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공성호,김재호 漢陽大學校 環境科學硏究所 2001 環境科學論文集 Vol.22 No.-
본 연구는 국내무연탄의 비연료 활용을 위해 국내무연탄을 원료로 하여 흡착제를 제조하는 것을 목적으로 하고 있다. 우선 활성탄 원료를 제조하기 위해서 중액선탄 방법으로 저회분 탄을 제조하였다. 파쇄탄과, 미분탄과 석탄 타르피치를 혼합하여 제조한 조립탄을 원료로 스팀과 CO_2로 활성화하여 활성탄을 제조하였다. 활성화 전에 알칼리로 처리하여 화학적 전처리의 영향을 고찰하였다. 활성탄의 흡착성능을 위해 액상으로는 페놀, 클로로포름을 중금속 시험으로는 Fe, Cr을, 그리고 기상용 실험으로는 벤젠, 사염화탄소 등을 사용하여 비교하였다. 활성화 결과 파쇄원탄으로 제조된 활성탄은 표면적 650㎡/g, 조립활성탄은 920㎡/g의 활성탄이 제조되었다. 파쇄원탄을 NaOH로 강한조건에서 화학적 처리한 결과 표면적이 650㎡/g에서 840㎡/g으로 증가하였으며 온순조건에서는 기공부피와 burn-off을 증가시키는 효과를 보였다. 화학적으로 처리된 파쇄활성탄과 CO₂로 활성화된 조립활성탄은 미세기공이 발달하여 기상용에 적합하였으며 스팀으로 활성화된 조립활성탄은 기공이 다양하게 발달하여 액상용으로 적합하였다. TPurpose of this study is development of activated carbons from domestic anthracite for non-fuel use. In order to obtain raw materials for activation, preparation of low ash coals by heavy media separation was conducted. Activated carbons were made with steam or CO₂ from crushed coals and granules made by mixing of pulverized coal and coal tar pitches. Treatment with alkali hydroxides was conducted prior to activation for the investigation of the effect of chemical pretreatment on the activation. Test for liquid phase organic compound removal, heavy metal removal and gas phase adsorption have been performed with phenol, chloroform, Fe, Cr, and with fumes of benzene and carbon tetrachloride. Activated carbons of surface area of 650㎡/g from crushed coals and of 920㎡/g from granules were produced. Chemical pretreatment has an effect on the surface area increase from 650㎡/g to 840㎡/g for the crushed raw coals at the strong pretreatment condition, and on the increase of pore size and burn-off by mild pre-treatment condition. It was found that the activated carbons from crushed coals by chemical pretreatment and from CO₂ activation have well developed microporosity, and that the activated carbons from granules by steam activation have wide ranges of porosity that are suitable for gas phase and liquie phase adsorption respectively.
Titaniun Interlayer가 TiN 박막의 밀착특성에 미치는 영향
공성호,김홍유,신영식,김문일 ( S . H . Kong,H . W . Kim,Y . S . Shin,M . I . Kim ) 한국열처리공학회 1992 熱處理工學會誌 Vol.5 No.1
In order to improve adhesive force of TiN film, we sputtered titanium as interlayer before TiN deposition by Plasma Enhanced Chemical Vapour Deposition. We observed changes of hardness and adhsion at a various thickness of titanium interlayer and also examined analysis. At the critical thickness of the titanium interlayer(about 0.2㎛) , adhesive force of TiN films were promoted mostly. But over the critical thickness, a marked reduction of adhesive force was showed, because of the internal stress of titanium interlayer. From AES analysis, the adhesion improvement of TiN films was mainly caused by nitrogen diffusion into titanium interlayer during TiN deposition process which relieved stress concentration at TiN coating-substrate interface.
Surgical Treatment of Gastric Gastrointestinal Stromal Tumor
공성호,양한광 대한위암학회 2013 Journal of gastric cancer Vol.13 No.1
Gastrointestinal stromal tumor is the most common mesenchymal tumor in the gastrointestinal tract and is most frequently developed in the stomach in the form of submucosal tumor. The incidence of gastric gastrointestinal stromal tumor is estimated to be as high as 25% of the population when all small and asymptomatic tumors are included. Because gastric gastrointestinal stromal tumor is not completely distinguished from other submucosal tumors, a surgical excisional biopsy is recommended for tumors >2 cm. The surgical principles of gastrointestinal stromal tumor are composed of an R0 resection with a normal mucosa margin, no systemic lymph node dissection, and avoidance of perforation, which results in peritoneal seeding even in cases with otherwise low risk profiles. Laparoscopic surgery has been indicated for gastrointestinal stromal tumors <5 cm, and the indication for laparoscopic surgery is expanded to larger tumors if the above mentioned surgical principles can be maintained. A simple exogastric resection and various transgastric resection techniques are used for gastrointestinal stromal tumors in favorable locations (the fundus, body, greater curvature side). For a lesion at the gastroesophageal junction in the posterior wall of the stomach, enucleation techniques have been tried preserve the organ’s function. Those methods have a theoretical risk of seeding a ruptured tumor, but this risk has not been evaluated by well-designed clinical trials. While some clinical trials are still on-going, neoadjuvant imatinib is suggested when marginally unresectable or multiorgan resection is anticipated to reduce the extent of surgery and the chance of incomplete resection, rupture or bleeding.
공성호,최용준,유건희,김윤우,박주현,임윤성 대한이비인후과학회 2017 대한이비인후과학회지 두경부외과학 Vol.60 No.2
Background and Objectives Abscess of neck is a life-threatening disease in children. Detection of abscess is important because it is essential for the determination of surgical drainage. However, clinical diagnosis is difficult, because children are seldom able to verbalize their symptoms or cooperate with physical examination. This study aims to review the clinical characteristics of 157 pediatric patients with neck inflammation and investigate the relative risk factors for abscess. Subjects and Method Pediatric patients who were admitted to Dongguk University Hospital from January 2005 to July 2014 with acute neck inflammation were reviewed. All 157 pediatric patients were divided into two groups, based on radiologic findings with and without neck abscess. Results Of 157 patients, 53 children were diagnosed with neck abscess, and peritonsillar abscess was the most common type of neck abscess followed by submandibular abscess, retro·parapharyngeal abscess and posterior triangle & other abscess. The dominant pathogens, staphylococcal infection (≤2 yr) and streptococcal infection (>3 yr), was different for the different age group. The abscess group except for peritonsillar abscess was characterized by younger age, higher heart rate and WBC count, and longer hospital days than those without abscess (p=0.026, 0.026, <0.001, 0.007 respectively). Multivariate analysis revealed younger age (≤24 mo) and higher heart rate were independent predictors for abscess formation (odds ratio: 3.022, 2.923). Conclusion Pediatric patients with high heart rate & younger age are at risk for abscess formation; meticulous care and early imaging work up are required in younger children with deep neck infection, and especially with higher heart rate. Korean J Otorhinolaryngol-Head Neck Surg 2017;60(2):76-82