충북 괴산 덕평리 일대 흑색셰일 및 흑색점판암기원 토양의 점토광물 조성 및 중금속원소의 분산

전철민,문희수,최선경,우남칠,Chon, Chul-Min,Moon, Hi-Soo,Choi, Sun Kyung,Woo, Nam Chil 대한자원환경지질학회 1997 자원환경지질 Vol.30 No.6

Concentrations of several heavy metals in soils derived from black shale and slate have been reported to be higher than the average concentrations in non-polluted soils. This study describes and characterizes soil minerals, and investigates the distribution of heavy metals in soils, and then examines their relationship. Soils in the study area are mainly consist of guartz and feldspars with minor amount of kaolin, illite, vermiculite, chlorite and illite-vermiculite interstratified minerals. Mineral compositions are similar in mountain-, farmland-, and paddy-soils. The residual soils derived from sandy phyllites contain less illites than those from black shale and black slate. Heavy metals appear to be more concentrated in soils than in rocks. The concentrate ratios in soils to rocks ranges 1.1 times for Cr, 2 for Cu, 1.4 for Ni. The contour maps of Cd, Zn, Pb, Cu contents using 0.43N $HNO_3$-extraction imply that these elements are highly concentrated in the soils near the past uranium exploration region, coal seams, black slate beds and tailings than other parts of the study area. The proportions of the day in most soils are less than 10%. In spite of small proportions of the clay, the concentrations of heavy metals from clay fractions to the total concentrations are high: 1~2.4 times for Co, 1.4~2.5 for Cu, 1.2~2.6 for Ni, 1~5 for Pb, 1~2.7 for Zn and 1.6~1.8 for Cr and V. The contents of organic carbons in clay fractions are also 1.5~3.9 times higher than in silt and sand fractions. Cu, Pb and organic carbons show positive relationship in all size fractions. In the size-fractionated soil profile samples, the contents of heavy metals and organic carbons show analogous trends with depth. For the clay fractions of soil profile samples, the contents of heavy metals with depth have analogous trends to abundances of vermiculites, which have the high CEC in main clay minerals.

대전 산업단지 지하수의 6가 크롬 오염 및 확산 평가

전철민,문상호,안주성,김영식,원종호,안경환,Chon, Chul-Min,Moon, Sang-Ho,Ahn, Joo-Sung,Kim, Yung-Sik,Won, Jong-Ho,Ahn, Kyoung-Hwan 대한자원환경지질학회 2007 자원환경지질 Vol.40 No.4

