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      SPAEK-based binary blends and ternary composites as proton exchange membranes for DMFCs

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      https://www.riss.kr/link?id=A107672977

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      Naphthalene-containing blend membranes, comprising sulfonated polyaryletherketone (SPAEK) as the primary matrix, and basic component polyazomethine (PAM), which has a chemical structure partially similar with SPAEK, were investigated as proton exchange membranes (PEMs). Further, a ternary-composite membrane was successfully prepared by introducing acid-functionalized polysilsesquioxane (POSS-SO<SUB>3</SUB>H) into SPAEK/PAM composite using a sol-gel process. The relevant properties of the PEMs, such as proton conductivity, methanol permeability, water uptake, and morphology were determined, and it was shown that the ternary-composite membrane, SPAEK/PAM/POSS-SO<SUB>3</SUB>H, showed a superior combination of properties for proton conductivity and methanol resistance. Its selectivity was 7.5 times higher than Nafion.
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      Naphthalene-containing blend membranes, comprising sulfonated polyaryletherketone (SPAEK) as the primary matrix, and basic component polyazomethine (PAM), which has a chemical structure partially similar with SPAEK, were investigated as proton exchang...

      Naphthalene-containing blend membranes, comprising sulfonated polyaryletherketone (SPAEK) as the primary matrix, and basic component polyazomethine (PAM), which has a chemical structure partially similar with SPAEK, were investigated as proton exchange membranes (PEMs). Further, a ternary-composite membrane was successfully prepared by introducing acid-functionalized polysilsesquioxane (POSS-SO<SUB>3</SUB>H) into SPAEK/PAM composite using a sol-gel process. The relevant properties of the PEMs, such as proton conductivity, methanol permeability, water uptake, and morphology were determined, and it was shown that the ternary-composite membrane, SPAEK/PAM/POSS-SO<SUB>3</SUB>H, showed a superior combination of properties for proton conductivity and methanol resistance. Its selectivity was 7.5 times higher than Nafion.

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