노화에 따른 아스팔트의 물리화학적 변화와 혼합물 성능에 미치는 영향 연구

이백운,황의윤,Hiroki Hosono,Makoto Hiramatsu 한국도로학회 2020 한국도로학회논문집 Vol.22 No.2

PURPOSES : Asphalt pavements are damaged by various causes, such as cracks, potholes due to climate, and traffic environment. Asphalt aging has a significant effect on cracks, which may also form potholes. The purposes of this study are to estimate the change in asphalt binder and mixture performance and to correlate the physicochemical changes of the asphalt binder and mixture performance with aging. METHODS : The aging process of the asphalt was determined in the laboratory, based on the methods used in previous studies. In terms of consistency (stiffness), crack-resistance performance, moisture susceptibility, SK investigated the binder part, and Shoreki investigated the mixture part depending on the aging time. RESULTS : The consistency (stiffness) and brittleness of both the asphalt binder and mixture tended to increase with aging. In particular, the crack-resistance performance of the asphalt binder (G*sinδ, ductility, and ΔTc) and mixture (flexural fatigue test and Cantabro test) deteriorated because of asphalt aging. Furthermore, the aging mechanisms (oxidation and polymerization) were identified based on the chemical structure analysis. CONCLUSIONS : It is confirmed that the aging affected the chemical composition change and the physical properties of the asphalt. Asphalt pavements are significantly affected by the aging characteristics of the binder. It is concluded that the crack-resistance performance of the mixture decreases with aging due to these physical and chemical changes.

액상 및 고상 박리방지제가 아스팔트 바인더의 노화에 미치는 영향

정구봉,김기병,이상섭,김우성 한국도로학회 2020 한국도로학회논문집 Vol.22 No.2

PURPOSES : The use of hydrated lime or other liquid anti-stripping agents (ASA) is the most common method of improving the moisture susceptibility of asphalt mixes. ASAs are also known to have an anti-aging effect, according to several researchers. Therefore, the use of ASAs is expected to enhance the stability of asphalt pavements. The purpose of this study is to investigate the anti-aging effect of ASAs that are found in the domestic market. METHODS : In this study, an asphalt binder and a mixture mixed with typical domestic solid and liquid ASAs were prepared and aged to evaluate the physicochemical changes. A liquid additive developed by a Korean oil refinery was used as the liquid ASA, and hydrated lime was utilized as the solid ASA. The aging process of the asphalt was determined in the laboratroy based on previous studies to simulate the aging process inh te field. RESULTS : The result of the laboratory experiment indicates that both the solid and liquid ASAs have an anti-aging effect. Moreover, the liquid additive performed relatively better than the hydrated lime. CONCLUSIONS : If ASAs have an anti-aging effect in addition to the anti-stripping function, it is expected to improve the stability of the asphalt pavement significantly. However, few studies have been carried out on the anti-aging effect of ASAs found in the domestic market. In this study, we conducted a fundamental study on the anti-aging effect to help in the selection and use of ASAs in the domestic asphalt-paving industry.

Physical and chemical properties of γ-irradiated EVOH film

Jae Byun, Y.,Hong, S.I.,Kim, K.B.,Jeon, D.H.,Kim, J.M.,Whiteside, W.S.,Jin Park, H. Pergamon 2007 Radiation physics and chemistry Vol.76 No.6

The effects of γ-irradiation on ethylene vinyl alcohol copolymer (EVOH) were investigated. Oxygen permeability decreased as irradiation dose increased in non-oriented (EF-CR), biaxially oriented (EF-XL) EVOH, and nylon/EVOH/PP. Irradiation increased tensile strength (TS) and elongation at break (%E) of EF-CR; whereas, TS of EF-XL was not significantly changed and %E of EF-XL decreased. Irradiation had no effect on TS and %E of nylon/EVOH/PP. Four volatile compounds, ε-caprolactam, 2-propyldecanol, 2-butyloctanol, and 2,3-diethyl-2,3-dimethyl-1,4-butanediol, were detected after irradiation. Optical properties were not changed.

