에너지 절감을 위한 External & Internal Blind -한국산업기술진흥원장상 수상작-

이창래,문석현 한국공학교육학회 2015 Ingenium(人材니움) Vol.22 No.2

새만금 해역에서 방조제 건설에 따른 동물플랑크톤 군집의 변화

이창래,강형구,노재훈 한국해양과학기술원 2009 Ocean and Polar Research Vol.31 No.4

Zooplankton community structure was investigated in the Saemangeum region in March, May, July and October of 2007 and 2008 in order to understand the potential effect of post construction of Saemangeum dyke on their temporal and spatial distribution. Mean abundance of zooplankton in the inner and outer area of the dyke, except for dinoflagellate Noctiluca scintillans, ranged from 173 to 15,830 ind.m−3, showing higher variability in the inner area compared to the outer area. Zooplankton abundance was higher in the outer area than the inner area in 2007, and vice versa in 2008. In the inner area of the dyke, zooplankton abundance was the highest in May 2007 and March 2008. In the outer area of the dyke, abundance was the highest in October 2007 and July 2008. Brackish species such as Tortanus derjugini and Pseudodiaptomus inopinus were dominant prior to construction of the dyke, and appeared less frequently in the inner area. Marine zooplankton taxa such as juvenile hydromedusa, and calanoid copepods Acartiahongi and Paracalanus parvus s.l. dominated both areas of the dyke. In CCA analysis, zooplankton community structure in the inner and outer area was similar in March and May, but different in July and October. Temperature, salinity and COD were important environmental factors affecting zooplankton community structure. These results suggest that zooplankton community structure in the inner and outer area of Saemangeum dyke are significantly affected by whether the sluice gates are closed or open.

MDCT의 관전압, 관전류, 슬라이스 두께 변화에 따른 팬텀의 선량 분포 측정

이창래,전성수,남소라,조효민,정지영,김희중,Lee, Chang-Lae,Jeon, Seong-Su,Nam, So-Ra,Cho, Hyo-Min,Jung, Ji-Young,Kim, Hee-Joung 한국의학물리학회 2007 의학물리 Vol.18 No.3

본 연구는 MDCT (multi-detector computed tomography) 파라미터 변화에 따른 환자선량을 측정하고 평가 하고자 하였다. MDCT 파라미터의 다양한 변화에 의한 환자선량은 MDCT (GE light speed plus 4 slice, USA)와 model 2026C electrometer (RADICAL 2026C, USA), 그리고 head와 body의 CT선량 표준팬텀(standard polymethylmethacrylate)을 사용하여 측정 하였다. 그 결과 환자선량 $CTDI_w$ 값은 관전압과 관전류가 증가할수록 선형적으로 증가하였고 beam collimation이 증가 할수록 감소하였다. 따라서 관전압, 관전류는 환자의 피폭선량에 직접적인 영향을 주고 슬라이스 두께는 영향이 적은 것을 알 수 있었다. 임상의 전형적인 MDCT 복부 scan에서 120 kVp, 180 mAs, 20 mm collimation과 0.75 pitch의 조건하에 $CTDI_w$와 $CTDI_{vol}$의 측정값은 각각 20.2 mGy, 26.9 mGy이었고 스캔 길이가 271.3 mm인 환자의 DLP와 유효선량은 각각 $729.1\;mGy{\cdot}cm$, 10.9 mSv였다.

$CaNi_{5}$ 및 MG-$CaNi_{5}$ 전극의 퇴화거동에 미치는 불화처리의 영향

이창래,오세진,강성군,Lee, C.R.,Oh, S.J.,Kang, S.G. 한국재료학회 1999 한국재료학회지 Vol.9 No.6

Effects of the fluorination in the $K_2$TiF\ulcorner solution and in-situ KF+ KOH electrolyte on the electrochemical charge-discharge properties of CaNi\ulcorner and the Mg-CaNi\ulcorner electrodes were investigated. In-situ fluorination in the KF+ KOH electrolyte compared with pre-fluorination in the$ K_2$TiF\ulcorner solution could improve the electrochemical cycling durability of CaNi\ulcorner and MG-CaN\ulcorner electrodes. The fluorinated layer on the alloy surface by pre-fluorination to improve the activity and anti-corrosion of the electrodes was dissolved in the pure KOH electrolyte during the cycling. The fluorinated layer was formed continuously on the surface of the electrode by thee2N KF addition in the 6N KOH electrolyte. The excess F\ulcorner ion addition in KOH electrolyte could improve the electrochemical cycling durability of CaNi\ulcorner and Mg-CaNi\ulcorner electrode. But, in case of MG-CaNi\ulcorner electrode, the discharge capacity of the electrode was reduced and the poor cycling property was shown with increasing of the MG process times.

