생물학적 유동층을 이용한 합성폐수의 질산화 반응

김환기,정우철,이복열 한국화학공학회 1986 Korean Chemical Engineering Research(HWAHAK KONGHA Vol.24 No.5

본 연구는 폐하수중에 포함된 질소성분 제거에 관한 기초연구로서 주로 질산화 반응에 관한 것이다. 실험에 사용한 시료는 정화조 유출수와 유사한 합성폐수를 사용하였고 질산화 반응이 단계적으로 일어날 것을 고려하여 4단계 생물학적 유동층 반응기(Biological Fluidized Bed Reactor)를 고안하였으며 이 반응기를 이용하여 질산화 반응의 가능성을 검토하였다. 그 결과 질산화 반응은 후기단계에서 88∼97%의 NH^+₄ - N이 제거됨으로써 본 4단계 생물학적 유동층 반응기는 질산화 반응에 매우 합리적이었다. 또한 유동층 반응기내의 유체 흐름형태는 적정 순환비가 30정도로서 완전 혼합류로 고려된다. 질산화 반응의 속도론적 해석으로 유기물 제거속도는 질산화 반응속도의 3배로 나타났으며 동시에 산소에 의한 미생물 생성의 Kinetics도 검토하였다. A basic study is done on the biological nitrification for the removal of nitrogenous components from synthetic wastewater. The composition of synthetic wastewater is similar to a typical septic tank effluent containing a considerable amount of nitrogenous compounds. As nitrification process is supposed to be step reactions, 4 Biological Fluidized Bed Reactors are prepared. Thus the feasibility of this nitrogen treatment is discussed as follows. The results obtained showes that as the nitrification process proceeded, 88 to 97% of the NH^+₄-N was removed in the latter stages. Thus the 4 stage Fluidized Bed Reactors proved to be very good in nitrification. The flow pattern resulted in the complete mixing in each stage when the recycle ratio was about 30. The kinetic analysis of the nitrification reaction showed that the organic removal rate was faster than the nitrification rate by three times, and the kinetics of microorganism formation by oxygen is discussed also.

茂朱 南大川 上流水系 汚染이 本流의 水質에 미치는 影響에 關한 硏究

金煥基,崔頭炯,韓雄在 全北大學校 附設 都市및環境硏究所 1996 都市 및 環境硏究 Vol.11 No.1

This study was investigated for the pollution load of water quality in the basin of Wondangchon. Total pollution load was measured that BOD was 683.6 ㎏/day, SS was 1,436.184 ㎏/day, T-N was 237.244 ㎏/day, and T-P was 62.078 ㎏/day respectively inthere. Furthermore, it was estimated that BOD is 1,056.863 ㎏/day, SS is 1,840.657 ㎏/day, T-N is 299,922 ㎏/day, and T-P is 74.154 ㎏/day respectively in 2006 year. In case of BOD loading, that by population accounted for 63% of all BOD loading of that, 57% was discharged in M-4 drainage area. However, since tourists have been increasing gradually, that by population was estimated to be analogous to that by tourists in 2006 year. In case of SS loading, that by livestock was bigger than that by population by holding for 49% of all SS loading, and that by tourists was 9.8% now, however, ratio of that by tourists was estimated to be increased up to 25.8% in 2006 year. In case of T-N loading, that from wastewater treatment plant located in M-1 drainage area was the biggest by accounting for 56.2%. In case of T-P loading, that by livestock discharged form M-4 drainage area accounted for 44.3% of all T-P loading, and ratio of both of that by tourists and that from wastewater treatment plant gradually was estimated to be increased From above results, showing yearly change in pollution load of each water quality items is estimated to be increased continuously in every items, and in the influence of the pollution load of each drainage area upon Muju Namdaechon, M-4 drainage area was the biggest by accounting for 45% of total pollution load, and nest was ordered to M-1, M-2, M-3 and polltion load from wastewater treatment plant. The water quality of Namdaechon in Muju influenced by the study area was in the result of BOD 17.7%, SS 13.0%, T-N 28.2% and T-P 22.9%.

