Examination of the melt temperature stability of the mold-type slit rheometer affected by plasticizing conditions and the shear heating in the nozzle and sprue

한은수,김진수,Bongju Kim,이병옥 한국유변학회 2021 Korea-Australia rheology journal Vol.33 No.2

Authors designed and built a mold-type slit rheometer. The slit rheometer has a vertical flow channel and interchangeable cores with various slit thicknesses. It is installed in an injection molding machine like a general mold. The melt is supplied by the plasticizing unit of the injection molding machine. The melt temperature supplied by the plasticizing unit varies by the plasticizing conditions and the shear heating effect in the nozzle and the sprue. In this study, the effects of the plasticizing conditions and the shear heating in the nozzle and the sprue were examined, and the influence of the melt temperature variation on the viscosity measurement was analyzed experimentally and numerically. A temperature sensor was designed to measure the melt temperature in the sprue. Its tip is fully immersed in the melt to have a higher sensitivity. Two resins with different thermal sensitivities were used to examine the effect of resin on the melt temperature variation. To check the shear heating effect in the nozzle and the sprue, two sets of the nozzle and the sprue with different orifice sizes were used. The numerical analysis was done by commercial software (Moldex3D) to check the melt temperature from the nozzle to the slit channel. The viscosity of long-fiber reinforced polypropylene (PP) was measured with various slit channel thicknesses to verify the reproducibility. The standard deviation of the viscosity values against the Cross model fitting curve was 3.01 Pa·s. The viscosity of acrylonitrile butadiene styrene (ABS) measured using the slit rheometer was compared with values obtained from a capillary rheometer and commercial database.

시간적, 공간적 특성을 활용하는 딥러닝기반 고무의 레오미터 품질 적합성 검사 모델

박재현,장용훈,이복동,이명섭 한국컴퓨터정보학회 2023 韓國컴퓨터情報學會論文誌 Vol.28 No.11

Rubber produced by rubber companies is subjected to quality suitability inspection through rheometer test, followed by secondary processing for automobile parts. However, rheometer test is being conducted by humans and has the disadvantage of being very dependent on experts. In order to solve this problem, this paper proposes a deep learning-based rheometer quality inspection system. The proposed system combines LSTM(Long Short-Term Memory) and CNN(Convolutional Neural Network) to take advantage of temporal and spatial characteristics from the rheometer. Next, combination materials of each rubber was used as an auxiliary input to enable quality conformity inspection of various rubber products in one model. The proposed method examined its performance with 30,000 validation datasets. As a result, an F1-score of 0.9940 was achieved on average, and its excellence was proved.

Wall slip of vaseline in steady shear rheometry

Song, Ki-Won,Chang, Gap-Shik,Koo, Ja-Seung The Korean Society of Rheology 2003 Korea-Australia rheology journal Vol.15 No.2

The steady shear flow properties of vaseline generally used as a base of the pharmaceutical dosage forms were studied in the consideration of wall slip phenomenon. The purpose of this study was to show that how slip may affect the experimental steady-state flow curves of semisolid ointment bases and to discuss the ways to eliminate (or minimize) wall slip effect in a rotational rheometer. Using both a strain-controlled ARES rheometer and a stress-controlled AR1000 rheometer, the steady shear flow behavior was investigated with various experimental conditions ; the surface roughness, sample preparation, plate diameter, gap size, shearing time, and loading methods were varied. A stress-controlled rheometer was suitable for investigating the flow behavior of semisolid ointment bases which show severe wall slip effects. In the conditions of parallel plates attached with sand paper, treated sample, smaller diameter fixture, larger gap size, shorter shearing time, and normal force control loading method, the wall slip effects could be minimized. A critical shear stress for the onset of slip was extended to above 10,000 dyne/$\textrm{cm}^2$. The wall slip effects could not be perfectly eliminated by any experimental conditions. However, the slip was delayed to higher value of shear stress by selecting proper fixture properties and experimental conditions.

