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      • KCI등재후보

        Edge-to-vertex detour number of a graph

        A. P. Santhakumaran,S. Athisayanathan 장전수학회 2011 Advanced Studies in Contemporary Mathematics Vol.21 No.4

        For two vertices u and v in a graph G = (V,E), the detour distance D(u, v)is the length of a longest u–v path in G. A u–v path of length D(u, v) is called a u–v detour. For subsets A and B of V , the detour distance D(A,B)is defined as D(A,B) = min{D(x, y) : x ∈ A, y ∈ B}. A u–v path of length D(A,B) is called an A–B detour joining the sets A, B ⊆ V where u ∈ A and v ∈ B. A vertex x is said to lie on an A–B detour if x is a vertex of an A–B detour. A set S ⊆ E is called an edge-to-vertex detour set if every vertex of G is incident with an edge of S or lies on a detour joining a pair of edges of S. The edge-to-vertex detour number dn_2(G) of G is the minimum order of its edge-to-vertex detour sets and any edge-to-vertex detour set of order dn_2(G) is an edge-to-vertex detour basis of G. Certain general properties of these concepts are studied. The edge-to-vertex detour numbers of certain classes of graphs are determined. Its relationship with the detour diameter is discussed and it is proved that for each triple D, k, q of integers with 2 ≤ k ≤ q − D + 2 and D ≥ 4 there is a connected graph G of order p with detour diameter D and dn_2(G) = k. It is also proved that for any three positive integers a, b, k with k ≥ 2 and a < b ≤ 2a, there is a connected graph with detour radius a, detour diameter b and dn_2(G) = k.

      • A study of nerve agent model organophosphonate binding with manganese-A<sub>2</sub>B-corrole and -A<sub>2</sub>B<sub>2</sub>-porphyrin systems

        Kim, K.,Kim, I.,Maiti, N.,Kwon, S.J.,Bucella, D.,Egorova, O.A.,Lee, Y.S.,Kwak, J.,Churchill, D.G. Pergamon Press 2009 Polyhedron Vol.28 No.12

        Herein the synthesis and binding studies of novel trans-A<SUB>2</SUB>B-corrole and trans-A<SUB>2</SUB>B<SUB>2</SUB>-porphyrin derivatives are presented in comparing manganese(III)-organophosphonate (OP) binding (e.g., M<SUP>n+</SUP>←O?PR(OR)<SUB>2</SUB>) capabilities. H<SUB>3</SUB>(PFP-VC) [PFP-VC=5,15-di(pentafluorophenyl)-10-(3-vinylphenyl)corrolate] was synthesized by way of literature procedures and was characterized by a variety of 2-D NMR spectroscopic techniques and single-crystal X-ray diffraction. These compounds represent the first example of 3-vinyl-phenyl-containing meso-substituted corroles or porphyrins. Mn(PFP-VC) (3) was treated separately with (CH<SUB>3</SUB>CH<SUB>2</SUB>O)<SUB>2</SUB>P?O(C<SUB>3</SUB>H<SUB>6</SUB>NMe<SUB>2</SUB>), (C<SUB>4</SUB>H<SUB>9</SUB>O)<SUB>2</SUB>P?O(Me), (C<SUB>2</SUB>H<SUB>5</SUB>O)<SUB>2</SUB>P?O(CH<SUB>2</SUB>COCH<SUB>3</SUB>), (CH<SUB>3</SUB>CH<SUB>2</SUB>O)<SUB>2</SUB>P?O(Me), to give 1:1 adducts, as determined by UV-Vis spectroscopy (Job Plot), giving a red shift; Ph<SUB>3</SUB>P?O, was also found to bind, but very weakly. The trans-A<SUB>2</SUB>B<SUB>2</SUB>-porphyrin analogue Mn(PFP-VP) (4) was also prepared by way of a literature procedure; related binding studies gave 1:1 organophosphonate-Mn(PFP-VP) adducts (Job Plot). A clean blue shift occurred for the Mn-porphyrins at higher organophosphonate loadings (K<SUB>a</SUB> values: 6.7 (0.9)-11.9 (0.4)M<SUP>-1</SUP>). DFT geometry optimizations of O?P(OMe)<SUB>2</SUB>Me binding and formal Mn-O or P-O cleavage products in the unsubstituted neutral Mn-corrolato and -porphyrinato systems with a range of metal-based spin states revealed greatest stability in formal phosphoryl oxygen binding (energies: 11-13kcal/mol) for the Mn-corrole (singlet); the Mn-porphyrin (sextet) was also quite stable.