간접폭기식(間接曝氣式) 생물학적(生物學的) 유동층(流動層)을 이용한 합성하수(合成下水) 처리(處理)

김환기,이기완,Kim, Hwan Gi,Lee, Ki Wan 대한토목학회 1987 대한토목학회논문집 Vol.7 No.3

본(本) 연구(硏究)에서는 생물학적(生物學的) 유동층(流動層)에서의 산소전달(酸素傳達) 능력(能力)을 향상(向上)시키기 위하여 에어리프트를 이용(利用)한 간접폭기방식(間接曝氣方式)을 채택(採擇)하고, 이에 따른 생물학적(生物學的) 유동층(流動層)에서의 산소전달(酸素傳達), BVS변화(變化)와 메디아 유동특성(流動特性), 기질제거(基質除去)와 산소이용(酸素利用)과의 관계 등을 검토(檢討)하였다. 실험(實驗)은, 생물학적(生物學的) 유동층(流動層)의 메디아로서 합성섬유(合成纖維) 부섬포(不纖布)를 사용(使用)하였고 합성하수(合成下水)에 대하여 $20^{\circ}C$를 유지(維持)한 연속식(連續式) 반응조(反應槽)로 수행(修行)되었다. 실험(實驗) 결과(結果), 에어리프트를 이용(利用)한 간접폭기(間接曝氣)는 산소전달면(酸素傳達面)에서 유동층(流動層)의 직접(直接) 폭기(曝氣)에 의한 산소공급(酸素供給) 방식(方式)보다 효과적(?果的)임을 알 수 있었고 메디아의 한계부착(限界附着) 미생물농도(微生物濃度)는 20~23g/l의 범위로 나타냈으며 생물학적(生物學的) 유동층(流動層) 반응조(反應槽)에 케이지를 적용(適用)하면, 유동층(流動層)의 균등(均等)한 미생물(微生物) 농도(濃度) 유지(維持)는 물론 메디아의 유동특성(流動特性)도 향상(向上)시킬 수 있는 것으로 나타났다. 또한, F/M비(比) 0.36~0.73까지의 부하변동(負荷變動)에도 91% 이상(以上)의 BOD 제거율(除去率)이 유지(維持)됨으로써 부하변동(負荷變動)에 따른 적응력(適應力)이 양호(良好)함을 확인(確認)할 수 있었고 BVS농도(濃度) 15~20g/l에서의 산소비섭취율(酸素比攝取率)($K_r$)은 $0.23{\sim}0.26gO_2/g\;VSS{\cdot}day$로 나타났다. To improve the ability of oxygen transfer in Biological Fluidised Bed(BFB) processes, air lift aeration system was introduced, experimental investigations were performed for the oxygen transfer in reactor, the fluidisation as to Biomass Volatile Solids variation and the relationship between substrate removal rate and oxygen utilization. The experiments for this purpose were executed for the synthetic wastewater by continuous type reactor at $20^{\circ}C$ using reticulated polypropylene sheets as media. The obtained results showed that the oxygen transfer by air lift aeration would be more effective than any other aeration systems used in BFB reactor. Also, it has observed that the critical biomass concentration in reactor took a range of 20 to 23g/l. Applying cages to BFB reactor, biomass would be maintained uniformly in the bed and the fluidisation characteristics of media could be improved. Varying F/M ratio from 0.36 to 0.73, BOD removals were 91% or more. Therefore, this process was suited to the treatment of which F/M ratios are variable and specific oxygen uptake rates ($K_r$) were 0.23 to 0.26g $O_2/g\;VSS{\cdot}day$ at range of 15 to 20g BVS/l.

생물학적(生物學的) 유동층(流動層)을 이용(利用)한 폐수처리(廢水處理)에 있어서의 심층(深層) 폭기장치(曝氣裝置)에 의한 산소전달(酸素傳達) 시스템

김환기,안송엽,정태섭,Kim, Hwan Gi,Ahn, Song Yeob,Jeong, Tae Seop 대한토목학회 1988 대한토목학회논문집 Vol.8 No.1