캡사이신유도체를 함유하는 폴록사머 겔제제의 물리화학적 특성 : based Gel Containing Capsaicin Analog

김태완,조청일,최춘영,이범진 한국약제학회 2003 Journal of Pharmaceutical Investigation Vol.33 No.1

Physicochemical changes of poloxamer-based gel containing capsaicin analog (N-[3-(3,4-dimethylphenyl)propyl]-4-(2-aminoethoxy)-3-methoxypheny] acetamide) such as drug content, viscosity and surface tension were investigated during the storage conditions at three different temperatures (25, 40 and 60℃) over 90 days. No noticeable changes of color were observed when stored at 25 and 40℃. However, the color of white poloxamer gels turned yellow during storage at 60℃. The drug contents were unchanged during storage at 25℃ but had tendency to decrease at 40℃. The drug contents were highly decreased over 40-50% when stored at 60℃. The viscosity of a poloxamer-based gel was unchanged during storage at 25 and 40℃ but greatly increased at 60℃. The surface tension of a poloxamer-based gel was not changed at three different temperatures. The storage conditions of a poloxamer-based gel containing capsaicin analog can be considered for further clinical applications.

버섯수확후배지의 퇴비화에 따른 물리 화학적 변화 및 식물 생육 효과

송지민,김자윤,강대선,유정연,강희완,Song, Ji-Min,Phong, Nguyen Hong,Kim, Ja-Yoon,Kang, Dae-Sun,Yu, Jeong-Yeon,Kang, Hee-Wan 한국버섯학회 2020 한국버섯학회지 Vol.18 No.3

표고(Lentinula edodes), 노루궁뎅이(Hericium erinaceus), 느타리(Pleurotus ostreatus)의 버섯수확후배지(spent mushroom substrate, SMS)를 퇴비화에 활용하였다. 퇴비화 온도변화는 50℃ 이상에서 7일에서 10일 동안 지속되어 30일에 부숙이 완료되었다. 퇴비화 된 LeCSMS, HeCSMS는 130%, 80% 무종자에 대한 종자 발아지수를 보여 부숙 도에 대한 종자 발아지수를 충족하였다. 퇴비화에 따른 물리 화학적 변화를 조사 한 바 pH 범위가 4-5에서 6-7로 증가 되었고 EC는 1-1.4 dS/m로 소폭 감소되었으며 유기질 함량은 LeCSMS에서 36.9%로 SMS에 비하여 60% 이상 가장 큰 폭으로 감소 되었다. LeCSMS를 기준으로 N (1.2%), P(2.3%), K(0.77%)함량이 조사되었으며 중금속은 모든 CSMS에서 기준치 이하였으며 Ca, Mg는 30%에서 60%이상 증가하였다. C/N비는 LeCSMS, HeCSMS에서 15% 낮았으나 PoSMS에서 32%로 높게 나타났다. LeCSMS 처리에 따른 고추 유묘 생육효과는 시판 유기퇴비 처리구 등 대조 구에 비하여 초장이 60%이상 높게 성장했으며 옆폭, 옆장, 옆수에서 다른 대조 구에 비하여 모두 우수한 생육 효과를 보였다. This study aimed to assess the feasibility of composting spent mushroom substrate (SMS) materials of Lentinula edodes (Le), Hericium erinaceus (He), and Pleurotus ostreatus (Po). The different SMSs were composted for 7 to 10 days at high temperatures over 50℃; the composting procedure was completed in 30 days. A maturity test was conducted using the radish seed germination index and CoMMe-100. The composted SMS (CSMS) from Le and He showed gemination indices of 130% and 81%, respectively, that satisfied the criteria of maturity standard (gemination index over 70%) and the CoMMe-100 analysis. The physicochemical changes of CSMSs included an increase in the pH range from 4-5 to 6-7, slight reduction in the EC to 1-1.4 dS/m, and an organic content of 36.9% in LeCSMS. In LeCSMS, the contents of N, P, and K were 1.2%, 2.3%, and 0.77%, respectively, and heavy metals were detected below the standard value in all CSMSs; the Ca and Mg contents in the CSMSs were increased from 30% to 60% when compared to those in the SMSs. The C/N ratio (from 26-33) in LeSMS and HeSMS decreased to 15.3-15.9 in CSMSs. The growth effect of LeCSMS treatment on pepper seedlings was 60% higher than that in the control groups, one of which was treated with commercial organic compost; the former showed a superior growth effect on the leaf width, leaf length, and leaf number compared to other control groups. In conclusion, LeCSMS and HeCSMS could be utilized as compost resources capable of efficient soil amendment and plant growth promotion.

