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Zhengde Li,Zhiying Zhan,Yuejiao Jia,Zhang Li,Ming Hu 한국공업화학회 2021 Journal of Industrial and Engineering Chemistry Vol.97 No.-
Based on the ligand 2,2'-bipyridine-5,5'-dicarboxylic acid (H2bpdc), a luminescent Eu-MOF wassuccessfully synthesized under solvothermal conditions, namely, [Eu(bpdc)1.5(H2O)2]n (1). Theexperimental explorations showed that compound 1 could not only detect Fe3+ and Cu2+ ions withhigh selectivity and recyclability, but also serve as an excellent selective sensing material for PO43 ionamong some anions. Surprisingly, as an outstanding example of Ln-MOFs withfluorescence response todichloromethane in aqueous solution, compound 1 could also behave as a functional probe with highsensitivity, selectivity, and recyclability. Meanwhile, the possible distinguishing mechanisms ofcompound 1 for above ions and CH2Cl2 molecule were further speculated.