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      • KCI등재

        Structure and Performances of xLiFePO4/C·(1 − x)Li3V2(PO4)3/C Cathode for Lithium-Ion Batteries by Using Poly(vinyl alcohol) as Carbon Source

        Chang-ling Fan,Wei-hua Zhang,Tao-tao Zeng,Ling-fang Li,Xiang Zhang,Shao-chang Han 대한화학회 2015 Bulletin of the Korean Chemical Society Vol.36 No.11

        Poly(vinyl alcohol), whose pyrolysis carbon possesses high conductivity of 8.88 × 10−1 S/cm, was used to synthesize xLiFePO4/C·(1 − x)Li3V2(PO4)3/C cathode. It was characterized by X-ray diffraction, scanning electron microscopy, conductivity, cyclic voltammetry, and galvanostatic charge and discharge experiments. Results show that LiFePO4/C and Li3V2(PO4)3/C coexists in the cathode. The particles sizes of 0.75LiFePO4/C·0.25Li3V2(PO4)3/C (x = 0.75) are much smaller than 100 nm due to the role of poly(vinyl alcohol). Its conductivity is 8.79 × 10−2 S/cm. The oxidative and reductive peaks in cyclic voltammetry are sharp and symmetrical. Their low potential gaps indicate that the extractions and insertions of lithium ion possess excellent reversibility. Its discharge capacities at 1 and 5 C are 141.1 and 100.1 mAh/g. The more Li3V2(PO4)3/C in cathode results in the deterioration of electrochemical performances due to its low theoretical capacity. It is concluded that poly(vinyl alcohol) is an effective carbon source in the preparation of xLiFePO4/C·(1 − x)Li3V2(PO4)3/C composite cathode with excellent performances.

      • KCI등재

        Controllable Synthesis of Co-Doped Spinel LiMn2O4 Nanotubes as Cathodes for Li-Ion Batteries

        Li-Xin Zhang,Yuan-Zhong Wang,Hong-Fang Jiu,Ya-Lei Wang,Yi-Xin Sun,Zhenzhong Li 대한금속·재료학회 2014 ELECTRONIC MATERIALS LETTERS Vol.10 No.2

        Spinel Co-LiMn2O4 nanotubes have been synthesized via solid state reaction using α-MnO2 nanotubes as selftemplates. The as-prepared powders were investigated by XRD, TEM, and galvanostatic discharge/charge analysis. The optimal doping amount was confirmed by galvanostatic charge/discharge measurements. The results indicate that about 67% of initial capacity (115 mAh/g) of LiMn2O4 nanotubes can be retained after 50 cycles. For Co-LiMn2O4 nanotubes, the initial reversible capacity is 126.6 mAh/g and 100 mAh/g can be maintained after 50 cycles. The capacitance retention rate of Co-LiMn2O4 nanotubes is as high as 79%. These results indicate that the doping Co can effectively improve circle stability and electrochemical performance of LiMn2O4 nanotubes.

      • SCOPUSKCI등재

        A Spectroscopic Study on Singlet Oxygen Production from Different Reaction Paths Using Solid Inorganic Peroxides as Starting Materials

        Li, Qingwei,Chen, Fang,Zhao, Weili,Xu, Mingxiu,Fang, Benjie,Zhang, Yuelong,Duo, Liping,Jin, Yuqi,Sang, Fengting Korean Chemical Society 2007 Bulletin of the Korean Chemical Society Vol.28 No.10

