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RISS 인기검색어
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- 저자 : Raana Sarvari (검색결과 3 건)
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Polyanizidine and Polycaprolactone Nanofibers for Designing the Conductive Scaffolds
Bakhshali Massoumi,Raana Sarvari,Amir Zareh,Younes Beygi-Khosrowshahi,Samira Agbolaghi 한국섬유공학회 2018 Fibers and polymers Vol.19 No.10
The main objective of this work was chemically bioactivation of the conducting polyanizidine (PANIZ) by incorporating a polyester such as polycaprolactone (PCL). Modified PANIZ nanocomposites were synthesized through ring opening and chemical oxidation polymerizations. A four-point probe was applied to measure the conductivity of newly synthesized star-like block copolymer (S-PCL-PANIZ) nanocomposite, which was about 0.44 S cm-1. Conductive biodegradable nanofibers were prepared by electrospinning with 25 and 75 % (wt/wt) S-PCL-PANIZ to PCL. The contact angle of each prepared nanofiber was 87±3 o, supporting their usefulness for cell culture. The cultured mouse osteoblast MG63 cells demonstrated normal morphology and significantly higher adhesion and spreading on the nanofiber. The bioactivated PANIZ based nanocomposite may be fruitful in tissue engineering to fabricate conducting biodegradable scaffolds with improved cell adhesion properties for various cell cultures.
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Somaiyeh Charoughchi,Samira Agbolaghi,Raana Sarvari,Sahar Aghapour 한국고분자학회 2018 Macromolecular Research Vol.26 No.13
Surfaces of multi-walled carbon nanotubes (CNTs) and reduced graphene oxide (rGO) nanosheets were chemically modified to design distinct donor-acceptor nano-hybrids having different morphologies and orientations. In unmodified CNTs and their derivatives functionalized with 2-hydroxymethyl thiophene (CNT-f-COOTh) and grafted with poly(3-dodecylthiophene) (CNT-g-PDDT), double-fibrillar, shishkebab, and stem-leaf nanostructures were decorated. Furthermore, rGO nanosheets functionalized with 2-thiophene acetic acid (rGO-f-TAA) and grafted with poly(3- dodecylthiophene) (rGO-g-PDDT) were prepared to study differences in CNT and rGO supramolecules. Three types of orientations subsuming face-on, edge-on, and flat-on were detected in nano-hybrids based on CNT and rGO. Morphology (fibrillar) and orientation (face-on) of poly(3-hexylthiophene) (P3HT) assemblies were similar onto unmodified CNT and rGO nanostructures. Although patternings of P3HT chains were completely different onto functionalized CNT and rGO (shish-kebab versus nanocrystal decorated nanosheets), edge-on orientation was detected in CNT-f-COOTh/P3HT and rGO-f-TAA/P3HT nano-hybrids. In CNT-g-PDDT/P3HT and rGO-g-PDDT/P3HT systems, P3HT chains were extendedly assembled onto grafted carbonic materials; however, their different natures reflected stem-leaf and patched-like configurations, respectively. For unmodified, functionalized, and grafted CNT and rGO patterned with P3HT chains, a photoluminescence quenching was detected for a donor-acceptor nature. Owing to flat-on oriented P3HTs, the best photoluminescence quenching, thereby the best donating-accepting features were detected for CNT-g-PDDT/P3HT and rGO-g-PDDT/P3HT supramolecules.
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Samira Agbolaghi,Sahar Aghapour,Somaiyeh Charoughchi,Farhang Abbasi,Raana Sarvari 한국공업화학회 2018 Journal of Industrial and Engineering Chemistry Vol.68 No.-
Reduced graphene oxide (rGO) nanosheets were patterned with poly[benzodithiophene-bis(decyltetradecyl-thien) naphthothiadiazole] (PBDT-DTNT) and poly[bis(triiso-propylsilylethynyl) benzodithiophene-bis(decyltetradecyl-thien) naphthobisthiadiazole] (PBDT-TIPS-DTNT-DT) and used in photovoltaics. Conductive patternings changed via surface modification of rGO; because polymers encountered a high hindrance while assembling onto grafted rGO. The best records were detected in indium tin oxide (ITO):poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS):PBDT-DTNT/rGO:PBDT-DTNT:LiF:Al devices, i.e., short current density (Jsc) = 11.18 mA/cm2, open circuit voltage (Voc) = 0.67 V, fill factor (FF) = 62% and power conversion efficiency (PCE) = 4.64%. PCE increased 2.31 folds after incorporation of PBDT-DTNT into thin films. Larger polymer assemblies on bared-rGO nanosheets resulted in greater phase separations.
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