기계.화학적 방법으로 제조된 고활성 나노-니켈 촉매의 특성 I. MA된 Ni-50wt% Al 합금의 미세구조 및 나노 촉매 제조

이창래,최재웅,강성군,Lee, Chang-Rae,Choe, Jae-Ung,Gang, Seong-Gun 한국재료학회 1999 한국재료학회지 Vol.9 No.6

The new process in order to fabricate of Ni catalyst with high activity by the mechanochemical(MC) method which was combined the mechanical alloying(MA) and the chemical treatment process. The microstructure and characterization of mechanically alloyed Ni-5-wt% Al powder and Ni catalyst gained by alkali leaching were investigated byt he various analysis such as XRD, SEM-EDS, HRTEM and laser particle analyzer. The steady state powder with 1~2$\mu\textrm{m}$ mean particle size was obtained after 30hr milling with the PCA of 2 wt% stearic acid under the condition of grinding stainless steel ball to powder ratio of 60:1 and rotating speed fo 300rpm. According to result of HRTEM diffraction pattern, MA powder of the steady state was nanocrystalline $Al_3$$Ni_2$ intermetallic compound. Ni catalyst was obtained after KOH leaching of the steady state powder was about 20nm nanocrystalline which contained about 8 wt % Al.

알칼리형 연료전지의 수소극용 Co-Mo 및 Ni-Mo 금속간화합물 전극의 전기화학적 안정성

이창래,강성군,Lee C. R.,Kang S. G. 한국전기화학회 1999 한국전기화학회지 Vol.2 No.3

The Electrochemical stabilities of the Brewer-Engel type intermetallic compounds of Co-Mo $(35 wt\%)$ and Ni-Mo$(35 wt\%)$ manufactured by the arc-melting method for the hydrogen electrode of $H_2-O_2$ alkaline fuel cell were investigated. Effects of temperature and concentration on the electrochemical behavior of the electrodes in the $80^{\circ}C$ 6 N KOH solution deaerated with $N_2$ gas were studied by electrochemical methods. The effect of overpotential on the electrochemical stabilities of Co-Mo and Ni-Mo intermetallic compounds was also discussed under the normal operation condition of AFC. It was shown that Co-Mo electrode had lower electrochemical stability as compared to Ni-Mo. In the case of Co-Mo electrode, a simultaneous dissolution of cobalt and molybdenum has occurred at low anodic overpotential form equilibrium hydrogen electrode potential, but the dissolution of cobalt was serious, and Co(OH)l layer on the electrode surface formed at the high anodic overpotential. In contrast the Ni-Mo electrode had high electrochemical stability because formation of the dense and thin protective $Ni(OH)_2$ layer prevented the dissolution of molybdenum.

$CaNi_5$ 수소저장합금의 전기화학 특성에 미치는 MG 처리 효과

이창래,강성균,Lee C. R.,Kang S. G. 한국전기화학회 1999 한국전기화학회지 Vol.2 No.2

The effect of the MG on the electrochemical charge-discharge properties of $CaNi_5$ hydrogen storage alloys was investigated under Ar and $H_2$ atmosphere. $CaNi_5$ alloy was partially decomposed to CaO and Ni phase during the MG process. The decomposition of $CaNi_5$ alloy was enhanced by the MG process which leads to crash and reformation of oxide layer on the alloy surface. As the MG process time increased, initial discharge capacity of the electrode was reduced, but the decay rate of the capacity compared to $CaNi_5$ alloys was slower. It may be described that the degradation of $MG-CaNi_5$ electrode was caused by the reduction of the reversible hydrogen reaction sites and increasing polarization resistance of hydrogen adsorption resulted from phase decomposition and disorder during the MG process, and/or by hydroxide formation during the electrochemical charge-discharge cycles.