생물학적(生物學的) 유동층(流動層)에 있어서 산소전달(酸素傳達) 시스템을 개발하기 위하여 수심(水深) 32 m 인 U자형 심층폭기장치(深層曝氣裝置)에 대한 관내(管內)의 유체(流體)흐름 특성 및 산소전달(酸素傳達) 특성과 생물학적(生物學的) 유동층내(流動層內)에서의 생물막(生物膜) 특성 및 산소이용(酸素利用) 관계를 연구한 결과, 심층폭기장치(深層曝氣裝置) 관내(管內)의 액체순환을 위한 추진력은 하향관(下向管) 공기주입 위치와 하향공기량(下向空氣量)의 영향을 받으며 액체의 흐름은 플러그류(流) 특성임을 확인하였다. 또한, 관내(管內) 순환유속을 0.52 m/s로 유지시킬 때 $K_La$ 값은 상향관(上向管) 25~30 m 구간에서 최대치를 나타내었고, 심층폭기장치(深層曝氣裝置)로부터 생물학적(生物學的) 유동층(流動層)에 이용될 용존산소 공급효율은 56~81%로 계산되었다. 심층폭기장치(深層曝氣裝置)를 이용한 생물학적(生物學的) 유기폐수(有機廢水) 처리에 있어서 용존산소 농도가 9.2 mg/l 이상인 경우, 생물막(生物膜) 내부의 물질확산 및 대사의 제한인자는 유기물(有機物)이었으므로 처리효율의 저하됨이 없이 유기물(有機物) 부하량(負荷量)을 효과적으로 증대시킬 수 있다. This paper is concentrated on the development of oxygen transfer system by U-tube deep shaft in biological fluidised bed process. The depth of the shaft is 32 m, it is composed of downcomer and riser. Not only flow pattern and oxygen transfer in the deep shaft but also oxygen limitation in biofilm and oxygen utilization in biological fluidised bed are investigated. In this investigation, driving force for liquid circulation in the deep shaft is affected by air injection depth and gas hold-up in downcomer. Flow pattern of the deep shaft is revealed to plug flow. When flow velocity in the deep shaft is maintained to 0.52 m/sec, $K_La$ value is peak at 25~30 m depth in riser. The efficiency of dissolved oxygen supply which passed from the deep shaft to biological fluidised bed is estimated to 56~81 % in the organic wastewater treatment using the deep shaft and when dissolved oxygen concentration is 9.2 mg/l and over, limiting factors of flux and substrate within biofilm are organic materials. Terefore, organic loadings could be increase without decreasing of BOD removal efficiency.

3단계 생물학적 유동층을 이용한 질소성분의 제거

김환기,권문선 대한환경공학회 1986 대한환경공학회 학술발표논문집 Vol.1986 No.12

PEN/PET 블랜드의 상호에스테르 교환반응에 따른 randomness의 변화 및 결정화 거동 고찰

김환기,강호종 한국고분자학회 2000 한국고분자학회 학술대회 연구논문 초록집 Vol.2000 No.10

펜턴試藥을 이용한 廢水處理 슬러지의 脫水特性에 關한 硏究

金煥起,朴相肅,劉永壽 全北大學校 1997 論文集 Vol.37 No.-

This study was carried out to improve the dewatering characteristics of wastewater treatment sludge using Fenton's Reagent. The Fenton's Reagent consisting of FeSO_4 and H_2O_2 has powerful oxidizing ability and reactivity. According to the experimental results, primary dosage of FeSO_4 was more effective than secondary in the wastewater treatment sludge and the reagent was almost completed at about 20 minutes contact time with the wastewater sludge. The dosage ratio of FeSO_4:H_2O_2=1mole : 1.6mole was the highest dewatering efficiency. The specific resistance of Fenton's Reagent, 7.335×l0 exp (10)m/㎏, was much lower than these studied as 2.88×10 exp(14)m/㎏ of activated sludge and 1.05×10 exp(12)m/㎏ of conditioned digested sludge. Therefore, the Fenton's Reagent oxidized organics in and then improved dewatering of the wastewater treatment sludge.

천연 제올라이트를 이용한 합성 폐수로부터의 암모늄 이온 제거

김환기,이현석 대한환경공학회 2003 대한환경공학회 학술발표논문집 Vol.2003 No.12

활성슬럿지법에 있어서 팽화(Bulking)의 원인과 대책 (두번째)

김환기 한국환경기술인연합회 1988 환경기술인 Vol.19 No.-

활성슬럿지법에 있어서 팽화(Bulking)의 원인과 대책 (첫번째)

김환기 한국환경기술인연합회 1988 환경기술인 Vol.18 No.-