<P><B>Abstract</B></P> <P>Nanoscale transport characteristics and catalyst utilization of vertically aligned carbon nanotube (VACNT) catalyst layers (CLs) are evaluated using a fully statistical modeling approach based o...
http://chineseinput.net/에서 pinyin(병음)방식으로 중국어를 변환할 수 있습니다.
변환된 중국어를 복사하여 사용하시면 됩니다.
https://www.riss.kr/link?id=A107446065
2019
-
SCI,SCIE,SCOPUS
학술저널
465-479(15쪽)
0
상세조회0
다운로드다국어 초록 (Multilingual Abstract)
<P><B>Abstract</B></P> <P>Nanoscale transport characteristics and catalyst utilization of vertically aligned carbon nanotube (VACNT) catalyst layers (CLs) are evaluated using a fully statistical modeling approach based o...
<P><B>Abstract</B></P> <P>Nanoscale transport characteristics and catalyst utilization of vertically aligned carbon nanotube (VACNT) catalyst layers (CLs) are evaluated using a fully statistical modeling approach based on the inherent random nature of the catalyst layer structures for fuel cell applications. Composite morphological structures of the catalyst layers are stochastically modeled with a 95% confidence level, and transport phenomena inside the catalyst layers are simulated using the D3Q19 lattice Boltzmann method (LBM). The effective diffusion coefficient of VACNT catalyst layers is predicted to be higher than that of the conventional catalyst layer, despite a relatively small pore diameter and a low-Knudsen diffusion coefficient. Consequently, the VACNT catalyst layers exhibit improved catalyst utilization compared to the conventional catalyst layers. These statistical results obtained from a series of numerical experiments confirm that the PEFC catalyst layers containing the VACNT catalyst supports can provide more efficient reactant transport, resulting in enhanced catalyst utilization for electrochemical reactions.</P> <P><B>Highlights</B></P> <P> <UL> <LI> A 3-dimensional Lattice Boltzmann method (LBM) was proposed for catalyst modeling. </LI> <LI> Structure–transport characteristics of catalyst layer were statistically predicted. </LI> <LI> VACNT catalyst layers can form more favorable pore structures for mass transport. </LI> <LI> Nanotube forest effects of VACNT catalyst layers induces lower Knudsen diffusion. </LI> <LI> Improved pore design and low tortuosity yield higher catalyst utilization in VACNT. </LI> </UL> </P> <P><B>Graphical abstract</B></P> <P>[DISPLAY OMISSION]</P>