경복궁 출토 기와의 자연과학적 조사 연구 - 소주방지, 흥복전지, 함화당지, 집경당지 출토 -

홍종욱,박지희,이한형,Hong, Jong-Ouk,Park, Ji-Jee,Lee, Han-Hyeong 국립문화재연구소 2008 保存科學硏究 Vol.29 No.-

Roofing tiles are very important archaeological artifacts which show science, architecture of that time, as well as information about the culture. It has been studied by many researchers steadily, but only focusing on archaeological, art historical and architectural study, so it is very difficult to find natural science research. Gyeongbokgung's roofing tiles were excavated from the ruins of same site, however glaze, body colour and shape of tiles are very diverse with the naked eye. Through natural science research which analyze the chemical composition and physical characteristics of roofing tiles's body and glaze examine the physical and chemical characteristics of each roofing tiles. the result of analazed roofing tiles is following. when roofing tiles were classified by 전암대자율 and chromaticity, each group has part of some matches. When you compare with green gazed traditional brick's glaze of Silla period, Gyeongbokgung roofing tiles have more $Al_2O_3$ and less PbO than Silla period's. We can see the technology of increasing firing temperature is better. and glaze colour depends on content of $Fe_2O_3$ and CuO. A lot of CuO tend to be more blue.

고대기와의 자연과학적 분석 연구 경기도 하남시 천왕사지출토기와를 중심으로

홍종욱,Hong, Jong-Ouk 국립문화재연구원 2004 헤리티지:역사와 과학 Vol.37 No.-

20세기에 들어와 컴퓨터의 발달로 문화재를 복원하는데 있어 다양한 자연과학적 방법이 시도되고 있다. 문화재에 적용되는 통계학을 비롯한 자연과학적인 방법을 통해 문화재의 재질에 대한 주성분 및 미량성분을 분석하여 산지추정을 할 수 있고, 더 나아가 고대의 교역 및 교류관계를 규명하고, 생산지와 소비지 사이의 정치 경제 문화관계 등 다양한 정보를 밝혀내고 있어 그 필요성이 더욱 요구되고 있다. 본 연구는 흡수율 및 광물결정분석, 편광현미경분석, 통계분석 등의 자연과학적인 방법을 이용하여 경기도 하남시 천왕사지 유적내 기와 가마로 추정되는 소성유구의 성격과 유구 및 주변 건물지에서 출토된 기와들에 대해 상호관계를 밝히고자 시도되었으며, 연구결과 다음과 같은 결론을 얻었다. 경질 기와 편들을 제외한 연질 기와 편들은 다른 기와에서 볼 수 있는 흡수율(10%이상)과 비슷한 수치를 보였으며, 흡수율이 낮은 일부시료에서는 Mullite, Tridymite, Cristobalite와 같은 고온 결정상 등이 존재하는 것으로 보아 다른 기와편에 비해 소성온도가 높았음을 알 수 있었다. 또한 미량성분을 통한 통계분석결과 소성유구와 천왕사지 내에서 출토된 기와는 한 군으로 분류된 것으로 보아, 밀접한 관련성을 가지고 있음을 알 수 있었고, 천왕사 축조시 원거리에서 기와를 공급받은 것이 아닌 사지 내에 가마를 설치한 후 공급하였음을 알 수 있었다. Today, in the cultural properties research, there are several methods for knowing the culture of the past through a lot of information that remains and relics contain. Especially, statistical method like presumption of producing center were introduced from computer development at the early 20th century. This study showed the characteristic about firing historic sites presumed as a tile-kiln in the remains of Cheonwang temple sites, Hanam, Gyeonggi province. Also, I used nature scientific methods for correlation between tiles excavated at historic sites and circumference building and obtained there results as follows. First, soft tile parts showed similar water suction ratio(over 10%) like another tiles, except hard tile parts. Second, identification about mineral crystallization in a sample showing low water suction ratio confirmed a result that Mullite, Tridymite, Cristobalite as high temperature crystal form were presented. I know that firing temperature was higher than the other tile parts from this result. Third, statistical analysis from micro-component resulted that tiles excavated at firing historic sites and Cheonwang temple sites were closely connected. As the results, I knew that the tiles got a supply after the establishment of tile-kiln, not at a long distance at the period of Cheonwang temple construction.

