를 위한 선택이온교환수지 합성과 우라늄(VI) 금속이온의 흡착특성

정오진,정학진,김준태,Jung Oh Jin,Hak Jin Jung,Joon Tea Kim 대한화학회 1988 대한화학회지 Vol.32 No.4

클로로메칠화된 스틸렌, 1,4-디비닐벤젠과 동공의 크기를 달리한 여러가지 거대고리화합물을 개시제로 하여 공중합법에 의하여 1%, 2%, 4% 및 10%의 다리결합도를 가진 새로운 이온교환수지를 합성하였다. 그리고 이들 수지에 대한 우라늄(VI), 구리(II), 및 희토류(III) 금속에 대한 흡착특성을 검토하였다. 이 수지들은 강산, 강염기 및 열에 대해서 안정하였으며 pH 4.0이상에서는 $UO_2^{+2}$의 흡착력이 증가하였다. U(Ⅵ)금속이온의 최적흡착시간은 20분이상이였으며 금속이온흡착력은 수지의 다리결합도와 흡착시 사용한 용액의 유전상수크기에 반비례하였다. 그리고 1% 다리결합도수지의 $UO_2^{2+}$이온에 대한 겉보기 용량이 가장 크게 났으며 U(VI)금속이온은 희토류(III)금속이온에 대하여 선택성을 보였다. Several new ion exchange resins have been synthesized from chloromethyl styrene-1,4-divinylbenzene(DVB) with 1%, 2%, 4%, and 10%-crosslinking and macrocyclic ligands of cryptand type by interpolymerization method. The adsorption characteristics and the pH, time, solvents and concentration dependence of the adsorption of metal ions by this resin were studied. The correlation between the separation characteristics of uranium, rare earths and transition metal on the resins and the stability constants of complexes with macrocyclic ligands have been examined. The resins were very stable in both acidic and basic media and have good resistance to heat at $280^{\circ}C$. The $UO_2^{+2}$ aqueous solution are not adsorbed on the resins below pH 3.0, but the power of adsorption of $UO_2^{2+}$ increased rapidly above pH 4.0. The optimum equilibrium time for adsorption of metallic ions was twenty minutes and adsorptive power decreased in proportion to crosslinking size of the resins and order of dielectric constants of solvents used and the selective sequence for metal cations is in the order of $UO_2^{2+},\;Cu^{2+}\;and\;Nd^{3+}$.

D.L-Mandelato Zirconium(Ⅳ) Complex의 物理的 特性과 加熱條件에 따른 構造變化

丁梧鎭,조경호,문경찬 조선대학교 기초과학연구소 1983 自然科學硏究 Vol.6 No.1

The dl-monomandelate zirconium(Ⅳ) and dl-tetramandelato zirconium(Ⅳ) complexes were synthesized from ZrOCl_2, 8H_2O and it was identified by UV-spectrum, IR-spectrum and element analysis, respectively. These transitional state and determination of structures according to heating curves were identified by aalytical methods of electron microphotograp and X-ray diffractiometry. The results obtained are as follows: 1) The dl-monomandelato zirconium(Ⅳ) complex obtained from the result of elements analysis for complexes synthesized was analyzed; H=3.60%, C=37.66% and Zr=31.03%. respectively and the dl-tetramandelato zirconium(Ⅳ) complex; H=4.153% C=55.23% and Zr=13.09%, respectively. 2) The dl-tetramandelato zirconium(Ⅳ) complexes were appeared with symmetric carbonyl streching mode from 1500 to 1700㎝^-1 and this symmetric carbonyl streching mode means the presense of coordinate bonding between Zr and carboxylic radical. 3) The mode of dl-monomandelato zirconium(Ⅳ) complex has asymmetrical peak, and this means the state for coordinate bonding of Zr-coo-but dl-tetramandelato zirconium(Ⅳ) complexes have symmetric peak in the range of 1000 to 1500㎝^-1 and this peak means the presence of more than one kind of zirconium carboxyl bond. 4) The dl-mono and tetramandelato zirconium(Ⅳ) complexes are formed in rtrong absorption band at 1360㎝^-1, and this values are shifted with respect to 1385㎝^-1 of the dl-mandelic acid, and complex compound synthesized from state of acetonitrile solution, is formed with strong carboxyl(vsy) band of absorption at 1360㎝^-1 and 1650㎝^-1, respectively. 5) The vcoo(sy) band of absorption at 1360~1385㎝^-1 range means to be eight coordinate complex and frequency of this range have vcoo characterics of structure. The weak band of absorption of the 2700㎝^-1 show the structure of coordinate bonding and this band have the typical harmonic vibration structure of O-H-O bonding. 6) The dl-mandelato zirconium(Ⅳ) complex in NH_4OH solution exhibits the maximum absorbany at 255mm. The maximum molar absorptivity of^-4 M dl-mono and tetramandelato zirconium(Ⅳ) complex have 0.54×10^4 and 1.2×10^4, respectively. 7) The white products (synthetic complex) precipitated from aqueous solution is polymeric with hydrogen bonding and this complexes are also insoluble in organic solvent as C_6H_6, C_2H_5OH, DMSO, and CH_3OHㆍㆍㆍetc. but is soluble in NH_4OH 8) The dl-mono and tetramandelato zirconium(Ⅳ) complex exhibit the endothermic peak of dehydration at 218.75℃ and 209.4℃, respectively. and exhibit the exothermic peak of decomposition for H_2O and CO at below 600℃ and 1050℃ in air calcination, respectively. 9) The synthetic complexes are formed with exothermic peaks transed from ZrO_2-monoclinic system to ZrO_2-tetragonal system at 1250℃ in air calcination. 10) The synthetic complexes have amorphous at below 110℃, and are appeared with ZrO_2-monoclinic systems in air calcination, respectively. If synthetic complexes are heated at 970℃ and 110℃ in air calcination, respectively. The clear crystalline structures of ZrO_2-monoclinic system are identified by X-ray diffractiometry and analytical method of electron microscope. and intensities of X-ray diffraction patterns are increased more trikis complex compound than mono complex.