조리방법에 따른 돼지고기 등심의 이화학적 특성 변화

양종범 ( Jong Beom Yang ),고명수 ( Myung Soo Ko ),문윤희 ( Yoon Hee Moon ) 한국식품저장유통학회 ( 구 한국농산물저장유통학회 ) 2009 한국식품저장유통학회지 Vol.16 No.4

과거 문헌 비교를 통한 원주천 수서곤충 군집구조 변화

한중수,최준길,원경호,이황구 한국환경생물학회 2018 환경생물 : 환경생물학회지 Vol.36 No.3

This study was a survey of the Wonju stream in Wonju city from May 2015 to September 2016. A total of three sites were selected from the upstream area Gwanseol-dong to the downstream area Hojeo-myeon. Physicochemical analysis, aquatic insect changes, cluster analysis, functional group analysis, rarefaction curve, and statistical analysis were compared between 2004 and 2016. A total of 19 species (38.78%) in 2004 and 22 species (36.67%) in 2016 were analyzed, with the largest number belonging to ephemeroptera. The individual ratio ranged from 27,759.2 (ind. m-2, 84.30%) in 2004 to 4,573.2 (ind. m-2, 41.64%) in 2016, with the highest number involving diptera. As a result of the community analysis, significant differences were detected in the indices of dominance, diversity, evenness, and richness in 2004 and 2016 (p<0.05). Burrowers of the habitat orientation groups showed the greatest variation with an average of -68.00% (±2.15) and the collector-gatherers of the functional feeding groups showed the highest variation of -40.12% (±1.77). The rarefaction curve analysis suggested that the species was the poorest in the midstream regions in 2004 and 2016. Physical factors and water quality showed a significant correlation with diversity index, evenness index, and the number of individuals. MDS analysis of the similarity of upstream and downstream regions was high in 2004, and low in 2016. The differences were attributed to physicochemical changes such as increase in flow velocity due to improvement of small dams and changes in bottom structure. 본 연구는 2015년 5월부터 2016년 9월까지 원주시의 주요 하천인 원주천을 대상으로 조사를 실시하였다. 조사지점은 상류지역인 관설동에서 하류지역인 호저면까지 총 3지점을 선정하였으며, 물리·화학적 분석, 수서곤충상 변화, 군집분석, 기능군 분석, Rarefaction curve, 통계분석 등을 실시하여 2004년의 연구와 비교·분석하였다. 2004년과 2016년의 종비율과 개체수 비율을 비교한 결과, 종비율은 2004년에 19종 (38.78%), 2016년에 22종 (36.67%)으로 하루살이목에서 가장 많은 것으로 분석되었으며, 개체수 비율은 2004년에 27,759.2개체 (ind. m-2, 84.30%), 2016년에 4,573.2개체 (ind. m-2, 41.64%)로 파리목에서 가장 높은 것으로 분석되었다. 전체 출현종 변화를 분석한 결과 공통종은 총 26종, 2004년에만 출현한 종은 총 23종, 2016년에만 출현한 종은 총 34종으로 분석되었다. 군집분석 결과, 2004년, 2016년의 우점도지수, 다양도지수, 균등도지수, 풍부도지수는 유의한 차이가 있는 것으로 분석되었다(p<0.05). 전체 우점종은 2004년, 2016년 모두 깔따구류(Cronomidae sp.)로 분석되었으며, 아우점종은 2004년에는 줄날도래 (Hydropsyche kozhantschikovi), 2016년에는 명주각다귀 KUa (Antocha KUa)로 나타났다. 기능군 분석 결과, 서식기능군은 Burrowers가 평균 -68.00% (±2.15)로 가장 큰 변동율을 나타내었으며, 섭식기능군은 Collector-gathers가 평균 -40.12% (±1.77)로 가장 큰 변동율을 나타내었다. Rarefaction curve 분석 결과, 연도별 관찰된 개체수를 71개체 (ind. m-2)로 가정할 때 2004년에 6종, 2016년에 8종으로 중류지역에서 종이 가장 빈약한 것으로 분석되었다. 물리적요인, 수질, 군집지수, 종수, 개체수의 상관성을 분석한 결과, 물리적 요인 및 수질은 다양도지수, 균등도지수, 개체수와 유의한 상관관계를 나타내는 것으로 분석되었다. MDS 분석결과, 2004년에는 상·하류지역의 유사도가 높은 것으로 분석되었고 2016년에는 상·하류지역의 유사도가 낮은 것으로 분석되어 물리·화학적 환경변화가 원주천 일대 수서곤충의 종조성에 영향을 미친 것으로 판단된다.