기장군출토 도자기의 미세구조 및 특성에 관한 연구

홍종욱,한민수,Hong, Jong Ouk,Han, Min Su 국립문화재연구소 2012 保存科學硏究 Vol.33 No.-

Jangan-eup, located in Busan, South Korea,is a famous pottery-producing area in the Joseon Dynasty period. The aim of this paper was to determine the correlation of the pottery from each kiln site of Jangan-eup by analyzing the ingredients of clay as well as its production technique and firing condition. The materials that were used for the study were fragments of inlaid celadon, white porcelain, and white porcelain painted with underglazed iron excavated from six kiln sites of Jangan-eup:Sil-li, Daeryong-li, Hajangan-li, Sangjangan-li, Yongso-li, and Dumyeong-li. In each of the samples from the six kilns, cristobalite, mullite, and quats were found. The firing temperature distinguished from the crystal structure was higher in the following order: Dumyeongli>Sangjangan-li>Daeryong-li>Hajangan-li>Yongso-li>Sil-li. The samples were divided into four groups based on the ingredients of the clayfound therein: the Sil-li andDaeryong-li group, the Hajangan-li and Sangjangan-li group, the Yongso-li group, and the Dumyeong-li group. It was also found that the sample of Dumyeong-li was made using the most homogeneous clay compared with the other samples. The pottery of Jangan-eup had $40-400{\mu}m$ glaze, had bubbles in their bodies, and had $10-150{\mu}m$ sizes. 조선초기에서 후기에 이르는 자기 생산지로 유명한 부산 기장군 장안읍 일대에 산재한 도요지 중 신리, 대룡, 하장안, 상장안, 용소, 두명리에서 출토된 상감청자, 백자 및 철화백자 편 등을 대상으로 성분과 미세구조를 분석하였고, 이러한 과학기술적 고찰을 통해 6개 도요지에서 출토된 자기의 태토원료, 제작기법, 번조상황 및 도요지간 상관관계 등을 규명하고자 하였다. 6개 사이트에서 출토된 자기에서 Cristobalite, Mullite, Quarts 등이 검출되었고, 결정구조에 따른 소성 온도는 두명리>상장안>대룡리>하장안>용소리>신리> 순으로 높았음이 확인되었다. 판별분석 결과 신리와 대룡리, 상장안리와 하장안리, 용소리, 두명리로 4개 그룹으로 분류되었다. 시편에 제작에 사용된 태토원료는 4개의 유사한 특성 분포를 가지고 있다. 기장군 도자기의 유약 두께는 $40{\sim}400{\mu}m$로 시유되었고, 기포는 $10{\sim}150{\mu}m$형성된 특징을 나타내고 있다. 태토의 균질성 측면에서도 두명리 출토 시편이 가장 우수한 특성을 나타내고 있는 것으로 밝혀졌다.

현지르뽀-기술지원으로 부락숙운이뤄

홍종욱,Hong, Jong-Uk 한국과학기술단체총연합회 1975 과학과 기술 Vol.8 No.7

익산 입점리 출토유물 보존처리

홍종욱,임선기,차재선,문상훈,Hong, Jong-Uk,Im, Seon-Gi,Cha, Jae-Seon,Mun, Sang-Hun 국립문화재연구소 1987 保存科學硏究 Vol.8 No.-

도.토기의 과학적 분석 및 분류-전남 완도군 장도 청해진 유적을 중심으로

홍종욱,조남철,강대일,이명희,Hong, Jong-Ouk,Cho, Nam-Chu,Kang, Dai-Il,Lee, Myong-Hee 국립문화재연구소 2000 保存科學硏究 Vol.21 No.-

This study has proved if there are homogeneities in crystal structures, firing temperaures and element compositions of 69 specimens for potteries and soils from Changdo, Kangjin-gun, Jinjuk-Ri in Korea and Yaezhou inChina and obtained the following results.1. XRD analyses showed that soft potteries seemed to contain ($\alpha$)quartz, feldspar, while hard potteries seemed to contain ($\alpha$-)quartz, mullite, tridymite, feldspar. Jinjuk-Ri soils consisted of clays such as Kiolinite, Montmorillonite, Muscovite, Illite and, mica and feldspar etc.2. It was estimated that the firing temperatures which are determined by crystals using XRD, ranged from $550^{\circ}C$ to $870^{\circ}C$ for soft potteries and $870^{\circ}C$ to $975^{\circ}C$ for hard potteries.3. The firing temperatures for 4-pieces of Changdo pottery were measured by using TG-DTA, and it was found that specimen No. 10 was fired at temperatures below $600^{\circ}C$, while specimens No. 14, No. 23 and No. 29 were fired at temperatures above $1000^{\circ}C$.4. It was found that the specimems for potteries and porcelains from Changdo, Kangjin-gun, Jinjuk-Ri in Korea and Yaezhou in China were apparently classified into 4 clusters. This suggests that there are no correlations between the raw materials used in each 4 regions. Among the porcelains from Changdo, there were many typologically similar ones to those from Yaezhou in China in the 9th centry, but the analyses of porcelains only from Changdo, Kangjin in Korea and Yaezhouin China showed that they were classified into 3 clusters. This suggest that there are no correlations between the raw materials used for making porcelains in Changdo, Kangjin-gun, Jinjuk-Ri in Korea and Yaezhou in China.