陰 Ion 交換樹脂에 依한 稀土類元素의 溶離行動에 關한 硏究

정오진,김일두,이계수,차기원,Oh Jin Jung,Il Doo Kim,Gyou Soo Lee,Ki-Won Cha 대한화학회 1984 대한화학회지 Vol.28 No.1

DTPA 용리액의 pH와 농도를 변화시키면서 음이온 교환수지관을 이용해서 희토류 원소들을 분리하는 연구를 하였다. 희토류 원소들의 가장 좋은 분리조건은 0.025M DTPA, pH 8.35이 있었으며 희토류 원소들의 용리순서는 Sm을 제외하고 희토류 원소들의 원자번호 순서와 일치하였다. 0.025M DTPA, pH 8.35에서 분리한 인접 희토류 원소들의 분리값은 3.03~1.25이었으며 그중 Ce/Pr이 3.03으로 최대값을,Eu/Gd은 최소값을 각각 갖는다. 0.025M DTPA 희토류 원소들을 용리하였을 때, pH 8.0~8.6의 넓은 범위에서 비교적 좋은 분리현상을 보였다. The separation of the rare earth elements with diethylene triamine N, N, N', N', N"-pentaacetic acid (DTPA) as eluent was carried out at different pH and concentrations by using anion exchange resin column. The rare earth elements were absorbed on the upper of the resin column and the best condition of the separation behavior was 0.025M of DTPA at pH 8.35. The elution order of the rare earths was in the order of the atomic number of the rare earth elements except samarium. The resolution of adjacent rare earth elements that have been separated with 0.025M-DTPA as eluent, was from 3.03 to 1.25 at pH 8.35. Resolution of Ce-Pr was maximum value in 3.03 and Eu-Gd was minimum in 1.25 at condition mentioned above, respectively. The resolution of rare earth elements separated with 0.025M DTPA eluent was very good at pH range of 8.0~8.6.

DBC-희토류금속들의 거대고리 착물형성에 관한 연구

정오진,송기둥,김호두,이용두 조선대학교 기초과학연구소 1985 自然科學硏究 Vol.8 No.1

The macrocyclic ligands of the dibenzo-18-crown-S(DBC) was synthesized from pyrocatechol and bis 1.1-dibromo ethane. The determination of stability constant, mole ratio, melting point and structure of solid type land calculation of thermodynamic function (△S, △H) of DBC complexes were investigated. The compound of DBC ligands with nitrate salt of rare earth element was formed 1 : 1 complexes as mole ratio in N, N-dimethyformamide. From those results, it was found that stability constant of the complexes with affects on the kind of anions. The stability constant and melting point of these complexes formed were 4.95 and 298℃ respectively.

光州地方의 土壤과 水分의 有機鹽素劑 殘留 濃度에 關한 硏究

丁梧鎭 朝鮮大學校 1977 綜合論文集 Vol.1977 No.-

In this paper, gas chromatographic determination was made on the residual concentration of organochlorine pesticides of soils and water collected from Kwangju area from March 1976 to October 1976 Having the samples been absorbed with Florisil (60~100mesh) and Wakogel S-1 (60~80mash), then pretreated with n-hexane, dichloromethane and nitril acetate (5:2:1) and the concentration of the organochlorine pesticides was detected by gas chromatogram of Gas Chromatograph (Hitachi Model 063) equiped with ??Ni-E.C.D The results obtained are 1. The absorption ratio and the collection ratio of the residual organochlorine pesticides were above 90% respectively. 2. In the soil more organochloride was detected than in water. 3. The residaul concentration of pesticides was the maximum from July to November and the least from March to May. 4. α-BHC was the most abundant in the ratio of each BHC isomer to the total BHC. γ-BHC the next then β-BHC and δ-BHC.

특집 EPR제도 시행 -EPR제도 도입 운영방안

정오진 (사)한국포장협회 2002 包裝界 Vol.106 No.-

Destruction of 2-Chloriphenol from Wastewater and Investigation of By-products by Ozonation

정오진,Jeong, O Jin Korean Chemical Society 2001 Bulletin of the Korean Chemical Society Vol.22 No.8

This study investigates the ozonation kinetics of 2-chlorophenol in wastewater under acidic condition. Intermediates and by-products generated during the process were rigorously identified and quantified. The major by-products are four carboxylic acids: tartaric acid, oxalic acid, maleic acid, and hydroxymalonic acid. The generation of these organic acids is in agreement with theoretical predictions. But hydroxylated compounds are more favorable to produce than their corresponding non-hydroxylated ones. Based on the information concerning the generation of organic acids and other aromatic intermediates, the complete reaction pathways toward mineralization can be proposed and mathematically modeled. The fitted second-order rate constants are in the same order of magnitude with the results from other studies. Using these oxidation pathways and the corresponding kinetic model, by-products generated in ozonation process can be predicted. This can help in optimizing the design and operation of any subsequent treatment processes.