The kinetics for decawite of etW enu pulymerizution catalyzed with fiCl, IcCI. Sio. has been investiated in the rancc of temperatures tetaeen 40 and 90C and in the range of ethylene pressures bwen 4 and 13=I atm. hhe decay of IxIwerizalion rate eras f...
The kinetics for decawite of etW enu pulymerizution catalyzed with fiCl, IcCI. Sio. has been investiated in the rancc of temperatures tetaeen 40 and 90C and in the range of ethylene pressures bwen 4 and 13=I atm. hhe decay of IxIwerizalion rate eras fitted well ht the ype of first order dec. The deay rate constant caused by nunennrr could Ire expressed by k.i-C. M. Some plnusibl specnlaticms htwc been propnsed on the deactivtic? merlt mism caused by numomer. THE activation enery for the deactivation reaction is 9.3 kcal mole.