완주 송광사 나한전 단청안료 분석

홍종욱,이장존,Hong, Jong-Ouk,Lee, Jang-jon 국립문화재연구소 2013 保存科學硏究 Vol.34 No.-

전라북도에 소재한 유형목조문화재의 단청기록화 사업의 일환으로 송광사 나한전(전라북도 유형문화재 제172호)에 채색된 안료에 대한 X-선형광분석을 실시하였으며, 이들에 대한 색상별 안료의 성분과 보수시기의 동일성을 비교하였다. 분석결과 주성분 및 미량성분을 검토한 결과 나한전에 사용된 안료는 청색은 군청(($3NaAl{\cdot}SiO_4{\cdot}Na_2S_2$), 녹색은 양록($Cu(C_2H_3O_2)_2{\cdot}3Cu(AsO_2)_3$, 주황은 장단($Pb_3O_4$), 황색은 크롬옐로($PbCrO_4$)로 분류되었다. 나한전 외부, 내부의 안료 성분분석으로는 채색 시기를 구별하긴 어려웠다. The purpose of this investigation is to Dancheong documentary project of Tangible cultural in Jeollabukdo. The colored pigments of Nahanjeon Hall in Songkwangsa Temple analyzed and composition and repair period for each pigments were compared. The result are that blue color is Ultramarine blue($Na_6Al_6Si_6O_{24}S_4$), green color is Yangrok($Cu(C_2H_3O_2)_2{\cdot}3Cu(AsO_2)_3$), orange color is Jangdan($Pb_3O_4$), yellow color is Chrome yellow($PbCrO_4$). It is difficult to distinguishable from coloring period by analysis of pigments of Nahanjeon Hall.

토기의 소성온도에 따른 미세조직 비교연구

홍종욱,정광룡,Hong, Jong-Ouk,Jung, Kwang-Yong 국립문화재연구소 1994 保存科學硏究 Vol.15 No.-

A typology was established for 15 pottery artefacts at Chejuisland. Conjectured methods of manufacture were confirmed by radiography X-ray diffraction. Scanning electron microscopy etc. The compositions and mineralogy of $500^{\circ}C$ to $1200^{\circ}C$ was measured and compared with those of microstructure. The mechanism of sintering was impurity-initiated, liquid-phase sintering. The making, firing, and sometimes exploding of the figurines may have been the prime function of the pottery at this site rather than being manufactured as permanent, portable object.

철기류의 부식도 비교시험

홍종욱,임선기,Hong, Jong-Uk,Im, Seon-Gi 국립문화재연구소 1986 保存科學硏究 Vol.7 No.-

The purpose of this paper is to select the suitable resin as changed in environmental and ingredients, in the conservation of metallic objects. Disposal way of metallic objects were used to various resin and grease which will must be well selected in the nature of relics. The contents of this report are summed up as follows ; The resins of Incralac, Ruscoat, wash primer, Amerlock-400 wrer coated on the slice of ironware (5% saltspray test on the view of nature & Adherence). After the coating, add increasing speed to a corrosion rate, and then the adherence of resins were tested. In this study corrosion test, 0.10-0.25% Amerlock-400 jis proved to be a rare one of corrosion rate and 1.0-2.5% Wash primer is found to be a plenty one of corrosion area.

도.토기의 화학조성-경주 황남대총 출토 도.토기를 중심으로

홍종욱,문환석,황진주,조남철,Hong, Jong-Ouk,Moon, Whan-Suk,Hwong, Jin-Ju,Jo, Nam-Cheol 국립문화재연구소 1999 保存科學硏究 Vol.20 No.-

This paper presents the results of investigation on crystal, firing temperature and trace elements analysis of fragments 4~8 centriesexcavated from Kyong ju historical sites such as Wang kyong,Walsung, Hwangnam great tomb by application of optical microscope, neutron activation analysis and X-ray diffraction. Temper analysis of clay for identification of local or foreign production; Trace elements is not presented a unique chemical composition. That’s data have to be treated a statistical process in order to normalize. The results followed ;(1) Firing temperature could be estimated $700^{\circ}C$ on some softness pottery at Walsung and most of hardness others are $1,000^{\circ}C$ to $1,200^{\circ}C$.(2) Crystal structures are divided into three kinds of mineralogical composition(Quartz, Mullite, Feldspar).(3) Considering of the results of statistical data, chemical composition of Walsung is more similarly Wang kyong than Hwangnam great tomb.