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유기물의 혐기성 분해시 황화물 및 황산염이 혐기성균에 미치는 영향
신항식,오세은 ( Hang Sik Shin,Sae Eun Oh ) 한국물환경학회 1996 한국물환경학회지 Vol.12 No.2
Batch test was performed to evaluate the activity of methane producing bacteria (MPB) and acetate producing bacteria(APB) according to change of sulfate and sulfide concentrations. MPB activity in the 100 and 150㎎S/ℓ was inhibited by 15 and 50%, respectively, while it was stopped at over 200㎎/ℓ. This indicated that the inhibition of sulfide concentration on methane producing bacteria increased as sulfide concentration increase. Different species of anaerobic microorganisms degrading organics showed different characteristics of acclimation and inhibition depending on the sulfide concentration. APB and MPB were much affected at the sulfide concentration over 100㎎/ℓ, resulting in accumulation of acetate in the reactor. This clearly showed that APB were more persistent than MPB to sulfide toxicity. Sulfate concentration less than 2000㎎/ℓ showed no inhibition to MPB in the anaerobic treatment of organics. Moreover, higher methane production was observed with sulfate concentration of 100㎎/ℓ in the batch than in the control, suggesting that small amount of sulfate was necessary for MPB.
음식쓰레기의 실험실 규모 퇴비화에서 셀룰로스 분해에 대한 퇴비 식종효과
신항식,정연구,황응주,Shin, Hang-Sik,Jeong, Yeon-Koo,Hwang, Eung-Ju 유기성자원학회 1998 유기물자원화 Vol.6 No.1
음식 쓰레기와 종이류의 혼합퇴비화에서 퇴비 식종 효과는 온도 변화, pH, 이산화탄소 발생량, 암모니아 발생 속도 등으로 판단하여 볼 때 유기성 질소를 비롯한 유기물의 분해를 퇴비화초기 단계에서는 촉진하는 것으로 나타났다. 하지만 이러한 퇴비식종이 최종적으로 유기물 분해율이나 질소 손실량에는 영향을 주지 않았다. 또한 퇴비를 식종함으로써 초기 고온 단계의 셀룰로스 분해가 촉진되었으며 건조 중량으로 25% 식종은 초기에 충분한 양의 셀룰로스 분해 미생물을 공급하는 것으로 나타났다. 아울러 퇴비 식종량이 증가함에 따라 초기 단계의 셀룰로스 분해 효소 활성도가 높았으며, 단시간에 최대값으로 증가하는 경향을 보였다. 그러나 최대 셀룰로스 분해효소의 활성도 유지기간이나 최대값은 대체로 비슷하였다. 또한 최종적인 셀룰로스 분해율도 비슷하여 퇴비 식종효과는 셀룰로스의 빠른 분해에 제한되며, 셀룰로스의 전반적인 분해도 향상에는 기여하지 못하는 것으로 판단된다. The effects of compost inoculation on the degradation of cellulosic fraction in composting of food waste and paper mixture were investigated by bench-scale composting. With the increase of seed inoculation, the time to reach the peaks of temperature, $CO_2$ evolution rate, and ammonia evolution rate was reduced, indicating that seed compost had beneficial effects on the enhanced degradation of organic materials at the early stage of composting. However, the final conversion of organic matters and the loss of ammonia were not affected by the amount of seed compost inoculated. The increasing of seed inoculum also resulted in the higher level of cellulase activity at initial stages and rapid rise to the maximums, suggesting that initial supply of sufficient cellulolytic microorganisms might facilitate the evolution of cellulase activity. The cellulose was degraded substantially during the increasing phase of cellulase activity, while they showed similar values at the end of 20 days composting. As a result, the seed inoculation seemed to be effective to the enhanced evolution of cellulase activity and cellulose degradation at initial stage of composting. But it did not contribute to increase the final degradation of cellulose after the entire composting reaction of 20 days.
신항식,배병욱,백병천,Shin, Hang Sik,Bae, Byung Uk,Paik, Byung Cheon 대한토목학회 1990 대한토목학회논문집 Vol.10 No.4
본 연구에서는 주정폐액의 고율처리를 위하여 이상 UASB 공정을 시험하였다. 상분리는 반응조의 pH를 조절하므로써 가능하였다. 유입폐수의 SS 농도가 4.1g/l일 때 산형성조는 유기부하 16.5kg $COD/m^3.day$까지 운전이 가능하였고, 이때 산생성율은 3.9g HAc/l.day를 나타내었다. 메탄형성조는 유기부하 44kg $COD/m^3.day$까지 운전이 가능하였으며, 이때 COD 제거율은 80%이었고 비가스 생성율은 16.51/l.day이었다. 두 반응조에서 입상슬러지가 형성된 이후에는 알칼리도의 주입없이 메탄조유출수의 재순환으로 산형성조의 pH를 적절하게 유지할 수 있었다. A two-phase UASB system was operated for high-rate treatment of concentrated distillery wastewater. The phase separation was obtained by adjusting pH in each reactor. When influent SS concentration was 4.1/g/l, the first phase UASB reactor was effectively operated up to the loading rate of 16.5kg $COD/m^3.day$, producing 3.9g HAc/l.day. In the methanogenic UASB reactor, loading rate up to 44kg $COD/m^3.day$ could be applied while removing 80% of influent COD with a specific gas production of 16.5 l/l. day. After the formation granular sludge in both reactors, it was possible to maintain the appropriate pH in the first phase only by recirculating the effluent from methanogenic phase without the addition of alkaline chemicals.