광중합 복합레진의 중합초기 동적 점탄성의 변화

김민호,이인복 대한치과보존학회 2009 Restorative Dentistry & Endodontics Vol.34 No.5

본 연구의 목적은 새로 개발한 점탄성 측정기를 사용하여 수종의 광중합 복합레진의 초기 동적 점탄성 변화를 측정하는 것이다. 본 연구에 사용된 점탄성 측정기는 세 부분으로 구성되었다. 첫째, 시편이 놓여지는 parallel plates; 둘째, DC 모터와 크랭크로 이루어진 회전진동전단변형 (Oscillatory shear strain)을 발생시키는 부분; 셋째, 전자기적 토크센서를 이용한 응력 측정 부분으로 구성되었다. 본 점탄성 측정기는 최대 2 Ncm의 토크를 측정할 수 있으며, 광중합기의 스위치는 컴퓨터와 연동하여 데이터 획득을 시작할 때 동시에 켜지도록 하였다. 본 연구에서는 시판 중인 6종의 광중합 복합레진 [Z-100 (Z1), Z-250 (Z2), Z-350 (Z3), DenFil (DF), Tetric Ceram (TC), Clearfil AP-X (CF)]을 사용하였다. 점탄성 측정기를 사용하여 동적 회전전단실험을 시행하였다. 직경 3 mm인 유리막대로 구성된 parallel plates 사이에 14.2㎣의 복합레진을 적용시켰으며, 6 Hz의 진동수와 0.00579 rad의 진폭으로 변형을 가하고 발생된 응력을 측정하였다. 광중합이 시작됨과 동시에 측정이 시작되었으며, 광중합 후 10초 동안 점탄성의 변화를 관찰하였다. 각 복합레진에 대해 5 회 반복하여 측정하였고, 실험은 에서 진행되었다. 측정된 변형-응력 곡선으로부터 복소전단탄성계수 G*, 저장전단탄성 계수 G', 손실전단탄성 계수 G"를 구하였고 G*가 10 MPa에 이르는 시간을 구하였다. 각 재료의 복소전단탄성계수 G*와 10 MPa에 이르는 시간에 대해 일원분산분석 (One-way ANOVA)과 사후검정 (Tukey 검정)을 시행하였다 (α= 0.05). 결과는 다음과 같다. 1. 본 연구를 위해 제작한 점탄성 측정기는 광중합 복합레진의 중합 초기 10초 동안의 동적 점탄성 변화를 신뢰성 있게 측정 할 수 있었다. 2. 모든 복합레진은 광조사 개시 후 초의 불응기를 지난 다음 급격한 전단탄성계수의 증가를 보였다. 3. 모든 복합레진은 광중합 10 초간 손실전단탄성계수보다 저장전단탄성계수의 높은 증가를 보였다. 4. 광중합 초기 10초 후 복소전단탄성계수 값은 로, Z-100이 가장 높았고, 그 다음 Clearfil, Z-250, Z-350, Tetric Ceram, DenFil의 순이었다. 5. 복소전단탄성계수가 10 MPa에 이르는 시간은 Z-100이 2.55초로 가장 빨랐고, DenFil이 4.06초로 가장 느렸다. The aim of this study was to measure the initial dynamic modulus changes of light cured composites using a custom made rheometer. The custom made rheometer consisted of 3 parts: (1) a measurement unit of parallel plates made of glass rods, (2) an oscillating shear strain generator with a DC motor and a crank mechanism, (3) a stress measurement device using an electromagnetic torque sensor. This instrument could measure a maximum torque of 2Ncm, and the switch of the light-curing unit was synchronized with the rheometer. Six commercial composite resins [Z-100 (Z1), Z-250 (Z2), Z-350 (Z3), DenFil (DF), Tetric Ceram (TC), and Clearfil AP-X (CF)] were investigated. A dynamic oscillating shear test was undertaken with the rheometer. A certain volume (14.2 ㎣) of composite was loaded between the parallel plates, which were made of glass rods (3 mm in diameter). An oscillating shear strain with a frequency of 6 Hz and amplitude of 0.00579 rad was applied to the specimen and the resultant stress was measured. Data acquisition started simultaneously with light curing, and the changes in visco-elasticity of composites were recorded for 10 seconds. The measurements were repeated 5 times for each composite at . Complex shear modulus G*, storage shear modulus G', loss shear modulus G" were calculated from the measured strain-stress curves. Time to reach the complex modulus G* of 10 MPa was determined. The G* and time to reach the G* of 10 MPa of composites were analyzed with One-way ANOVA and Tukey's test (α = 0.05). The results were as follows. 1. The custom made rheometer in this study reliably measured the initial visco-elastic modulus changes of composites during 10 seconds of light curing. 2. In all composites, the development of complex shear modulus G* had a latent period for seconds immediately after the start of light curing, and then increased rapidly during 10 seconds. 3. In all composites, the storage shear modulus G" increased steeper than the loss shear modulus G" during 10 seconds of light curing. 4. The complex shear modulus of Z1 was the highest, followed by CF, Z2, Z3, TC and DF the lowest. 5. Z1 was the fastest and DF was the slowest in the time to reach the complex shear modulus of 10 MPa.

