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    Elasticity-controlled molecular dynamics of 9,9′-bifluorenyldene as a function of temperature and force

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    https://www.riss.kr/link?id=A107555395

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    <P>Medium elasticity is an important coupling parameter that influences the molecular motions that occur in solids. In this work, the light-induced twisting motion of 9,9′-bifluorenyldene (BF) was investigated in an elastic polymer, ultra low density polyethylene (ULDPE), as a function of temperature and applied force. Analysis of the BF fluorescence lifetime in accordance with the modulus change of the ULDPE showed that temperature and force significantly affected the excited-state molecular dynamics in the elasticity-controlled regime.</P>

    <P>Graphic Abstract</P><P>We investigated the light-induced twisting motion of 9,9′-bifluorenyldene in an elastic polymer as a function of temperature and applied force, which showed that temperature and force significantly affected the excited-state molecular dynamics in the elasticity-controlled regime.
    <IMG SRC='http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=c2nj40092h'>
    </P>
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    <P>Medium elasticity is an important coupling parameter that influences the molecular motions that occur in solids. In this work, the light-induced twisting motion of 9,9′-bifluorenyldene (BF) was investigated in an elastic polymer, ultra ...

    <P>Medium elasticity is an important coupling parameter that influences the molecular motions that occur in solids. In this work, the light-induced twisting motion of 9,9′-bifluorenyldene (BF) was investigated in an elastic polymer, ultra low density polyethylene (ULDPE), as a function of temperature and applied force. Analysis of the BF fluorescence lifetime in accordance with the modulus change of the ULDPE showed that temperature and force significantly affected the excited-state molecular dynamics in the elasticity-controlled regime.</P>

    <P>Graphic Abstract</P><P>We investigated the light-induced twisting motion of 9,9′-bifluorenyldene in an elastic polymer as a function of temperature and applied force, which showed that temperature and force significantly affected the excited-state molecular dynamics in the elasticity-controlled regime.
    <IMG SRC='http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=c2nj40092h'>
    </P>

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