본 연구의 목적은 대전 산업단지 폐수종말처리장 내 국가지하수관측망(대전, 문평)의 6가 크롬 오염지하수의 오염 현황을 파악하고 그 확산 여부를 평가하는 것이다. 대전(문평) 관측소에서 나타나는 6가 크롬($Cr^{+6}$) 수질장해의 원인을 규명하고 6가 크롬의 오염 범위를 파악하기 위해 금번 연구에서는 보조 관측정을 설치 활용하였다. 수질분석 결과, 6가 크롬이 $3.2{\sim}4.5mg/L$ 정도 검출됨으로써 6가 크롬에 의한 관측소 충적공의 수질오염은 지속되고 있음이 파악되었다. 그러나 관측소의 암반관정 및 0.05mg/L 수질기준 이하의 농도를 보이는 MPH-1과 3번 관측공을 제외한 주변 관측공에서는 검출되지 않았다. 따라서 6가 크롬 및 총 크롬 함량의 오염 범위는 관측소 충적층 관정 인근에 한정되어 나타나고 있는 것으로 파악되었다. 또한 신규 5개 보조 관측정에서 채취한 77개의 시추 코어 및 슬라임 시료 모두에서 수용성/교환성 6가 크롬이 검출 한계(0.01mg/L) 이하로 나타나, 오염이 관측된 관측소 관정 주변의 토양 및 풍화토에서는 직접적으로 6가 크롬의 오염원이 확인되지 않았다. 지하수 수질분석 및 코어시료 분석 결과, 그 오염원의 중심 및 오염 확산 범위는 관측소 주위 반경 100m 이내로 매우 한정되는 것으로 판단되며 그 확산의 범위가 매우 좁을 것으로 예상된다. 시추조사 결과, 폐수종말처리장 부지조성 당시의 불량 매립층이 확인되었으며, 이러한 불량 매립산업폐기물이 관측소 인근의 6가 크롬 수질장해 원인으로 추론된다. 지표매질의 6가 크롬 자연저감능 평가를 위해 초기 농도 5mg/L Cr(VI)을 이용한 6가 크롬 유효 환원능을 분석하였다. 그 결과, 암회색 점토층에서 각각 58%, 66%, 64% 정도의 높은 6가 크롬 저감율을 보였으며, 이는 유기물 함량과 상호 관련이 있을 것으로 판단되었다. 비포화대/충적층 매질에 대한 6가 크롬 함량 및 자연저감 능력의 정량적 평가 결과, 매질에 의한 6가 크롬의 자연 저감능이 확인되었으며 관정 주변으로의 오염 확산은 충분히 제어되고 있는 것으로 판단된다. 그러나 시추 관측정 및 기설 관정의 수가 부족했기 때문에 매우 제한적인 선택적 유동(preferential flow) 경로에 의한 확산 가능성을 완전히 배제할 수 없다. 정기적인 양수작업을 통하여 지하수에 부화된 6가 크롬의 농도를 지속적으로 제거하고 관측소 주변에 설치된 보조 관측정들을 지속적으로 활용하여 6가 크롬의 농도 변화 추이 및 시간의 흐름에 따른 오염 확산 여부를 지속적으로 관측하고 감시하는 방안이 필요할 것으로 판단된다. The objective of this research was to characterize the fate and transport of Cr(VI) contaminated groundwater in the Daejeon industrial area. Five subsidiary monitoring wells were newly installed and two existing wells were utilized for the investigation and the reduction process of Cr(VI) contaminated groundwater of the Daejeon(Mun-pyeong) national groundwater monitoring station. The Cr(VI) concentrations at the shallow aquifer well of the station were in the range of 3.2-4.5 mg/L indicating continuous contamination. However, Cr was not detected at the deep bedrock well and the other monitoring wells except MPH-1 and 3. The Cr(VI) concentrations of MPH-1 and MPH-3 were below the drinking water guideline value (0.05 mg/L). Therefore, the plume of the Cr(VI) contaminated groundwater was predicted to be confined within the narrow boundary around the station. The soluble/exchangeable Cr(VI) concentrations were below the detection limit in all core and slime samples taken from the five newly installed wells. Although the exact source of contamination was not directly detected in the study area, the spatial Cr(VI) distribution in groundwater and characteristics of the core samples indicated that the source and the dispersion range were confined within the 100 m area from the monitoring station. The contamination might be induced from the unlined landfill of industrial wastes which was observed during the installation of an subsidiary monitoring well. For the evaluation of the natural attenuation of Cr(VI), available reduction capacities of Cr(VI) with an initial concentration of 5 mg/L were measured in soil and aquifer materials. Dark-gray clay layer samples have high capacities of Cr(VI) reduction ranging from 58 to 64%, which is obviously related to organic carbon contents of the samples. The analysis of reduction capacities implied that the soil and aquifer materials controlled the dispersion of Cr(VI) contamination in this area. However, some possibilities of dispersion by the preferential flow cannot be excluded due to the limited numbers of monitoring wells. We suggest the removal of Cr(VI) contaminated groundwater by periodical pumping, and the continuous groundwater quality monitoring for evaluation of the Cr(VI) dispersion should be followed in the study area.

유방 초음파 검사에서 석회화 유발 환경에 따른 반짝 허상과 팸텀을 활용한 영상 변화에 관한 연구

전철민 한국방사선학회 2023 한국방사선학회 논문지 Vol.17 No.5

Breast ultrasonography is difficult to image in fatty breasts and to find micro-calcification, but the discovery of micro-calcification is very important for breast cancer screening. Among the color Doppler artifact of ultrasound, twinkle artifact mainly occur on strong reflectors such as stones or calcification in images, and evaluation methods using them are clinically being used. In this study, we are conducting experiments on the color Doppler settings of ultrasound equipment, such as repetition frequency, ensemble, persist, wall filtering, smoothing, linear density, and dissociation value, by producing a breast simulation phantom using the largest amount of calcium phosphate among breast implants. The purpose of this study was to improve the contrast of twinkle artifact in breast ultrasound examinations and to maximize their use in clinical practice. As a result, the pulse repetition frequency occurred in the range of 3.6 kHz to 7.2 kHz, and did not occur above 10.5 kHz. For ensembles, twinkle artifact occurred in all sizes of calcification under low conditions, and in threshold settings, the twinkle artifact increased slightly only under 80 to 100 conditions, and did not occur in 1 mm size calcification. Persist, wall filter, smoothing, and line density settings did not have much meaning in the setting variable because conditions did not increase by condition, and pulse repetition frequency, ensemble, and thresholds had the greatest impact on the twinkling artifact image. This study is expected to help examiners select optimal conditions to effectively increase twinkle artifact by adjusting color Doppler settings.