      • THE UNAM-KIAS CATALOG OF ISOLATED GALAXIES

        Herná,ndez-Toledo, H. M.,,zquez-Mata, J. A.,Martí,nez-Vá,zquez, L. A.,Choi, Yun-Young,Park, Changbom American Institute of Physics 2010 The Astronomical journal Vol.139 No.6

        <P>A new catalog of isolated galaxies from the Sloan Digital Sky Survey Data Release 5 (SDSS DR5) is presented. A total of 1520 isolated galaxies were found in 1.4 sr of sky. The selection criteria in this UNAM-KIAS catalog are a variation on the criteria developed by Karachentseva, including full redshift information. Through an image processing pipeline that takes advantage of the high-resolution (~0<img entity='farcs' SRC='http://ej.iop.org/icons/Entities/farcs.gif' ALT='farcs' ALIGN='BOTTOM' />4 pixel<SUP>–1</SUP>) and high dynamic range of the SDSS images, a uniform g-band morphological classification for all these galaxies is presented. We identify 80% (Sa-Sm) spirals (50% later than Sbc types) on one hand, and a scarce population of early-type E (6.5%) and S0 (8%) galaxies amounting to 14.5% on the other hand. This magnitude-limited catalog is ~80% complete at 16.5, 15.6, 15.2, 14.6, and 14.4 mag in the ugriz bands, respectively. Some representative physical properties including SDSS magnitudes and color distributions, color-color diagrams, absolute magnitude-color, and concentration-color diagrams as a function of morphological type are presented. The UNAM-KIAS Morphological Atlas is also released along with this paper. For each galaxy of a type later than Sa, a mosaic is presented that includes (1) a g-band logarithmic image, (2) a g-band filtered-enhanced image where a Gaussian kernel of various sizes was applied, and (3) a red giant branch color image from the SDSS database. For E/S0/Sa galaxies, in addition to the images in (1), (2), and (3), plots of r-band surface brightness and geometric profiles (ellipticity ε, position angle PA, and A<SUB>4</SUB>/B<SUB>4</SUB> coefficients of the Fourier series expansions of deviations of a pure ellipse) are provided. The size of the sample, the redshift completeness, the availability of high-quality multicolor photometric data and detailed morphological and spectroscopic information make the UNAM-KIAS catalog of isolated galaxies a suitable sample to address important issues such as (1) comparative studies of environmental effects, (2) constraining the currently competing scenarios of galaxy formation and evolution, (3) the nature and evolution of elliptical and spiral galaxies in the field, (4) the spectral properties of a statistically significant number of isolated galaxies and their evolution as a function of redshift, and (5) the fraction of active galactic nuclei in isolated environments, among other important topics. The optimization and estimation of new structural parameters as well as important information to complement existing ones in other wavelengths is being carried out.</P>

      • KCI등재

        2G HTS wire with enhanced engineering current density attained through the deposition of HTS layer with increased thickness

        A. Molodyk,A. Markelov,A. Valikov,V. Chepikov,A. Petrzhik,B. Massalimov,P. Degtyarenko,R. Uzkih,A. Soldatenko,Kideok Sim,Soon Hwang 한국초전도.저온공학회 2019 한국초전도저온공학회논문지 Vol.21 No.4

        2G HTS wire with high engineering current density is desired for applications where compact, high power density superconducting equipment is important. We have succeeded in enhancing engineering current density of commercial SuperOx 2G HTS wire based on GdBCO by increasing the HTS layer thickness without fast degradation of the HTS film microstructure. This was possible after improving the temperature uniformity along the HTS film deposition zone. In particular, the wire engineering current density was increased from 700-770 A/mm2 (for a 65 µm-thick wire without stabilisation) or 430-480 A/mm2 (for a 105 µm-thick stabilised wire) at the beginning of this study to almost 1200 A/mm2 (for a 67 µm-thick wire without stabilisation) or 770 A/mm2 (for a 107 µm-thick stabilised wire) at completion of this study.