Capillary Rheometer를 이용한 숙성시간 및 함수율 변화 도자소지의 가소성평가

김근희,피재환,김진호,김영환,조우석,김경자,Kim, Geun-Hee,Pee, Jae-Hwan,Kim, Jin-Ho,Kim, Young-Hwan,Cho, Woo-Seok,Kim, Kyeong-Ja 한국세라믹학회 2012 한국세라믹학회지 Vol.49 No.3

Plasticity is the ability of clay to respond to pressure with a continuous and permanent change of shape in any direction without breaking apart, and hold that shape when released. In this work, the effect of water content and aging period on the plasticity of porcelain clay was evaluated using the capillary rheometer to measure the flow rate and the shear stress. The shear stress of porcelain clay was slightly increased with increasing the aging period, indicating that the plasticity of porcelain clay was influenced by an organic content. It was also observed that the water content in the porcelain clay had a great influence on the plasticity of porcelain clay. The shear stress with water content of 21 wt% was sharply increased with increasing shear rate, but the shear stresses with water contents of 24 and 27 wt% is gently incremented.

Capillary rheometry of polymer melts - Simulation and experiment

Seppo Syrjala,Johanna Aho 한국유변학회 2012 Korea-Australia rheology journal Vol.24 No.3

This paper discusses shear viscosity measurements of polymer melts by the capillary rheometer. Particular emphasis is placed on investigating the effects of viscous heating and pressure dependence of viscosity in capillary flows. The capillary flow problem is addressed by means of numerical simulation using the finite element method to solve the equations of continuity, momentum and energy along with the viscosity model that accounts for the dependence on shear rate, temperature and pressure. Simulations clearly reveal that vis\-cous heating and pressure dependence of viscosity can have a considerable impact on capillary rheometer experiments. On the other hand, as far as the pressure drop over the capillary is concerned, it is possible that these two contributing factors compensate for each other. Selected experimental data from the capillary rheometer are also presented and discussed in connection with the simulated results.

Capillary rheometry of polymer melts - Simulation and experiment

Syrjala, Seppo,Aho, Johanna 한국유변학회 2012 Korea-Australia rheology journal Vol.24 No.3

This paper discusses shear viscosity measurements of polymer melts by the capillary rheometer. Particular emphasis is placed on investigating the effects of viscous heating and pressure dependence of viscosity in capillary flows. The capillary flow problem is addressed by means of numerical simulation using the finite element method to solve the equations of continuity, momentum and energy along with the viscosity model that accounts for the dependence on shear rate, temperature and pressure. Simulations clearly reveal that viscous heating and pressure dependence of viscosity can have a considerable impact on capillary rheometer experiments. On the other hand, as far as the pressure drop over the capillary is concerned, it is possible that these two contributing factors compensate for each other. Selected experimental data from the capillary rheometer are also presented and discussed in connection with the simulated results.

Measurements of the rheological properties of standard reference material 2490 using an in-line micro-Fourier rheometer

J. A. Glasscock,R. S. Smith 한국유변학회 2004 Korea-Australia rheology journal Vol.16 No.4

The control of the rheological properties of a fluid during processing is important and can determine the efficiency of the production in addition to the performance of the final product. The vast majority of process fluids are viscoelastic, hence an instrument that measures both the viscous and elastic properties of the material during processing would be of great practical use. However, most in-line instruments commercially available to date are only capable of measuring viscosity at a single shear rate. An in-line rheometer that measures both the viscous and elastic properties of fluids over a wide range of shear rates simultaneously has been described in a previous publication (Glasscock et al., 2003) in which the results of measurements on flowing sunflower oil were presented. Before this instrument can be used in an industrial situation, it must be demonstrated that the generated results are the same as, or bear some fixed relationship to, the results obtained by conventional off-line rheometers. To this end, the present investigation describes the measurements of a standard reference fluid, polyisobutylene dissolved in 2,6,10,14-tetramethylpentadecane, labelled SRM2490 by the National Institute of Standards and Technology (NIST) in the USA. The results obtained using the in-line rheometer show remarkably good correlation for viscosity, using a modified Cox-Merz rule, with the results supplied with the reference material from NIST.

