Controlling the chemo‐ and regioselectivity of transition‐metal‐catalyzed C−C activation remains a great challenge. The transformations of benzocyclobutenones (BCBs) usually involve the cleavage of C1−C2 bond. In this work, an unprecedented ...
http://chineseinput.net/에서 pinyin(병음)방식으로 중국어를 변환할 수 있습니다.
변환된 중국어를 복사하여 사용하시면 됩니다.
https://www.riss.kr/link?id=O107423624
2021년
eng
1433-7851
1521-3773
SCI;SCIE;SCOPUS
학술저널
Angewandte Chemie international edition
19079-19084 [※수록면이 p5 이하이면, Review, Columns, Editor's Note, Abstract 등일 경우가 있습니다.]
0
상세조회0
다운로드다국어 초록 (Multilingual Abstract)
Controlling the chemo‐ and regioselectivity of transition‐metal‐catalyzed C−C activation remains a great challenge. The transformations of benzocyclobutenones (BCBs) usually involve the cleavage of C1−C2 bond. In this work, an unprecedented ...
Controlling the chemo‐ and regioselectivity of transition‐metal‐catalyzed C−C activation remains a great challenge. The transformations of benzocyclobutenones (BCBs) usually involve the cleavage of C1−C2 bond. In this work, an unprecedented highly selective cleavage of C1−C8 bond with the insertion of alkynes is achieved by using blocking strategy via Ni catalysis, providing an efficient method for synthesis of 1,8‐disubstituted naphthalenes. Notably, the blocking group could be readily removed after the transformation.
A Ni‐catalyzed highly selective C1−C8 bond cleavage of BCBs with the insertion of alkynes was achieved by the assistance of a removable blocking group. This method provided an atom‐ and step‐economical approach to structurally important 1,8‐naphthalenediols under pH‐neutral conditions.
Light‐Promoted Organic Transformations Utilizing Carbon‐Based Gas Molecules as Feedstocks