신항식,임경호,이의신,최계운 ( Hang Sik Shin,Kyeong Ho Lim,Eui Sin Lee,Gye Woon Choi ) 한국물환경학회 1995 한국물환경학회지 Vol.11 No.4
Biofilm system is suitable for the pretreatment of water because biofilm can act as niches where slow-growing degraders can survive at low organic concentrations. In order to cope with stringent environmental standards, it became essential to improve the understanding of the phenomena governing biological degradation of organics. In this study, effects of hydraulic retention time (HRT) and temperature on the efficiency of submerged biofilm reactors were investigated. Removal efficiency total organic carbon (TOC), turbidity, and algae increased with the HRT. It is considered that over 1 hr HRT is needed to ensure the removal of higher than 30% TOC. In comparison to honey comb type media, fibrous media were more favorable to the attachment and growth of active microorganisms. The close relationship with chlorophyll-a concentration and particulate organic carbon (POC) concentration make POC a surrogate parameter for estimating the removal efficiency of algae.
신항식,임경호 ( Hang Sik Shin,Kyeong Ho Lim ) 한국물환경학회 1995 한국물환경학회지 Vol.11 No.2
In this study, organic stabilization and nitrogen removal were investigated using a household-type hollow fiber membrane separation bioreactor of 1.9L volume. The process employed direct solid-liquid separation by the hollow fiber membrane module and an aeration tank. There was a distinct effect of solid content on the membrane flux. The steady water flux decreased as MLSS concentration increased from 3,500 to 13,300㎎/ℓ. The reduction of influent COD aver 95% was obtained in the system without sludge wastage. However, by-products of cell degradation could accumulate and have adverse effect in the biological reactor if sludge was not wasted. SS was completely removed from the effluent so that clean effluent could be obtained by the membrane bioreactor. Enteric bacteric such as E. coli was not detected in the effluent. By the ultrafiltration membrane bioreactor, TKN was removed up to 90% or more by simultaneous nitrification and aerobic denitrification. Endogenous denitrification rate of 0.0139g NO₃-N/g VSS.day was observed.
Solidification of Hazardous Wastes from Electroplating Industry
신항식,허남룡,구자공,Shin, Hang Sik,Her, Nam Ryoung,Koo, Ja Kong Korean Society of Civil Engeneers 1988 대한토목학회논문집 Vol.8 No.2
본 연구는 도금공장에서 생산된 슬러지를 시멘트 고형화방법을 이용하여 처리할 때 고형화에 영향을 미치는 인자들 중에 모래/시멘트 비, 물시멘트 비, 젖은 슬러지의 양, 그리고 중금속 용출방지제를 네가지의 인자로 하여 압축강도와 용출량의 변화를 살펴 보았다. 모래/시멘트 비는 Cr(VI) 용출에 가장 큰 영향을 미치는 인자이며, 물/시멘트 비는 Zn와 압축강도에 가장 큰 영향을 미치는 인자였다. Cr(VI)는 Zn보다 시멘트 고형화에서 leachability가 더 적었다. 현장에서의 Cr(VI)과 Zn 그리고 압축강도를 예측하기 위한 모델을 계발하였으며, 고체화의 3급 Brick으로의 이용을 위해 혼합조건을 제시하였다. 그리고 30g의 건조슬러지를 고형화할 때 최적조건은 모래/시멘트 비, 물/시멘트 비, 그리고 중금속 용출방지제의 양은 각각 1, 1.5, 1.075g이었다. This research evaluated factors on cement-based solidification process designed for hazardous sludge produced from electroplating industry. Four factors of sand/cement ratio, water/cement ratio, amount of wet sludge and amount of a precipitator, were investigated in terms of leachability and compressive strength of the solidified materials. Results of triplicate tests and statistical analysis indicated that sand/cement ratio(S/C) had the greatest effect on leaching of Cr(VI) from the solidified materials while water/cement ratio(W/C) on Zn and compressive strength. Cr(VI) was fixed better than Zn by portland cement. An experimental modeing was developed to estimate leached metal concentration and compressive strength at a given condition. Proper mixing criteria were also suggested for the use of the solidified mixture as construction materials. In solidification of 30g dry sludge, optimal condition was studied for S/C ratio, W/C ratio and the weight of precipitator which were 1, 1.5 and 1.075g respectively.