Measurements of the rheological properties of standard reference material 2490 using an in-line micro-Fourier rheometer

Smith R. S.,Glasscock J. A. The Korean Society of Rheology 2004 Korea-Australia rheology journal Vol.16 No.4

The control of the rheological properties of a fluid during processing is important and can determine the efficiency of the production in addition to the performance of the final product. The vast majority of process fluids are viscoelastic, hence an instrument that measures both the viscous and elastic properties of the material during processing would be of great practical use. However, most in-line instruments commercially available to date are only capable of measuring viscosity at a single shear rate. An in-line rheometer that measures both the viscous and elastic properties of fluids over a wide range of shear rates simultaneously has been described in a previous publication (Glasscock et at., 2003) in which the results of measurements on flowing sunflower oil were presented. Before this instrument can be used in an industrial situation, it must be demonstrated that the generated results are the same as, or bear some fixed relationship to, the results obtained by conventional off-line rheometers. To this end, the present investigation describes the measurements of a standard reference fluid, polyisobutylene dissolved in 2,6,10,14-tetramethylpentadecane, labelled SRM2490 by the National Institute of Standards and Technology (NIST) in the USA. The results obtained using the in-line rheometer show remarkably good correlation for viscosity, using a modified Cox­Merz rule, with the results supplied with the reference material from NIST.

Rheological characterization of thermoplasticized injectable gutta percha and resilon

장주혜,백승호,이인복 大韓齒科保存學會 2011 Restorative Dentistry & Endodontics Vol.36 No.5

연구목적: 본 연구의 목적은 열연화주입형 gutta percha와 resilon의 온도 변화에 따른 점탄성 변화를 관찰하고 조작성을 비교하기 위함이다. 연구 재료 및 방법: Obtura-II 시스템을 이용하여 세 종류의 gutta percha와 resilon을 와 로 가열한 후 사출 온도를 측정하였다. 점도계를 이용하여 온도 변화에 따른 재료들의 점탄성 특성(전단탄성계수, G'; 전단점성계수, G"; 손실 탄젠트, tan; 복소점도, )을 관찰하였다. 점도계와 차동주사열측정기(DSC)로 재료들의 상전이 온도를 측정하였고 가압법으로 와 에서 재료들의 점조도를 비교하였다. 결과: 세 종의 gutta perchas는 온도에 따라 서로 다른 점탄성 특성을 나타냈다. 에서 연화된 재료의 고체화 상변이가 일어났고, 점도계와 DSC로 측정된 상변이 시작 온도는 유사하였다. 상변이 시작 온도와 가압 시 점조도는 재료들마다 차이를 보였다(p < 0.05). Resilon은 gutta percha와 비슷한 유변학적 특성을 보였다. 결론: 열연화된 근관충전재는 냉각과정 동안 유변학적 특성의 변화를 나타냈고 재료들마다 서로 다른 점탄성 특성은 근관 내주입 시와 충전 시 서로 다른 조작성을 보임을 알 수 있다. Objectives: The purpose of this study was to observe the change in the viscoelastic properties of thermoplasticized injectable root canal filling materials as a function of temperature and to compare the handling characteristics of these materials. Materials and Methods: Three commercial gutta perchas and Resilon (Pentron Clinical Technologies) in a pellet form were heated in the Obtura-II system (Obtura Spartan) at and , and the extrusion temperature of the thermoplasticized materials was measured. The viscoelastic properties of the materials as a function of temperature were evaluated using a rheometer. The elastic modulus G', viscous modulus G", loss tangent tan, and complex viscosity were determined. The phase transition temperature was determined by both the rheometer and a differential scanning calorimeter (DSC). The consistency of the materials was compared under compacting pressure at and by a squeeze test. Results: The three gutta perchas had dissimilar profiles in viscoelastic properties with varying temperature. The phase transition of softened materials into solidification occurred at to , and the onset temperatures obtained by a rheometer and a DSC were similar to each other. The onset temperature of phase transition and the consistency upon compaction pressure were different among the materials (p < 0.05). Resilon had a rheologically similar pattern to the gutta perchas, and was featured between high and low-flow gutta perchas. Conclusions: The rheological characteristics of the thermoplasticized root canal filling materials changed under a cooling process. The dissimilar viscoelastic properties among the materials require different handling characteristics during an injecting and compacting procedure.