Application of Comprehensive 2D GC-MS and APPI FT-ICR MS for More Complete Understanding of Chemicals in Diesel Fuel

다국어 초록 (Multilingual Abstract)

In this study, comprehensive two dimension gas chromatography (2D GC-MS) and 15 T Fourier transform ion cyclotronresonance mass spectrometry (15T FT-ICR MS) connected to atmospheric pressure photo ionization (APPI) have beencombined to obtain detailed chemical composition of a diesel oil sample. With 2D GC-MS, compounds with aliphatic alkyl, saturatedcyclic ring(s), and one aromatic ring structures were mainly identified. Sensitivity toward aromatic compounds with morethan two aromatic rings was low with 2D GC-MS. In contrast, aromatic compounds containing up to four benzene rings wereidentified by APPI FT-ICR MS. Relatively smaller abundance of cyclic ring compounds were found but no aliphatic alkyl compoundswere observed by APPI FT-ICR MS. The data presented in this study clearly shows that 2D GC-MS and 15T FT-ICRMS provides different aspect of an oil sample and hence they have to be considered as complementary techniques to each otherfor more complete understanding of oil samples.

참고문헌 (Reference)

1 Silva, S. L, 707 : 18-, 2011

2 Adahchour, M, 25 : 726-, 2006

3 Müller, A. L. H, 89 : 82-, 2012

4 Genov, G, 39 : 1229-, 2008

5 Li, M, 197 : 193-, 2002

6 Wang, Z. D, 7 : 105-, 2006

7 Marriott, P. J, 936 : 1-, 2001

8 Tabanca, N, 1097 : 192-, 2005

9 Dallüge, J, 1000 : 69-, 2003

10 Marriott, P, 21 : 573-, 2002

11 Marshall, A. G, 18 : 316-, 1985

12 Maikhunthod, B, 1217 : 1522-, 2010

13 Dutriez, T, 89 : 2338-, 2010

14 Flego, C, 90 : 2863-, 2011

15 Marsman, J. H, 1150 : 21-, 2007

16 Nizio, K. D,

17 Ai-Thamir, W. K, 67 : 871-, 1988

18 Dutriez, T, 96 : 108-, 2012

19 Marshall, A. G, 17 : 1-, 1998

20 Rodgers R. P, 47 : 636-, 2002

21 Wang, J, 85 : 609-, 2011

22 Hughey, C. A, 33 : 743-, 2002

23 Helms, J. R, 44 : 21-, 2012

24 Miyabayashi, K, 89 : 397-, 2008

25 Hur, M, 2009

26 Reichenbach, S. E, 71 : 107-, 2004

27 Murphy, R. E, 70 : 1585-, 1998

28 Reichenbach, S. E, 985 : 47-, 2003

29 Kallio, M, 1148 : 228-, 2007

30 Vendeuvre, C, 1086 : 21-, 2005

31 Adam, F, 1186 : 236-, 2008

32 Cookson, D. J, 66 : 758-, 1987

33 Manhoi Hur, "Optimized Automatic Noise Level Calculations for Broadband FT-ICR Mass Spectra of Petroleum Give More Reliable and Faster Peak Picking Results" 대한화학회 30 (30): 2665-2668, 2009

34 Eunkyoung Kim, "Compositional Characterization of Petroleum Heavy Oils Generated from Vacuum Distillation and Catalytic Cracking by Positive-mode APPI FT-ICR Mass Spectrometry" 사단법인 한국질량분석학회 2 (2): 41-44, 2011