다도해해상국립공원 칠발도 및 여서도 해역의 해황과 동물플랑크톤 군집 특성

이창래,김성용,이병관,노형수,정주학,송성준,김태균 국립공원연구원 2012 국립공원연구지 Vol.3 No.3

아산만 해역 중형동물플랑크톤의 시공간적 변동

이창래,박철,양성렬,신용식,LEE C. R.,PARK C.,YANG S. R.,SIN Y. S. 한국해양학회 2006 바다 Vol.11 No.1

서해 중부 연안에 위치한 아산만의 과거 동물플랑크톤 연구는 주로 3개월 간격의 계절별 자료에 근거하고 있다. 본 연구에서는 상대적으로 짧은 주기의 월별 채집을 바탕으로 동물플랑크톤의 월 변동을 파악하고, 수온과 염분, 식물플랑크톤의 출현량을 환경 요인으로 취급하여 이들의 변화 특성 및 이와 동물플랑크톤 분포와의 관계를 파악하였다. 수온은 시간적으로 전형적인 온대수역의 변화양상을 보여주며, 공간적으로는 만의 안쪽에서 연간 변화의 폭이 다소 크게 나타났다. 염분의 계절변화는 장마에 의한 계절변화가 크며 이 시기 인공담수호의 간헐적인 담수유출이 플랑크톤 생태계에 적지 않은 영향을 미칠 것으로 판단되었다. 식물플랑크톤의 클로로필 양은 과거에 비해 상당한 증가를 보였는데 만의 안과 밖에서 봄철 대증식의 시작과 기간에서 차이가 있었다. 만 안쪽에서 바깥쪽으로 가면서 춘계 대증식이 2월에서 4월로 늦춰졌고, 만 안쪽과 중앙에서는 대증식 기간이 3개월 정도 유지된 반면, 만 바깥쪽에서는 약 1개월 정도로 그 기간이 짧아졌다. 식물플랑크톤의 클로로필 양과 동물플랑크톤의 양, 특히 최 우점종 Acartia hongi의 양 간에는 약하지만 의미있는 양의 상관관계를 보였다(p<0.05).과거 계절별 자료에 근거한 시간변동과 비교하여 월별 채집의 필요성이 확인되었다. Previous studies on zooplankton in Asan Bay were mostly based on samples collected seasonally with three months intervals. Present study was aimed to know the temporal variation of meso-zooplankton distribution using the data collected monthly. Relationships between zooplankton abundances and environmental factors such as seawater temperatures, salinities and chlorophyll-a contents were also studied. Seawater temperature showed typical pattern of seasonal variation found in temperate waters. The fluctuations of environmental factors ranged relatively wider In the inner part of the bay than those in outer part of the bay. Salinity was very low right after the summer rainy period due to the sporadic outflow of freshwater from the adjacent artificial lakes. Sudden changes in salinity seemed to have significant impact on zooplankton assemblages. Chlorophyll-a contents were increased in general when compared with previous reports probably due to the recent human exploitations in the coastal zone, which might enhance the nutrients level . The timing and duration of spring bloom showed geographical differences. In the inner part of the bay it began earlier (February) and last longer (three months) while in the outer part of the bay it began late (April) and last just one month. Zooplankton abundance, especially most abundant taxon Acartia hongi, showed weak but significant positive correlation with chlorophyll-a contents. The difference in temporal variation found with two different sampling intervals indicated the necessity of shorter time interval samplings.

수소연료전지용 분리판 소재 및 제조공정기술

이창래,양철남,Lee, Chang-Rae,Yang, Cheol-Nam 재료연구소 2009 機械와 材料 Vol.21 No.2

분리판은 수소연료전지 스택을 구성하는 부품 중에서 가장 많은 수량이 사용되는 부품의 하나로서 연료전지의 출력밀도(powder density, W/L), 비출력(specific power, W/kg) 및 가격($/kWe) 관점에서 가능한 저가의 소재 및 제조공정으로 경량/박형화가 이루어져야 하는 핵심부품이다. 이러한 저가의 경량/박형화 분리판 개발의 전제 조건은 연료전지 스택에서 요구하는 다양한 물성, 장기 수명 및 신뢰성을 나타내는 내구성을 만족해야 하는 것이다. 본고에서는 지금까지의 수소연료전지, 특히 고분자전해질 연료전지를 중심으로 분리판에서 사용되는 소재 및 제조공정기술의 현황, 분리판 개발에서 요구되는 다양한 기술적인 요소 및 그 문제점을 중심으로 살펴봄으로써 고성능, 고내구성 분리판 소재 및 제조공정 개발의 발전방향에 대하여 고찰하였다.