An efficient distal C(sp3)−H azidation of both ketoxime esters and N‐acyloxy imidates for the synthesis of γ‐azido ketones and β‐azido alcohols is reported in the Full Paper by J. Zhu, et al. on page 9477 ff. The artwork represents two e...
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https://www.riss.kr/link?id=O118946618
2019년
-
0947-6539
1521-3765
SCI;SCIE;SCOPUS
학술저널
n/a-n/a [※수록면이 p5 이하이면, Review, Columns, Editor's Note, Abstract 등일 경우가 있습니다.]
0
상세조회0
다운로드다국어 초록 (Multilingual Abstract)
An efficient distal C(sp3)−H azidation of both ketoxime esters and N‐acyloxy imidates for the synthesis of γ‐azido ketones and β‐azido alcohols is reported in the Full Paper by J. Zhu, et al. on page 9477 ff. The artwork represents two e...
An efficient distal C(sp3)−H azidation of both ketoxime esters and N‐acyloxy imidates for the synthesis of γ‐azido ketones and β‐azido alcohols is reported in the Full Paper by J. Zhu, et al. on page 9477 ff. The artwork represents two essential processes of the proposed mechanism: the 1,5‐hydrogen atom transfer of an imine/imidate radical through a chair‐like transition state, and the iron‐mediated redox azido transfer to the translocated carbon radical.
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