      • KCI등재

        Comparative and Structural Analysis of the Interaction between β-Lactoglobulin type A and B with a New Anticancer Component (2,2'-Bipyridin n-Hexyl Dithiocarbamato Pd(II) Nitrate)

        A. Divsalar,A. A. Saboury*,H. Mansoori-Torshizi,B. Hemmatinejad 대한화학회 2006 Bulletin of the Korean Chemical Society Vol.27 No.11

        The interaction between whey carrier protein b-lactoglobulin type A and B (BLG-A and -B) and 2,2'-bipyridin n-hexyl dithiocarbamato Pd(II) nitrate (BPHDC-Pd(II)), a new heavy metal complex designed for anticancer property, was investigated by fluorescence spectroscopy combined with chemometry and circular dichroism (CD) techniques. A strong fluorescence quenching reaction of BPHDC-Pd(II) to BLG-A and -B was observed. Hence, BPHDC-Pd(II) complex can be bound to both BLG-A and -B, and quench the fluorescence spectra of the proteins. The quenching constant was determined using the modified Stern-Volmer equation. The binding parameters were evaluated by fluorescence quenching method. The results of binding study provided evidences presence of two and three sets of binding sites on the BLG-B and -A, respectively, for BPHDC-Pd(II) complex. Using fluorescence spectroscopy and chemometry, the ability of BLG-A and -B to form an intermediate upon interaction with BPHDC-Pd(II) complex was assessed. CD studies displayed that under influence of different concentrations of BPHDC-Pd(II) complex, the regular secondary structure of BLG-B had no significant changes, whereas for BLG-A a transition from a-helix to b-structure was appeared. The results for both of BLG-A and -B displayed that BPHDC-Pd(II) complex can induce a conformational transition from the native form to an intermediate state with a slightly opened conformation, which is detectable with chemometry analyses.

      • KCI등재

        A 12-MHz CW RFQ for the AEBL Project

        D. L. Schrage,P. N. Ostroumov,A. Barcikowski,D. Fallin,A. A. Kolomiets 한국물리학회 2008 THE JOURNAL OF THE KOREAN PHYSICAL SOCIETY Vol.52 No.3

        The Advanced Exotic Beam Laboratory (AEBL) at the Argonne National Laboratory (ANL) will provide a research facility for studies of nuclear phenomena by using beams of short-lived isotopes for research on the nature of nucleonic matter and the origin of the elements, for tests of the Standard Model, for applications in medicine and industry, and for other applied physics research. The proposed design of the AEBL driver linac evolved from the Rare Isotope Accelerator (RIA) project. The AEBL will be a CW linac capable of accelerating uranium ions up to 200 MeV/u and protons to 580 MeV with 400 kW beam power. The AEBL facility also includes a post-accelerator which is designed for acceleration of radioactive ions with charge-to-mass ratios in the range from 1/238 to 1/6. Very low charge-state ions can be most eciently bunched and accelerated by using normally-conducting radio-frequency quadrupole (RFQ) for the rst few MV of the post accelerator. A two-meter long, 12-MHz CW RFQ was designed, built, and tested in the late 1990s as the rst section of a three-section RFQ [18]. This RFQ achieved inter-electrode voltages of 110 kV CW (the peak surface eld was 15 MV/m) and accelerated beams with A/q as large as 132 (132Xe). The AEBL requires a similar RFQ for the post-acceleration of singly-charged unstable nuclides. Our plan is to replace the vanes of this RFQ with a design that incorporates a stronger focusing and that will achieve a higher peak surface eld (16 MV/m) at 82.2-kV inter-vane voltage. The objectives of this project are 1. to conrm the possibility of a low injection energy of 0.4 keV/u which signicantly reduces the voltage required for a high-voltage deck; 2. to test the highest possible peak surface eld on the RFQ electrodes designed for the lowest frequency of 12 MHz compared to existing RFQs worldwide; 3. to provide a technical base for the design of a post-accelerator for the future Advanced Exotic Beam Facility. At the present time, the design is complete, and the fabrication of the 12 MHz RFQ is scheduled to commence in October 2007 with testing planned in 2008. The physics and engineering design of the RFQ is discussed. The Advanced Exotic Beam Laboratory (AEBL) at the Argonne National Laboratory (ANL) will provide a research facility for studies of nuclear phenomena by using beams of short-lived isotopes for research on the nature of nucleonic matter and the origin of the elements, for tests of the Standard Model, for applications in medicine and industry, and for other applied physics research. The proposed design of the AEBL driver linac evolved from the Rare Isotope Accelerator (RIA) project. The AEBL will be a CW linac capable of accelerating uranium ions up to 200 MeV/u and protons to 580 MeV with 400 kW beam power. The AEBL facility also includes a post-accelerator which is designed for acceleration of radioactive ions with charge-to-mass ratios in the range from 1/238 to 1/6. Very low charge-state ions can be most eciently bunched and accelerated by using normally-conducting radio-frequency quadrupole (RFQ) for the rst few MV of the post accelerator. A two-meter long, 12-MHz CW RFQ was designed, built, and tested in the late 1990s as the rst section of a three-section RFQ [18]. This RFQ achieved inter-electrode voltages of 110 kV CW (the peak surface eld was 15 MV/m) and accelerated beams with A/q as large as 132 (132Xe). The AEBL requires a similar RFQ for the post-acceleration of singly-charged unstable nuclides. Our plan is to replace the vanes of this RFQ with a design that incorporates a stronger focusing and that will achieve a higher peak surface eld (16 MV/m) at 82.2-kV inter-vane voltage. The objectives of this project are 1. to conrm the possibility of a low injection energy of 0.4 keV/u which signicantly reduces the voltage required for a high-voltage deck; 2. to test the highest possible peak surface eld on the RFQ electrodes designed for the lowest frequency of 12 MHz compared to existing RFQs worldwide; 3. to provide a technical base for the design of a post-accelerator for the future Advanced Exotic Beam Facility. At the present time, the design is complete, and the fabrication of the 12 MHz RFQ is scheduled to commence in October 2007 with testing planned in 2008. The physics and engineering design of the RFQ is discussed.

