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이태희,김철규,임병문,Lee, Tae-Hee,Kim, Chul-Kyue,Lim, Byung-Moon 한국재무관리학회 2001 財務管理硏究 Vol.18 No.2
자사주 매입에 대한 선행연구는 대부분 그 분석기간이 10일 또는 20일에서 길어도 3개월을 초과하지 않는다. 그러나 투자자들의 공시에 대한 믿음의 수정은 이익발표 등과 같은 추가적인 정보가 나올 때에 이루어질 가능성이 더 크며 이러한 정보들이 자사주매입 공시 후 20여일 후에 나올 가능성은 더 크다고 할 수 있다. 외국의 선행연구에서도 공시후 주가추이분석은 $1{\sim}5$년을 측정기간으로 하고 있으며 동 기간동안에 추가적인 주가상승이 있음을 보고하고 있다. 본 연구에서는 기존의 연구와 달리 표본기간과 표본수를 확대하고 주가반응을 살피는 기간을 연장하여 자사주매입 공시의 정보효과에 대해 검증하였다. 검증 결과 기존의 연구나 실무계에서 주장하는 공시 후 20여일 동안의 주가상승은 자사주매입의 정보신호효과로 인한 것이라는 증거를 찾을 수 없으며, 주가의 상승 자체도 일반적인 현상이 아니라 특정한 연도(주가하락이 극심했던 1997년도)에 국한된 현상임을 확인하였다. 그러나 특정연도에 추가적인 주가상승이 발생한 이유에 대해서는 명확한 결론을 내 릴 수 없었다. 또한 자사주매입으로 인한 주가의 추가 상승은 단기적인 현상이 아니라 매우 장기적인 현상일 것이라는 점에 착안하여 분석기간을 공시 후 80여일로 늘려서 분석을 실시한 결과 정보신호효과와 관련된 변수가 유의적인 값을 가지기 시작하였다.
염수분무 환경에서 알루미늄-크롬 용융도금강판의 부식생성물이 내식성에 미치는 영향
임병문,홍승현,정재인,최장현,정원섭 대한금속재료학회 2003 대한금속·재료학회지 Vol.41 No.10
The effect of corrosion products of hot-dip Al-Cr steel sheet on the corrosion resistance were investigated. The results of XRD and XPS measurements showed that there was not found a hydroxide type corrosion product on the surface of aluminized steel after salt spray test(SST) but there was found some cracks in the surface layer which accelerates corrosion during SST. In Al-Cr coated steel case, the main phase of the corrosion products after salt spray test was found to be Al(OH)₃. The polalization curves of aluminized steel after SST shows that there was no passivation layer. For the Al coated layer, a porosity in the Al-oxide film on the surface layer leads to preferential corrosion. After the Al coated layer was completely removed, the Al_(5)Fe₂layer was selectively corroded and then, the steel substrate was exposed to the electrolyte. However, the polalization curves of Al-Cr coated steel after SST shows that the passivation layer was formed, which could increase the corrosion resistance of Al-Cr coated steel. In case of the Al-Cr coated layer, the densely covered hydroxide layer of Al(OH)₃and the intermetallic compound layer of Al_(13)Cr₂became a barrier against further corrosion after the Al layer was removed. In this case, corrosion was not proceeded even through the same current density. The densely covered hydroxide of Al(OH)₃and the intermetallic compound layer of Al_(13)Cr₂were considered to be one of the reasons of high corrosion resistance for Al-Cr coating.
임병문,홍승현,정재인,최장현,정원섭 대한금속재료학회 2003 대한금속·재료학회지 Vol.41 No.8
The microstructure and the corrosion behavior of aluminized steel sheet and hot-dipped Al-Cr wteel sheet were investigated. The EPMA, GDLS and XRD measurements of the Al-Cr coated layer showed that the coating layer was characterized by three phases. The surface layer was Al, the middle layer was Al_(13)Cr_(2), and the interfacial layer between the Fe substrate and the coated layer was composed of Al_(13)Fe_(4) and Al_(5)Fe_(2). The polalization curve indicates that the corrosion behavior of Al-Cr coated layer was different from that of Al coated layer. For the Al coated layer, porosities in the Al-oxide film on the surface layer lead to preferential corrosion. After the Al coated layer was completely removed, the Al_(5)Fe_(2) layer was selectively corroded and then, the steel substrate was exposed to the corrosion medium. In case of the Al-Cr coated layer, the Al_(13)Cr_(2) layer became a barrier against further corrosion after the Al layer was removed. In this case, corrosion was not proceeded even through the same current density. The high corrosion resistance was due to the existence of the Al_(13)Cr_(2) layer.
알루미늄-크롬 용융도금강판의 미세조직과 집합조직에 미치는 크롬의 영향
임병문,홍승현,정재인,최장현,정원섭 대한금속재료학회 2003 대한금속·재료학회지 Vol.41 No.10
Microstructure and texture changes of aluminized coatings on steel sheets having Cr ranging from 0.0% to 1.0% in the coated layer were investigated. The surface morphology of the Al-Cr coated steel is not influenced by the increase of Cr contents in the coated layer. While the coated layer of aluminized steel consisted of two phases of Al and Al_(5)Fe₂, the aluminized coating layer containing Cr was composed of three phases of Al, Al_(13)Cr₂, and Al_(13)Fe₄+Al_(5)Fe₂. The surface layer was Al, the middle layer was Al_(13)Cr₂, and the interfacial layer between the coating and the steel substrate was Al_(13)Fe₄and Al_(5)Fe₂. The texture of the aluminized coating without Cr was characterized as a {001} fiber texture which major orientation was {001}<110>. As the Cr content in the aluminized layer was increased to 1.0%, the texture of the aluminized coating was not changed but the intensity of the {001} fiber texture was increased. The major orientation in the {001} fiber texture was changed from the rotated cube orientation of the aluminized coating with 0.1%Cr to the cube orientation of the aluminized coating with 1.0%Cr.