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- 검색키워드
- 저자 : Vali Ahmad Sajjadian (검색결과 3 건)
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Arsalan Zeinalzadeh,Reza Moussavi-Harami,Asadollah Mahboubi,Vali Ahmad Sajjadian 한국지질과학협의회 2018 Geosciences Journal Vol.22 No.4
The Darquain field is located in the Abadan Plain SW Iran, which has a high potential for exploration and production of hydrocarbon resources with poorly defined petroleum systems. The goal of this paper is to characterize the Cretaceous source rock potential in the Darquain field. A gamma-sonic log was used as a proxy to identify probable source rock zones and to select sample depths. A total of 37 samples were analyzed by Rock-Eval, elemental, Gas Chromatography (GC) and gas chromatographymass spectrometry (GC-MS) techniques. The petroleum generation potential, as well as origin of the organic matter of samples, have been investigated. The results of this study indicate that, in the Early Cretaceous successions, there are favorable source zones in Garau, Gadvan, and Kazhdumi Formations. These source zones predominantly contain organic matter from marine origin, suggesting kerogen type II, while some samples contain terrestrial organic matters, suggesting kerogen type III. The Lower Garau zone, with 1.14 to 14.29% total organic carbon (TOC), is an excellent source rock with a fair genetic potential in the range of 2.74 and 9.5 mg/g. Elemental analysis results in the Lower Garau zone allow the classification of kerogens as high-sulfur. There are very good source zones in the Kazhdumi Formation, with fair to good genetic potential. The results of Rock-Eval and petrophysical analyses show that gamma ray data can be used as a useful tool to determine the potential source zones, although where TOC is less than 1% there is inconsistency. The results obtained from the biomarker characteristics are in agreement with the results of Rock-Eval pyrolysis and indicated carbonate source rocks, which contain a mixture of marine organic matter with a minor amount of terrigenous organic matter. Biomarker characteristics also suggest that the organic matter was deposited in a marine environment under reducing conditions, and that Early Cretaceous source zones are at the stage of early oil window to peak of oil generation.
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Alvand Ehsan,Aalaie Jamal,Hemmati Mahmood,Sajjadian Vali Ahmad 한국고분자학회 2017 Macromolecular Research Vol.25 No.1
The objective of the present study is to improve the behavior of sulfonated polyacrylamide (SPA) by adding Laponite and/or chromium(III) with a focus on enhanced oil recovery applications. The resultant systems are weak nanocomposite hydrogels which are subjected to rheological, thermal stability and adsorption tests. The interactions between ingredients of the hydrogel are investigated by Fourier transform infrared (FTIR) spectroscopy. In addition, dispersion of Laponite nanoparticles in hydrogel is confirmed by transmission electron microscopy (TEM). The thermal stability is determined by measuring the loss of viscosity after an aging cycle. The adsorption tests are performed on calcite and evaluated using thermo gravimetric analysis. FTIR spectra confirmed the interaction of Laponite and Cr3+ with SPA. TEM micrograph showed an approximately uniform dispersion of Laponite in the crosslinked SPA/Cr3+/Laponite system. The viscoelastic behaviors of the systems improved with the addition of either Laponite or chromium(III). The sulfonated polyacrylamide/chromium(III)/Laponite system slightly loses its viscosifying power when subjected to harsh conditions of themo-chemical aging process. The adsorption behavior of the systems improved with Laponite concentration while the presence of chromium(III) weakened the adsorption. Therefore the introduced polymeric systems of the present study may be a potential option for enhanced oil recovery applications in hostile conditions.
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Jamal Aalaie,Ehsan Alvand,Mahmood Hemmati,Vali Ahmad Sajjadian 한국화학공학회 2016 Korean Journal of Chemical Engineering Vol.33 No.6
The aim of this study was to outline the preparation of colloidal dispersion gels (CDGs) based on sulfonated polyacrylamide (SPA) and chromium triacetate and investigating their stability in harsh conditions. The effect of crosslinker, polymer concentration, salinity, and gelation time and temperature on the formation, rheological behavior and size distribution of CDGs and also their thermo-chemical stabilities were investigated. It was found that the shear viscosity and size of CDGs decreased with increasing of preparation time. Dynamic light scattering and scanning electron microscopy evaluations showed that the size of CDGs particles decreased with increasing of the Cr3+ concentration. In addition, SPA solution had yield stress, while CDGs did not. The elevation of temperature inhibits while the salinity does not disturb the formation of CDGs. In the systems with lower polymer concentration, CDGs were formed. Conversely, in the systems with higher polymer concentration, bulk gels were formed. After aging, CDG sample had a minimal viscosity loss, indicating its exceptional thermo-chemical stability.
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