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        Surface Modification of Poly(vinylidene fluoride) Ultrafiltration Membranes with Chitosan for Anti-Fouling and Antibacterial Performance

        Weiwei Xia,Manman Xie,Xia Feng,Li Chen,Yiping Zhao 한국고분자학회 2018 Macromolecular Research Vol.26 No.13

        A graft copolymer (PVDF-g-PAA) having poly(vinylidene fluoride) (PVDF) backbones and poly(acrylic acid) (PAA) side chains was synthesized using the radical polymerization method and the PVDF-g-PAA copolymer membrane was prepared via immersion phase inversion. Then the chitosan was immobilized on the surface of the copolymer membrane by covalent bond. The morphology, surface chemical structure and performance of the modified membranes were characterized by scanning electron microscopy, attenuated total reflection-Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, water contact angle, permeation measurement, antifouling and antibacterial tests. The results showed that the contact angle of the modified membrane decreased, and the water flux increased from 37.74Lm-2h-1 for pure PVDF membrane to 119.43 Lm-2h-1, which indicated that the modified membrane had higher hydrophilicity than unmodified membrane. The modified membrane has better antifouling properties than pure PVDF membrane due to the increase of surface hydrophilicity, and the highest water flux recovery ratio can achieve 93.2%. Furthermore, the modified membrane showed good antibacterial activity (E. coli), and the maximum antibacterial ratio of the modified membrane was 89.6%.

      • KCI등재

        Mussel-Inspired Multifunctional Coating for Enhancing the UV-Resistant Property of Polypropylene Fibers

        Zhengyi Liu,Juncheng Hu,Qi Sun,Li Chen,Xia Feng,Yiping Zhao 한국고분자학회 2017 Macromolecular Research Vol.25 No.5

        In this paper, UV-resistant polypropylene (PP) fibers were prepared with a simple and versatile strategy. The PP fiber was firstly coated a polydopamine (PDA) layer by simply dipping the fiber into an alkaline dopamine solution. Then, the titania (TiO2) nanoparticles were chemically bound to the PDA layer through the reduction capacity of catechol groups in PDA, endowing the fibers with excellent UVresistant properties. The surface chemical composition of modified fibers was confirmed by attenuated total reflectance fourier transform infrared (ATR-FTIR) spectroscopy and X-ray photoelectron spectroscopy (XPS). The surface morphology and the crystalline structure of the modified fibers were studied by scanning electron microscopy (SEM) and X-ray diffraction (XRD) respectively. Thermo stability was characterized by thermogravimetry analysis. Besides, the mechanical and UV protection properties were further investigated through monofilament tensile and the UV transmittance test. The results showed that the PDA and TiO2 were successfully coated on fiber surface. Comprared to the pristine fiber, the modified fiber exhibited better thermal stability. Particularly, the as-prepared PP-PDA-TiO2 fibers could strongly resist the UV rays with no change in mechanical properties.

      • SCIESCOPUSKCI등재

        Simulation Research of Multi-morphological Microstructures Chaining Mechanism of Nano-magnetic Fluid

        Lei Yang,Yibiao Chen,Yao Yao,Shuaikang Wei,Yuhui Xie,Decai Li,Jun Yu,Hongming Zhou,Yiping Feng 한국자기학회 2024 Journal of Magnetics Vol.29 No.1

        For nano-magnetic fluid(NMF), the magnetic nano-particle(MNP) kinematic behavior in a magnetic field and the chain-like microstructure evolution are important to study the NMF properties at the microscopic level. However, the chain structure formation mechanism and the effects of multiple environmental factors on microstructural morphology remain unclear. In this paper, the interaction of a two-particle system, chain structure formation process, microstructure evolution and response time simulation of NMF is investigated by the discrete element simulation method. The results show that the magnetic dipole and repulsive forces dominate the chain structure formation and evolution under a uniform magnetic field. MNPs assemble into chain-like structures and various complex structures along the magnetic f ield direction. The volume fraction, magnetization intensity and particle size significantly affect the microstructure and the response time. The above study can obtain the specific morphology of the microstructure at different working conditions and broaden the application of NMF in practical engineering.

      • On the direct insulator-quantum Hall transition in two-dimensional electron systems in the vicinity of nanoscaled scatterers

        Liang, Chi-Te,Lin, Li-Hung,Kuang Yoa, Chen,Lo, Shun-Tsung,Wang, Yi-Ting,Lou, Dong-Sheng,Kim, Gil-Ho,Yuan-Huei, Chang,Ochiai, Yuichi,Aoki, Nobuyuki,Chen, Jeng-Chung,Lin, Yiping,Chun-Feng, Huang,Lin, Sh Springer 2011 Nanoscale research letters Vol.6 No.1

        <P>A direct insulator-quantum Hall (I-QH) transition corresponds to a crossover/transition from the insulating regime to a high Landau level filling factor ν > 2 QH state. Such a transition has been attracting a great deal of both experimental and theoretical interests. In this study, we present three different two-dimensional electron systems (2DESs) which are in the vicinity of nanoscaled scatterers. All these three devices exhibit a direct I-QH transition, and the transport properties under different nanaoscaled scatterers are discussed.</P>

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