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Kim, Yeonwoo,Yang, Sena,Jeon, Eun Hee,Baik, Jaeyoon,Kim, Namdong,Kim, Hyun Sung,Lee, Hangil Springer US 2016 NANOSCALE RESEARCH LETTERS Vol.11 No.1
<P>To design a high-performance photocatalytic system with TiO<SUB>2</SUB>, it is necessary to reduce the bandgap and enhance the absorption efficiency. The reduction of the bandgap to the visible range was investigated with reference to the surface distortion of anatase TiO<SUB>2</SUB> nanoparticles induced by varying Fe doping concentrations. Fe-doped TiO<SUB>2</SUB> nanoparticles (Fe@TiO<SUB>2</SUB>) were synthesized by a hydrothermal method and analyzed by various surface analysis techniques such as transmission electron microscopy, Raman spectroscopy, X-ray diffraction, scanning transmission X-ray microscopy, and high-resolution photoemission spectroscopy. We observed that Fe doping over 5 wt.% gave rise to a distorted structure, i.e., Fe<SUB>2</SUB>Ti<SUB>3</SUB>O<SUB>9</SUB>, indicating numerous Ti<SUP>3+</SUP> and oxygen-vacancy sites. The Ti<SUP>3+</SUP> sites act as electron trap sites to deliver the electron to O<SUB>2</SUB> as well as introduce the dopant level inside the bandgap, resulting in a significant increase in the photocatalytic oxidation reaction of thiol (–SH) of 2-aminothiophenol to sulfonic acid (–SO<SUB>3</SUB>H) under ultraviolet and visible light illumination.</P><P><B>Electronic supplementary material</B></P><P>The online version of this article (doi:10.1186/s11671-016-1263-6) contains supplementary material, which is available to authorized users.</P>
Solid-Phase Synthesis of 2-Arylbenzothiazole Using Silica Sulfuric Acid under Microwave Irradiation
Niralwad, Kirti S.,Shingate, Bapurao B.,Shingare, Murlidhar S. Korean Chemical Society 2010 Bulletin of the Korean Chemical Society Vol.31 No.4
The condensation of several aromatic/heteroaromatic aldehydes with 2-aminothiophenol catalyzed by silica sulfuric acid under microwave irradiation afforded 2-arylbenzothiazoles in high yields and short reaction times under solvent-free conditions. The major advantages of the present method are good yields, ecofriendly, reusable catalyst, mild and solvent-free reaction conditions.
Solid-Phase Synthesis of 2-Arylbenzothiazole Using Silica Sulfuric Acid under Microwave Irradiation
Kirti S. Niralwad,Bapurao B. Shingate,Murlidhar S. Shingare 대한화학회 2010 Bulletin of the Korean Chemical Society Vol.31 No.4
The condensation of several aromatic/heteroaromatic aldehydes with 2-aminothiophenol catalyzed by silica sulfuric acid under microwave irradiation afforded 2-arylbenzothiazoles in high yields and short reaction times under solvent-free conditions. The major advantages of the present method are good yields, ecofriendly, reusable catalyst, mild and solvent-free reaction conditions.