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Duffy 방법을 이용한 임의 형상 도체의 전자파 산란 해석
이승학,김채영,이창원 한국전자파학회 2002 한국전자파학회논문지 Vol.13 No.8
임의 모양의 완전도체의 전자파 산란을 해석하기 위하여 모멘트 방법을 이용하였다. GID(Graphic Interface Design)툴을 이용하여 설계된 금속 도체의 표면은 서로 다른 모양의 삼각패치로 모델링 되었다. 도체 표면전류는 삼각패치의 벡터 기저함수로 확장되었다. 관측점과 전원점이 동일 삼각패치에 위치할 때, 삼각패치의 특이점 적분은 Duffy 방법을 이용하여 특이점이 없는 적분으로 변환이 가능하였고, 변환된 특이점 항들은 1차원의 가우시안 구적법을 이용하여 간단하게 계산되어질 수 있었다. 특이점을 제외한 적분들은 2차원 가우시안 구적법으로 계산되었다. The method of moment is applied to the analysis of electromagnetic scattering from an arbitrarily-shaped conductor. The conducting surface is discretized into triangular patches using a GID tool. Surface currents on a conductor are expanded with a vector triangle basis function. By using the Duffy's method, the singular integration appeared in a triangle patch can be transformed into the non-singular integral form suitable for one dimensional Gaussian quadrature integration method. Mutual and self integration extracted singular terms are evaluated by two dimensional Gaussian quadrature techniques.
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이승학,김문경,한용해,심창구,Lee, Sung-Hack,Kim, Moon-Kyoung,Han, Yong-Hae,Shim, Chang-Koo 한국약제학회 1994 Journal of Pharmaceutical Investigation Vol.24 No.3
In the present study, quantitative and qualitative histology was used to assess the effects of ibuprofen suppositories with various treatments on the rectal mucosa of rats. Two suppositories were prepared with Witepsol W35 and compared with two commercial ibuprofen suppositories Reference I (Showa Pharm.ind., Tokyo, Japan), Reference II (P.Pharm., Seoul, Korea). Single and multiple dose(dosing interval 4 hr, n=4) studies were conducted. All suppositories significantly increased epithelial cell loss, but the extent of rectal irritation was variable. These studies showed that the incorporation of ibuprofen into the suppository bases increases the morphological change in rectal tissue both for the single and multiple administrations of suppositories, but which was significantly recovered within 24 hr although the interanimal variability in scores was very substantial. Multiple administration of ibuprofen suppositories caused significant damage to rectal mucosa, but it must be considered that these were under the severe condition, that is, interval of administration (4 hr) was three times shorter than normal interval of administration and dose was fifteen times larger than usual human dose. Aluminum oxide $(Al_2O_3)$, a dispersing agent, slightly increased the irritation of rectal mucosa in rats at 5 hr and 24 hr after multiple administration, but it was possible to ignore the difference of irritation in the data at 5hr and 24hr after single administration. Finally, it was concluded that Witepsol W35 and ibuprofen had a slight rectal mucosa-irritating effect on the usual human dose, and ibuprofen suppositories prepared with Witepsol W35 or Witepsol W35, $Al_2O_3$ showed almost similar extent of rectal irritation with commercial ibuprofen products.