가열조리방법에 따른 돼지고기 목심의 이화학적 특성 변화

양종범 ( Jong Beom Yang ),고명수 ( Myung Soo Ko ) 한국식품저장유통학회 2010 한국식품저장유통학회지 Vol.17 No.3

일부 시판 생막걸리 제품의 저장기간에 따른 품질 특성 변화

지윤정 ( Yun Jeong Ji ),정해정 ( Hai Jung Chung ) 한국식생활문화학회 2012 韓國食生活文化學會誌 Vol.27 No.4

This study was conducted to investigate the physicochemical and sensory changes of 6 kinds of commercial Makgeolli (A, B, C, D, E, and F) during storage at 4±1oC for 30 days. The initial pH was 3.50~4.23, but it increased to 3.65~4.37 by the end of the storage period (p<0.05) There were no significant differences in titratable acidity between the beginning and end of the storage period. The reducing sugar content of A and B increased, whereas C, D, E, and F decreased with increasing storage time. A decrease in lightness (L values) was observed in all samples with increasing storage time (p<0.05). The alcohol content increased from beginning values of 5.90~6.10% to ending values of 6.30~7.35% at the end of storage, of which sample B exhibited the highest value. A sensory evaluation test revealed that the overall acceptability of samples A, B, D, and E were still within acceptable limits, but samples C and F showed undesirable changes during 30 days of storage at 4oC.

감마선 조사가 비트(Beta vulgaris L.)의 물리화학적 특성 및 Betalain 색소 안정성에 미치는 영향

김경희,이성아,육홍선,Kim, Kyoung-Hee,Lee, Sung-A,Yook, Hong-Sun 한국식품영양과학회 2007 한국식품영양과학회지 Vol.36 No.4

감마선 조사가 비트의 품질특성 및 비트의 주요 색소인 betalain에 미치는 영향을 알아보기 위해 비트에 2.5kGy, 5kGy, 10kGy 및 30kGy로 감마선 조사를 실시하였다. 조사에 따른 betalain추출량에는 차이가 없었으며 betacyanin과 betaxanthin은 5kGy의 조사선량에서 높은 optical density 값을 나타내었다. 조사선량이 증가할수록 비트의 명도, 적색도 그리고 황색도는 감소하였으며 pH는 조사에 따른 차이를 나타내지 않았다. 10kGy이상의 감마선 조사는 물성에 나쁜 품질을 나타내었으며 항산화효과는 감마신 조사에 의한 유의적인 변화(p<0.05)를 보이지 않았다. 따가서 천연색소 및 물성 측면에서 볼 때 비트에 대한 10kGy 이상의 감마선 조사는 바람직하지 않은 것으로 생각한다. The physicochemical properties of red beets and the stability of betalain pigments irradiated at 2.5, 5, 10 and 30 kGy were evaluated. Betalain extraction yield of irradiated red beets was not significantly different from non-irradiated red beet. The red beet irradiated at 5kGy showed high optical density value in betacyanin and betaxanthin. In Hunter's color value lightness (L), redness (a) and yellowness (b) decreased with increment of irradiation dose. All red beets showed no difference in pH. The red beets irradiated above 10 kGy had poor textural property quality but antioxidant activity of betalain was not significantly changed by gamma irradiation. Considering natural colorant and textural quality, the gamma irradiation above 10kGy was an undesirable technique for red beets.