중성자분말회절법을 이용한 흑운모의 Rietveid Structure Refinement

전철민,김신애,문희수 대한자원환경지질학회 2001 자원환경지질 Vol.34 No.1

철-망간 산화광물의 합성과 비소제거 이용 연구

전철민,김재곤,송호철,장세은 한국암석학회 2011 한국암석학회 학술발표회 논문집 Vol.2011 No.5

수중 세슘 제거를 위한 층상 황화 금속 물질 자성화 연구

전철민,박지원,류정호,장정윤,조동완 한국지하수토양환경학회 2023 지하수토양환경 Vol.28 No.4

In the fabrication of magnetic adsorbent by incorporating iron species on base materials with layered structure, there canbe a potential loss of adsorption capacity from the penetration of dissolved iron species into the structure. This work newlysynthesized a magnetic adsorbent by incorporating nano magnetite and glucose into layered metal sulfide via hydrothermaltreatment, and tested the removal efficiencies of cesium ions (Cs+) by the adsorbents fabricated under different conditions(final temperature and glucose mass ratio). As a result, the optimal fabrication condition was found to be mass ratio of 1(layered metal sulfide): 0.1 (nano magnetite) : 0.4 (glucose) and final temperature of 160oC. As-prepared adsorbentpossessed good adsorption ability of Cs+ (54.8 mg/g) without a significant loss of adsorption capacity from attachingglucose and nano magnetite onto the surface.

DBMS를 위한 3차원 지적 모델링 : 구분지상권을 중심으로

전철민,Jun, Chul Min 한국공간정보학회 2013 한국공간정보학회지 Vol.21 No.2

3D cadaster problems are getting attention and studied increasingly. However, correct concepts have not been established for three dimensional land uses and different rights problems around them. This is primarily due to the lack of proper methods for implementation and operation of 3D cadaster. 3D cadaster requiring far more huge data than 2D should be built in DBMS and need appropriate methods and processes for this. This study propose a method to model 3D cadaster using DBMS. First, it analyse and visualize possible problems around divided superficies in 3D spaces. Based on this, it illustrates UML models and shows an O-R mapping process to implement them using a RDBMS. 최근 몇 년 사이 3차원 지적에 대한 관심과 관련 연구가 증가하고 있다. 그러나 아직까지는 입체적인 토지 이용과 이를 둘러싼 다양한 권리문제에 대한 정확한 개념이 정립되지 못하고 있으며, 이는 3차원 지적의 적절한 구현과 운영방안의 부재에서도 그 이유를 찾아볼 수 있다. 2차원 지적보다도 더욱 방대한 데이터가 필요한 3차원 지적은 DBMS에 기반하여 구현되어야 하며 이를 위한 적절한 방법론과 프로세스가 필요하다. 본 연구에서는 DBMS를 위한 3차원 지적의 모델링 방법에 대해 제시한다. 먼저 3차원 공간상에서 존재하는 다양한 형태의 구분지상권에 대해 가시적으로 분석한다. 이를 이용하여 UML에 기반한 모델을 예시한 후 관계형 데이터베이스 시스템(RDBMS)을 이용해서 구현하기 위한 O-R Mapping 과정을 제시한다.

흰민들레의 동맥경화 유발인자인 저밀도 지질단백질 산화에 미치는 영향

전철민,양기숙,Jeon, Cheol-Min,Yang, Ki-Sook 한국생약학회 1996 생약학회지 Vol.27 No.3

The methanol extract of Taraxacum coreanum Nakai (Compositae) was examined on the in vitro oxidation of human low density lipoprotein (LDL). It is well known that LDL oxidation induced artherosclerosis, if we can protect LDL oxidation process, excess plasma lipoprotein accumulation into the arterial lesion prone areas can be blocked. The methanol extract was treated with oxidized LDL which was incubated with $16\;{\mu}M$ $Cu^{2+}$ for metal catalyzed oxidation and TBA value, mobility on agarose gel and formation of conjugated diene and change of vitamin E were determined for the evaluation. The extract showed antioxidative effect at concentration $200\;{\mu}g/ml$ on LDL oxidation.