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Nitrate Reduction without Ammonium Release using Fe-loaded Zeolite
이승학,이성수,박준범,이광훈 한국지하수토양환경학회 2005 지하수토양환경 Vol.10 No.1
Nitrate reduction with zero valent iron (Fe0) has been extensively studied, but the proper treatment for ammonium by-product has not been reported yet. In groundwater, however, ammonium is regarded as contaminant species, and particularly, its acceptable level is regulated to 0.5 mg-N/L for drinking water. This study is focused on developing new material to reduce nitrate and properly remove ammonium by-products. A new material, Fe-loaded zeolite, is derived from zeolite modified by Fe(II) chloride followed by reduction with sodium borohydride. Batch experiments were performed without buffer at two different pH to evaluate the removal efficiency of Fe-loaded zeolite. After 80 hr reaction time, Fe-loaded zeolite showed about 60% nitrate removal at initial pH of 3.3 and 40% at pH of 6 with no ammonium release. Although iron filing showed higher removal efficiency than Fe-loaded zeolite at each pH, it released a considerable amount of ammonium stoichiometrically equivalent to that of reduced nitrate. In terms of nitrogen species including NO3-N and NH4+ - N, Fe-loaded zeolite removed about 60% and 40% of nitrogen in residual solution at initial pH of 3.3 and 6, respectively, while the removal efficiency of iron filing was negligible. 영가 철을 이용한 질산성 질소 환원에 대한 연구는 지금까지 활발히 진행되어 왔지만, 이 반응에서 생성된 암모늄 부산물에 대한 적절한 처리과정은 아직 보고되지 않았다. 하지만, 암모늄은 먹는 물 수질기준에 의해 지하수 오염물로 분류되고 있어 (허용치 0.5 mg-N/L), 질산성 질소로 오염된 지하수 정화에 영가 철을 단독으로 사용하는 것에는 한계가 있다. 따라서, 본 연구의 목적은 질산성 질소를 환원함과 동시에 이 과정에서 발생하는 암모늄을 제거할 수 있는 반응물질을 개발하는데 있다. 본 연구에 사용한 Fe-loaded zeolite는, 제올라이트와 Fe(II) 용액을 교반시켜 제올라이트 구조 안으로 Fe(II)를 흡착유도하고, 이를 sodium borohydride로 환원하는 과정을 통해 제작되었다. Fe-loaded zeolite 제작에 사용된 Fe(II) 용액의 농도를 실험을 통해 산정하고, 이를 통해 Fe-loaded zeolite를 제작한 후, Fe-loaded zeolite의 질산성 질소 제거 성능을 확인하기 위해 두 가지 pH 조건에서 회분식 실험을 수행하였다. 80시간의 반응을 통해 Fe-loaded zeolite는 초기 pH가 3.3 인 경우 약 60%의 질산성 질소를, pH가 6인 경우는 약 40%의 질산성 질소를 제거하였고, 암모늄 부산물은 전혀 검출되지 않았다. 영가 철의 경우, 각 초기 pH 조건에서 Fe-loaded zeolite 보다 뛰어난 질산성 질소 제거성능을 보였지만, 반응 후 상당량의 암모늄 부산물을 생성하였다. 질산성 질소와 암모늄을 포함한 질소(-N)제거 효능의 관점에서 Fe-loaded zeolite의 경우 pH 3.3과 6의 경우에서 각각 60%와 40%의 제거효율을 보인 반면, 영가 철의 제거효율은 무시할만한 수준으로 나타났다.
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이승학,송형용,김동건,임성욱,박은영,현규 한국고분자학회 2017 Macromolecular Research Vol.25 No.4
The effects of the curing and blowing agent concentration in an epoxy resin were investigated using rheological, mechanical, and optical methods. The curing time from the time sweep test decreased with increasing amount of curing agent at the fixed blowing agent concentration. On the other hand, with increasing blowing agent at a fixed curing agent concentration, the curing time showed a local minimum value. Minimization of the curing time is very useful for reducing the processing time. Axial normal forces as a function of time showed a relationship between the contraction force by the curing process and the expansion force by foaming process. From the axial normal force measurements, it could be categorized quantitatively into three parts: the curing dominant region (negative axial normal force development), transition region, and the foaming dominant region (positive axial normal force development). At the transition region, the axial normal force development was delayed because the foaming process was disturbed by the contraction. Mechanical and structural analysis were conducted for the fully cured and foamed epoxy resin. The completely developed epoxy foams with the high curing agent concentration become brittle. On the other hand, they contained well-distributed unit cell foams inside. This is because the fast curing process interrupts the coalescence of the closed foams. Overall, the optimal curing and blowing agent concentration for the epoxy resin could be determined from rheological analysis during the process and mechanical and structural analysis for fully cured and foamed epoxy resin.
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