      • SCISCIESCOPUS

        A spick-and-span approach to the immobilization of horseradish peroxidase on Au nanospheres incorporated with a methionine/graphene biomatrix for the determination of endocrine disruptor bisphenol A

        Vilian, A.T. Ezhil,Giribabu, Krishnan,Choe, Sang Rak,Muruganantham, Rethinasabapathy,Lee, Hoomin,Roh, Changhyun,Huh, Yun Suk,Han, Young-Kyu Elsevier Sequoia 2017 Sensors and actuators. B Chemical Vol.251 No.-

        <P><B>Abstract</B></P> <P>In the present study, we employ a straightforward, benign strategy to prepare thiol-functionalized reduced graphene oxide (S-RGO) using methionine as the sulphur source and reducing agent. The immobilization of horseradish peroxidase (HRP) over the AuNPs/S-RGO was developed by incorporating AuNPs on the S-RGO surface. The fabricated HRP/AuNPs/S-RGO electrode exhibits a remarkable decrease in the overpotential and a significantly increased oxidation peak current of bisphenol A (BPA) compared with the bare glassy carbon electrode (GCE) and AuNPs/S-RGO electrode. The biosensor shows an excellent amperometric analytical performance with a low detection limit of 2.6×10<SUP>−12</SUP> M and a linear range from 2.0×10<SUP>−11</SUP> to 1.18×10<SUP>−9</SUP> M, with the response time <2s for BPA. From the results, the apparent Michaelis-Menten constant was calculated as 8.14nM. The HRP/AuNPs/S-RGO biosensor exhibited faster response, adequate storage stability, inexpensive, simple fabrication with disposability, satisfactory reproducibility and repeatability, and outstanding selectivity. Finally, the constructed biosensor was utilized successfully for detecting BPA in tomato juice and milk samples with acceptable results.</P> <P><B>Highlights</B></P> <P> <UL> <LI> HRP/AuNPs/S-RGO biocomposite has been prepared to determine bisphenol A. </LI> <LI> The AuNPs/S-RGO is a promising platform for HRP immobilization. </LI> <LI> The biosensor exhibits excellent stability, reproducibility and high selectivity. </LI> <LI> It exhibits LOD of 2.6×10<SUP>−12</SUP> in a wide linear range from 2.0×10<SUP>−11</SUP> to 1.18×10<SUP>−9</SUP> M. </LI> <LI> It detects bisphenol A in real samples such as tomato juice and milk. </LI> </UL> </P> <P><B>Graphical abstract</B></P> <P>[DISPLAY OMISSION]</P>

      • Van der Waerden's continuity theorem for the commutator subgroups of connected Lie groups and Mishchenko's conjecture