산도변화와 침지시간이 광중합 복합레진의 잔류단량체 유출에 미치는 영향

전철민,유현미,권혁춘 大韓齒科保存學會 2004 Restorative Dentistry & Endodontics Vol.29 No.3

Objectives : The purpose of this study was to determine whether pH and time has any influence on the degradation behavior of composite restoration by analyzing the leached monomers of dental composites qualitatively and quantitatively after storage in acetate buffer solution as a function of time using high performance liquid chromatography (HPLC) / mass spectrometer. Materials and Methods : Three commercial composite restorative resin materials (Z-250, Heliomolar and Aeliteflo) with different matrix structure and filler composition were studied. Thirty specimens (7 ㎜ diameter × 2 ㎜ thick) of each material were prepared. The cured materials were stored in acetate buffer solution at different pH (4, 7) for 1, 7 and 45days. As a reference, samples of unpolymerized composite materials of each product were treated with methanol (10 mg/ml). Identification of the various compounds was achieved by comparison of their mass spectra with those of reference compound, with literature data, and by their fragmentation patterns. Data were analysed statistically using ANOVA and Duncan's test. Results : 1. Amounts of leached TEGDMA in Aeliteflo were significantly larger than those of UDMA in Z-250 and Heliomolar at experimental conditions of different storage time and pH variation (p<0.001). 2. As to comparison of the amounts of leached monomers per sorage time, amounts of leached TEGDMA in Aeliteflo and UDMA in 2-250 and Heliomolar were increased in the pH 4 solution more significantly than in the pH 7 solution after 1day, 7days and 45days. respectively (p<0.001). 3. In total amounts of all the leached monomers with storage times, the overall amounts of pH 4 extracts were larger than those of pH 7 extracts for all resin groups, but there was no significant difference (p >0.05).

개선된 Floor Field 기반 보행 시뮬레이션 모델

전철민,Jun, Chul-Min 한국공간정보학회 2010 한국공간정보시스템학회 논문지 Vol.12 No.1

실내 공간과 같이 마이크로한 스케일에서의 분석을 위해 다양한 보행시뮬레이션 모델들이 연구 되어 왔으며, 이 중에는 social force 모델과 floor field 모델이 주목을 받는다. 이 중 연산이 복잡한 social force 모델보다는 CA 기반의 floor field 모델이 컴퓨터 시뮬레이션에 더 적합한 모델이라고 할 수 있다. 그러나 Kirchner 등이 제안한 floor field 모델에서는 dynamic field의 연산 시 자신의 dynamic 값에도 영향을 받을 수 밖에 없는 단점을 가지고 있으며, 본 연구에서는 이를 개선한 알고리즘을 제안한다. 본 연구에서는 dynamic field의 데이터 구조를 변경함으로써 자신의 dynamic 값은 배제한 다른 에이젼트의 영향만을 받도록 하였으며, dynamic 값의 초기값을 할당하는 문제도 현실적으로 변경하였다. 본 연구에서 제시된 알고리즘을 테스트하는 데에는 공간 DBMS에 저장된 실제 3차원 건물모델을 사용하여 추후 실내 센서를 이용한 실시간 대피 시스템에 적용할 수 있는 기반이 되도록 하였다. Many pedestrian simulation models for micro-scale spaces as building indoor areas have been proposed for the last decade and two models - social force model and floor field model - are getting attention. Among these, CA-based floor field model is viewed more favourable for computer simulations than computationally complex social force model. However, Kirchner's floor field model has limitations in capturing the differences in dynamic values of different agents and this study proposes an enhanced algorithm. This study improved the floor field model in order for an agent to be able to exclude the influences of its own dynamic values by changing the data structure, and, also modified the initial dynamic value problem in order to fit more realistic environment. In the simulations, real 3D building data stored in a spatial DBMS were used considering future integration with indoor localization sensors and real time applications.