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Rafizadeh, Massoud,Tayebee, Reza,Amani, Vahid,Nasseh, Mohammad Korean Chemical Society 2005 Bulletin of the Korean Chemical Society Vol.26 No.4
Treatment of a solution of $CuCl_2$ in dimethyl phosphate (DMP) with DMSO under nitrogen atmosphere afforded to a light blue fluorescence powder. Slow evaporation of $H_2O$-DMSO solution of this powder resulted in blue-sky crystals of a new polymeric Cu(II) complex, with a unit cell composed of $Cu_2(DMP)_4$(DMSO), (1). The crystal and molecular structure of the complex acquired crystallographically. Compound (1) crystallizes in the monoclinic space group $P2_1$/n with a = 12.8920(11) $\AA$, b = 13.1966(11) $\AA$, c = 14.7926(13) $\AA$, $\alpha$ = 90$^{\circ}$, $\beta$ = 98.943(2)$^{\circ}$, $\gamma$ = 90$^{\circ}$, V= 2486.1(4) ${\AA}^3$, and Z = 4. A square pyramidal environment for the metal center was established by coordination of oxygen atoms of four bridging DMP ligands in the basal positions and binding a tri-centered oxygen atom of DMSO in the apical disposition of Cu(II). The sixth position was also affected by a weak interaction with the sulfur atom of another DMSO. The phosphorous atom in the bridging DMP was arranged in a deformed tetrahedron with (gg) conformation for methyl esters with $C_{2v}$ symmetry.
Massoud Rafizadeh*,Reza Tayebee*,Vahid Amani,Mohammad Nasseh 대한화학회 2005 Bulletin of the Korean Chemical Society Vol.26 No.4
Treatment of a solution of CuCl2 in dimethyl phosphate (DMP) with DMSO under nitrogen atmosphere afforded to a light blue fluorescence powder. Slow evaporation of H2O-DMSO solution of this powder resulted in blue-sky crystals of a new polymeric Cu(II) complex, with a unit cell composed of Cu2(DMP)4(DMSO), (1). The crystal and molecular structure of the complex acquired crystallographically. Compound (1) crystallizes in the monoclinic space group P21/n with a = 12.8920(11) Å, b = 13.1966(11) Å, c = 14.7926(13) Å, = 90o, = 98.943(2)o, = 90o, V= 2486.1(4) Å3, and Z = 4. A square pyramidal environment for the metal center was established by coordination of oxygen atoms of four bridging DMP ligands in the basal positions and binding a tri-centered oxygen atom of DMSO in the apical disposition of Cu(II). The sixth position was also affected by a weak interaction with the sulfur atom of another DMSO. The phosphorous atom in the bridging DMP was arranged in a deformed tetrahedron with (gg) conformation for methyl esters with C2v symmetry.
Ayub Elyasi,Taher Moradi,Javad Moharrami,Saeid Parnian,Akbar Mousazadeh,Sepideh Nasseh 국제구조공학회 2016 Structural Engineering and Mechanics, An Int'l Jou Vol.57 No.6
Tunneling is one of the challenging tasks in civil engineering because it involves a variety of decision making and engineering judgment based on knowledge and experience. One of the challenges is to construct tunnels in risky areas under shallow overburden. In order to prevent the collapse of ceilings and walls of a large tunnels, in such conditions, either a sequential excavation method (SEM) or ground reinforcing method, or a combination of both, can be utilized. This research deals with the numerical modeling of L-profiles and pipe fore-poling pre-support systems in the adit tunnel in northwestern Iran. The first part of the adit tunnel has been drilled in alluvial material with very weak geotechnical parameters. Despite applying an SEM in constructing this tunnel, analyzing the results of numerical modeling done using FLAC3D, as well as observations during drilling, indicate the tunnel instability. To improve operational safety and to prevent collapse, pre-support systems, including pipe fore-poling and L-profiles were designed and implemented. The results of the numerical modeling coupled with monitoring during operation, as well as the results of instrumentation, indicate the efficacy of both these methods in tunnel collapse prevention. Moreover, the results of modeling using FLAC3D and SECTION BUILDER suggest a double angle with equal legs (2L100×100×10 mm) in both box profile and tee array as an alternative section to pipe fore-poling system while neither L80×80×8 mm nor 2L80×80×8 mm can sustain the axial and shear stresses exerted on pipe fore-poling system.