        A. I. Shtern 장전수학회 2006 Advanced Studies in Contemporary Mathematics Vol.13 No.2

        As was proved by van der Waerden in 1933, every finite-dimensional locally bounded representation of a semisimple compact Lie group is continuous. In this paper, with the help of an earlier result of the author claiming that the van der Waerden theorem holds for any connected semisimple Lie group, it is proved that every locally bounded finite-dimensional representation of a connected Lie group is continuous on the commutator subgroup of the group; moreover, it turns out that a connected Lie group satis¯es the assertion of the van der Waerden theorem (i.e., all locally bounded finite-dimensional representations of the group are continuous) if and only if the group is perfect (i.e., coincides with the commutator subgroup). Thus, for perfect connected linear Lie groups, the structure of (totally) bounded sets de¯nes the topology, and any boundedness-preserving group isomorphism of a perfect connected linear Lie group onto another perfect connected linear Lie group is automatically continuous. To study this phenomenon, the notion of discontinuity group of a locally bounded finite-dimensional representation of a topological group is introduced and studied. The notion of local boundedness of a representation is naturally related to the notion of point oscillation (at the identity element of the group) introduced by the author in 2002. According to a conjecture expressed by A. S. Mishchenko, the finite-dimensional representations of Lie groups can take only three possible values for the (reasonably defined) point oscillation, namely, 0, 2, and 1. We prove the validity of the conjecture. As a corollary, we prove that the class of connected Lie groups for which the point oscillation of a finite-dimensional representation can take only two values, 0 and 1, is the very class of perfect connected Lie groups. Related open problems are indicated.

      • KCI등재후보

        지역사회간호사업의 내용 및 평가에 관한 연구 : 일부 저소득층 지역사회를 중심으로

        방매륜,한영란 이화여자대학교 간호과학연구소 1990 Health & Nursing Vol.2 No.-

        All people aspire to a life of health from birth to death. Health is both a right and a responsibility. Health as a human right is expressed in the WHO stated purpose of "Health for All by the Year 2000." In Korea an unequal distribution of health services is related to the ever increasing cost of medical care due to the professionalization of health services, the costly training and education of health care professionals and the soaring costs of medical equipment. It is now generally accepted that the health care wanted and needed by the people is first and foremost the activation and expansion of equally accessable primary health care. This study was carried out by the nursing staff of the Community Health Nursing Clinic of the Social Welfare Centre of Ewha Womans Uni versity. The research problems included the identification of principles from theories supportive of community health nursing services and of criteria from these theories useful for the evaluation of the services and as objectives to guide future services : the description of the i development of the services with a selected community group over a three year period : the evaluation of those services using the criteria developed from the theories and the recommendation of guide - lines for the planning and practice of these and similar community health nursing services. The purpose was to develop a community health nursing model for the expansion and activation of primary health care. The population was a group of women living with their families in a crowded poor area in one district in the Mapho area of Seoul. The women had organized as a mothers association to strength - en their autonomy and decision-making power. The study describes the process whereby the nurses and women worked together from 1987 to 1989 and how the women changed to become active and critical participants in decision making about their health and the nursing services. A theoretical framework was developed to support and guide the practice using Rogers Science of Unitary Human Beings, concepts of Primary Health Care from Health for All by the Year 2000, the health challenges, promotion mechanisms and implementation strategies of the Framework for Health Promotion of the Canadian Ministry of Health and Welfare and principles from the Ottawa Charter for Health Promotion. Four criteria for evaluation of the nursing services were developed from the concepts and principles of the theories. They were : 1. that a nursing theory worthy of providing a world view of the complexity of interrelationships between the human and environmental fields involved in community health nursing - the Science of Unitary Human Beings suplemented by concepts from Primary Health Care and Health Promotion-be used to direct services ; 2. that the people of a community participate in full partnership with service agencies in making decisions regarding the planning, provision and evaluation of their health care ; 3. that both the nurses and people be empowered , and 4. that the community health services be strengthened. Evaluation using the criteria demonstrated the effectiveness of the services in achieving the valued objectives of theory-directed care, empowerment and participation with this population, but relative ineffectiveness in achieving change in official public health policies which would strengthen services or promote a more healthy environment. The four criteria were proposed for use in building more concrete objectives for community health nursing services and the process as helpful for developing future services.

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