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      Selective Pd recovery from acidic leachates by 3-mercaptopropylphosphonic acid grafted TiO2: does surface coverage correlate to performance?Electronic supplementary information (ESI) available: Evolution of the phosphorus concentration during pressure filtration. N2 physisorption data of the unmodified and 3MPPA modified TiO2 support with different surface coverages. XRD data of the TiO2 support. DRIFT spectra of unmodified and 3MPPA modified TiO2. Negative ToF-SIMS spectra of unmodified and 3MPPA modified TiO2, with detailed overlay of the S−, TiO2SH− and C3H8PO3S− ion fragments. DFT calculated adsorption energies and 31P chemical shifts of a selection of different surface conformations of 3MPPA on anatase (101). Impact of the chlorine concentration on the palladium speciation at pH 2 and pH 5. Comparison between non-linear pseudo first-order and non-linear pseudo second-order fitting on the Pd adsorption kinetics. Calculated S⋯S distances for adjacent 3MPPA groups on anatase (101). XPS S 2p and Pd 3d spectra of 3MPPA modified TiO2, before and after Pd adsorption. Plot of distribution coefficients and adsorption capacities for metals present in the acidic leachate upon adsorption with unmodified TiO2 and 3MPPA modified TiO2 at different surface coverages. Separation factors of Pd relative to Pt, Fe and Cu after adsorption from the acidic leachate for the different surface coverages of 3MPPA. See DOI: https://doi.org/10.1039/d2ra07214a

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      https://www.riss.kr/link?id=O119385814

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