        Using solid inorganic peroxides (including Li2O2, Na2O2, SrO2 and BaO2) as starting materials, three reaction paths for singlet oxygen (1O2) production were developed and studied. Their 1O2 emission spectra in the near- IR region and visible region from these reaction paths were simultaneously recorded by a near-IR sensitive Optical Multichannel Analyzer and a visible sensitive Optical Spectrum Analyzer, respectively. The comparison of their 1O2 emission spectra indicated that: (1) in term of the efficiency for 1O2 production, the gasliquid- solid reaction path (in which Cl2 or HCl and H2O reacted with the solid inorganic peroxides suspension in CCl4) was prior to the gas-solid reaction path (in which Cl2 or HCl reacted with the solid inorganic peroxides suspension in CCl4), but was inferior to the gas-liquid reaction path (in which Cl2 or HCl reacted with the solid inorganic peroxides solution in H2O or D2O); (2) the alkali metal peroxides (such as Li2O2 and Na2O2) was prior to the alkaline earth metal peroxides (such as SrO2 and BaO2) as the solid reactants, and Cl2 was favorable than HCl as the gas reactant in efficiency for 1O2 production in these reaction paths.

      • KCI등재

        A Spectroscopic Study on Singlet Oxygen Production from Different Reaction Paths Using Solid Inorganic Peroxides as Starting Materials

        Qingwei Li*,Fang Chen,Weili Zhao,Mingxiu Xu,Benjie Fang,Yuelong Zhang,Liping Duo,Yuqi Jin,Fengting Sang 대한화학회 2007 Bulletin of the Korean Chemical Society Vol.28 No.10

        Using solid inorganic peroxides (including Li2O2, Na2O2, SrO2 and BaO2) as starting materials, three reaction paths for singlet oxygen (1O2) production were developed and studied. Their 1O2 emission spectra in the near-IR region and visible region from these reaction paths were simultaneously recorded by a near-IR sensitive Optical Multichannel Analyzer and a visible sensitive Optical Spectrum Analyzer, respectively. The comparison of their 1O2 emission spectra indicated that: (1) in term of the efficiency for 1O2 production, the gas-liquid-solid reaction path (in which Cl2 or HCl and H2O reacted with the solid inorganic peroxides suspension in CCl4) was prior to the gas-solid reaction path (in which Cl2 or HCl reacted with the solid inorganic peroxides suspension in CCl4), but was inferior to the gas-liquid reaction path (in which Cl2 or HCl reacted with the solid inorganic peroxides solution in H2O or D2O); (2) the alkali metal peroxides (such as Li2O2 and Na2O2) was prior to the alkaline earth metal peroxides (such as SrO2 and BaO2) as the solid reactants, and Cl2 was favorable than HCl as the gas reactant in efficiency for 1O2 production in these reaction paths.

      • KCI우수등재

        Home and Real Estate in Howards End: Marx, Mauss and Ruqaiya Hasan

        Fang Li 한국영어영문학회 2024 영어 영문학 Vol.70 No.1

        The epigraph of E.M. Forster’s Howards End, “Only Connect,” is a transitive verb without a direct object or even a subject: the verb connect is a connector, but there is no person to connect and nothing to connect to. Here I source the mysterious Connector and its Connect-ee by using three theories, all connected to historical materialism in one way or another. First, I use the concepts of C-M-C’ and M-C-M’ in Marx’s historical materialist study Capital to distinguish between characters concerned with the eponymous Howards End as home (typically uncountable) and those who treat it as “a house”, that is, a unit of real estate. Marx’s concepts, however, explain commodity circulation, not gift-giving. So I then link Marx’s historical materialist study to Mauss’s exploration of gift-giving in so-called “primitive societies”, which can be used to situate Forster’s argument in pre-capitalist times going back at least as far as Beowulf. But Marx and Mauss are neither literary nor linguistic theorists. So, finally, I apply Hasan’s understanding of three levels of patterning in verbal art: verbalization (text), symbolic articulation (patterns of text that realize characters, events, situations), and finally theme (some theory of human social being). In this way, I try to explain Forster’s textual choices by his symbolic articulation into a contrast of two value forms and his symbolic articulation by the theme of connecting real estate and home.

