Preparation of Multi-Functional Polyester Fabrics with the Use of a New Organo-Clay Nanopigment in High Temperature/High Pressure Condition

다국어 초록 (Multilingual Abstract)

For the first time, the ability of dyeing the montmorillonite (Mt) mineral with reactive dye aiming to prepare a newnanopigment was investigated and the optimum conditions were determined. The prepared nanopigment was characterizedby Fourier-transform infrared spectra (FTIR), transmission electron microscope (TEM), Brunauer-Emmett-Teller (BET),reflectance spectrophotometer (RS) and colorimetry analyses. The results showed that the dye molecules were attached to thehydroxyl groups of Mt plates through a covalent linkage. Also, the BET surface area values slightly increased after the dyeingprocess due to the separation of Mt plates and the reduction of particle size because of penetration of dye molecules amongthe plates. Colorimetry analysis revealed that the intercalation of dye molecules was depended on dye concentration andnumber of reactive sites on the Mt surface. The prepared nanopigment was used for dyeing the polyester fabric in highpressure and temperature conditions. The SEM, colorimetry, electromagnetic reflectance, flammability, and TGA tests wereperformed to investigate the properties of fabrics. Results indicated that intercalation of Mt nanopigment in the polyester fiberenhances the flame retardant, electromagnetic reflection and breathability of fabrics. Also, the optimum amount ofnanopigment in the dyeing process was reported. It can be suggested that the prepared fabric can be a good candidate forutilizing in military and electronic aspects.

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