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        Polar poly(n‑butyl acrylate)‑g‑polyacrylonitrile elastomer with high temperature elasticity and healability as flexible electronic substrate

        Yuzhu Zheng,Deli Xu,Shiyou Tian,Manli Li,Wenwen Wang,Ke Liu 한국의류학회 2021 Fashion and Textiles Vol.8 No.1

        In this work, graft copolymer poly (n-butyl acrylate)-g-polyacrylonitrile with poly (n-butyl acrylate) as backbones and polyacrylonitrile as side chains (PnBA-g-PAN) was synthesized by macromonomer method and emulsion polymerization. The macromonomer was synthesized by atom transfer radical polymerization and end-group modification. The chemical structures and thermal properties of macromonomer and graft copolymer were investigated by FTIR, GPC, NMR and TGA, etc. The mechanical properties of graft copolymer elastomer was also measured by uniaxial tensile test. Rheological properties at different temperature and mechanical property demonstrated that graft copolymer elastomer possessed elasticity until 180 oC because of cyclization of cyano groups. Ag nanowires@PnBA-g-PAN composite elastomer was developed, and the resulted material exhibited autonomic healing property on account of segments’ flexibility and dynamic interaction between Ag nanowires (AgNWs) and cyano groups. This is a general method for generation of elastomer with high temperature elasticity and fast self-healing. The composite elastomer has potential application in flexible electronic conductor.

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        Exploratory Study on Improving Bond Strength of Shotcrete in Hot and Dry Environments of High Geothermal Tunnels

        Shengai Cui,Deli Xu,Pin Liu,Yuezhong Ye 대한토목학회 2017 KSCE JOURNAL OF CIVIL ENGINEERING Vol.21 No.6

        To solve the problem on the serious loss of bond strength of shotcrete in hot and dry environments, the measures for improving the bond strength were explored by mixing mineral admixtures or fiber materials into shotcrete mixture. The bond strengths between shotcrete and rock in hot and dry environments were measured by splitting method, and macroscopic, mesoscopic and microscopic analyses were carried out on shotcrete specimens. The results show that: in hot and dry environments, the bond strengths all decrease when mixed with mineral admixtures, and especially for the fly ash, with which the bond strength of shotcrete decreases by 36.7%. Mixing polypropylene fibers into shotcrete makes its bond strength decrease by 10.2%, but for steel fibers, it will be improved by 41.8% compared with basic mix proportion. Moreover, according to submicroscopic measurement and microscopic analysis, the influence mechanisms of mineral admixtures and fiber materials have been explored to some extent. Therefore, it’s feasible and effective to improve the bond strength by adding steel fibers in hot and dry environment.

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