      • KCI등재

        Protection of chickens against infectious bronchitis virus with a multivalent DNA vaccine and boosting with an inactivated vaccine

        Fang Yan,Zhong Li,Yongting Hu,Jianyang Qiu,Wenxin Lei,Wenhui Ji,Xuying Li,Qian Wu,Xiumin shi,Yujun Zhao 대한수의학회 2013 Journal of Veterinary Science Vol.14 No.1

        The protective efficacy of DNA plasmids encoding avian infectious bronchitis virus (IBV) S1, N, or M protein was investigated in chickens. Chickens were inoculated monovalently (with plasmid pVAX1-16S1, pVAX1-16M, or pVAX1-16N alone) or multivalently (combination of the three different plasmids, pVAX1-16S1/M/N). A prime-boost immunization protocol against IBV was developed. Chickens were immunized with the multivalent DNA vaccine twice and then boosted with an inactivated vaccine once. Antibody titers of the chickens immunized with pVAX1-16S1/M/N were much higher than those of the monovalent groups (p < 0.01). A protective rate up to 90% was observed in the pVAX1-16S1/M/N group. The serum antibody titers in the prime-boost birds were significantly higher than those of the multivalent DNA vaccine group (p < 0.01) but not significantly different compared to the inactivated vaccine group at 49 days of age. Additionally, the prime-boost group also showed the highest level of IBV-specific cellular proliferation compared to the monovalent groups (p < 0.01)but no significant difference was found compared to the multivalent DNA vaccine group, and the prime-boost group completely protected from followed viral challenge.

      • KCI등재

        A novel UiO-66-NH2/graphene oxide composite thin membrane for retarding membrane wetting in membrane distillation

        Fangqing Li,Lin Chen,Yufei Wei,Zhiwei Yin,Keying Que 한국공업화학회 2023 Journal of Industrial and Engineering Chemistry Vol.123 No.-

        Membrane distillation (MD) is considered an emerging desalination technology. However, the presenceof surfactants allows liquid to penetrate the membrane, resulting in membrane wetting, which hindersthe commercialization of MD. In this study, we use very few modified materials to prepare novel Janusthin membranes that immobilize modified materials (graphene oxide (GO) and UiO-66-NH2) on polytetrafluoroethylene(PTFE) hydrophobic base membranes via crosslinkers. The composite thin membraneproperties with eight different ratios and contents of GO and UiO-66-NH2 were fabricated and testedby a feed solution of sodium chloride containing a high concentration of sodium dodecyl sulfate. An optimalratio of Janus membrane with high flux without affecting the effluent water quality was obtained. The Janus membrane exhibited excellent anti-wetting properties compared to the original PTFE membrane. A desalination rate of up to 99.9% was still available even under 48 h of long-term operating conditionsby maintaining a flux of approximately 21.2 L/(m2h). The anti-wetting mechanism of thismembrane was further confirmed by the modified XDLVO model. It suggested that the novel Janus membranecould be a highly promising substitute to the MD process for the resource-based treatment ofsurfactant-containing wastewater, which played an important role in promoting its application.

      • KCI등재후보

        Experimental study on the cable rigidness and static behaviors of AERORail structure

        Fangyuan Li,Peifeng Wu,Dongjie Liu 국제구조공학회 2012 Steel and Composite Structures, An International J Vol.12 No.5

        This paper presented a new aerial platform-AERORail for rail transport and its structure evolution based on the elastic stiffness of cable; through the analysis on the cable properties when the cable supported a small service load with high-tensile force, summarized the theoretical basis of the AERORail structure and the corresponding simplified analysis model. There were 60 groups of experiments for a single naked cable model under different tensile forces and different services loads, and 48 groups of experiments for the cable with rail combined structure model. The experimental results of deflection characteristics were compared with the theoretical values for these two types of structures under the same conditions. It proved that the results almost met the classical cable theory. The reason is that a small deflection was required when this structure was applied. After the tension increments tests with moving load, it is verified that the relationships between the structure stiffness and tension force and service load are simple. Before further research and applications are made, these results are necessary for the determination of the reasonable and economic tensile force, allowable service load for the special span length for this new platform.

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