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      KCI등재

      경유 대체 합성연료로서 OME 혼합 사용시 예상되는 기본 연소 특성 변화 및 생성물 예측 = Predicting Fundamental Combustion Properties and Products from Synthetic Oxymethylene Ethers as an E-diesel Blendstock

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      https://www.riss.kr/link?id=A108400530

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      다국어 초록 (Multilingual Abstract)

      Ignition delay times and counterflow diffusion flame products are predicted by blending oxymethylene ether-2 (OME-2) into a surrogate diesel. OME-2 is one of a promising e-diesel blendstock which is synthesized from carbon dioxide and hydrogen, thereb...

      Ignition delay times and counterflow diffusion flame products are predicted by blending oxymethylene ether-2 (OME-2) into a surrogate diesel. OME-2 is one of a promising e-diesel blendstock which is synthesized from carbon dioxide and hydrogen, thereby reducing net carbon emission from a carbon life-cycle perspective. Results show that OME-2 is more reactive in engine-relevant conditions and the formation of particulate matter from a diffusion flame could be suppressed, thanks to its higher oxygen content. However, potentially harmful intermediates, e.g., formaldehyde and methyl formate, could be formed in large quantity with the use of OME-2, therefore novel combustion strategy and proper exhaust after-treatment system shall be essential for its practical use.

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      참고문헌 (Reference) 논문관계도

      1 이기용, "대용 디젤연료의 대향류 비예혼합 화염에서 Methyl Decanoate 첨가가 방향족 생성에 미치는 영향" 한국연소학회 24 (24): 11-17, 2019

      2 W. Sun, "Speciation and the laminar burning velocities of poly(oxymethylene)dimethyl ether 3(POMDME3)flames : an experimental and modeling study" 36 : 1269-1278, 2017

      3 C. W. Gao, "Reaction Mechanism Generator: Automatic construction of chemical kinetic mechanisms" 203 : 212-225, 2016

      4 L. Golka, "Pyrolysis of dimethoxymethane and the reaction of dimethoxymethane with H atoms: a shock-tube/ARAS/TOF-MS and modeling study" 37 : 179-187, 2019

      5 V. Dieterich, "Power-to-liquid via synthesis of methanol, DME or Fischer–Tropsch-fuels: a review" 13 (13): 3207-3252, 2020

      6 D. Pélerin, "Potentials to simplify the engine system using the alternative diesel fuels oxymethylene ether OME1 and OME3−6 on a heavy-duty engine" 259 : 116231-, 2020

      7 A. Omari, "Potential of long-chain oxymethylene ether and oxymethylene ether-diesel blends for ultra-low emission engines" 239 : 1242-1249, 2019

      8 J. Wullenkord, "Laminar premiexed and non-premixed flame investigation on the influence of dimethyl ether addition on n-heptane combustion" 212 : 323-336, 2020

      9 K. Seshadri, "Laminar flow between parallel plates with injection of a reactant at high reynolds number" 21 (21): 251-253, 1978

      10 "IEA World Energy Outlook 2020" International Energy Agency 2020

      1 이기용, "대용 디젤연료의 대향류 비예혼합 화염에서 Methyl Decanoate 첨가가 방향족 생성에 미치는 영향" 한국연소학회 24 (24): 11-17, 2019

      2 W. Sun, "Speciation and the laminar burning velocities of poly(oxymethylene)dimethyl ether 3(POMDME3)flames : an experimental and modeling study" 36 : 1269-1278, 2017

      3 C. W. Gao, "Reaction Mechanism Generator: Automatic construction of chemical kinetic mechanisms" 203 : 212-225, 2016

      4 L. Golka, "Pyrolysis of dimethoxymethane and the reaction of dimethoxymethane with H atoms: a shock-tube/ARAS/TOF-MS and modeling study" 37 : 179-187, 2019

      5 V. Dieterich, "Power-to-liquid via synthesis of methanol, DME or Fischer–Tropsch-fuels: a review" 13 (13): 3207-3252, 2020

      6 D. Pélerin, "Potentials to simplify the engine system using the alternative diesel fuels oxymethylene ether OME1 and OME3−6 on a heavy-duty engine" 259 : 116231-, 2020

      7 A. Omari, "Potential of long-chain oxymethylene ether and oxymethylene ether-diesel blends for ultra-low emission engines" 239 : 1242-1249, 2019

      8 J. Wullenkord, "Laminar premiexed and non-premixed flame investigation on the influence of dimethyl ether addition on n-heptane combustion" 212 : 323-336, 2020

      9 K. Seshadri, "Laminar flow between parallel plates with injection of a reactant at high reynolds number" 21 (21): 251-253, 1978

      10 "IEA World Energy Outlook 2020" International Energy Agency 2020

      11 L. Marrodán, "High pressure oxidation of dimethoxymethane" 29 : 3507-3517, 2015

      12 B. Chen, "Exploring the combustion chemistry of anisole in laminar counterflow diffusionflames under oxy-fuel conditions" 243 : 111929-, 2022

      13 S. A. Issacs, "Environmental and Economic Performance of Hybrid Power-to-Liquid and Biomass-to-Liquid Fuel Production in the United States" 55 (55): 8247-8257, 2021

      14 S. W. Wagnon, "Effects of buffer gas composition on autoignition" 161 (161): 898-907, 2014

      15 S. Jacobs, "Detailed kinetic modeling of dimethoxymethane. Part II: experimental and theoretical study of the kinetics and reaction mechanism" 205 : 522-533, 2019

      16 J. A. Cooke, "Computational and experimental study of JP-8, a surrogate, and its component in counterflow diffusion flames" 30 : 439-446, 2005

      17 J. Yanowitz, "Compendium of Experimental Cetane Numbers" National Renewable Energy Laboratory 2017

      18 D. G. Goodwin, "Cantera: An object-oriented software toolkit for chemical kinetics, thermodynamics, and transport processes, Version 2.6.0"

      19 S. M. Sarathy, "An experimental and kinetic modeling study of methyl decanoate combustion" 33 (33): 399-405, 2011

      20 K. De Ras, "A detailed experimental and kinetic modeling study on pyrolysis and oxidation of oxymethylene ether-2 (OME-2)" 238 : 111914-, 2022

      21 L. Xu, "A comparative study of the sooting tendencies of various C5-C8 alkanes, alkenes and cycloalkanes in counterflow diffusion flames" 1-4 : 100007-, 2020

      22 T. He, "A chemical kinetic mechanism for the low- and intermediate-temperature combustion of Polyoxymethylene Dimethyl Ether 3 (PODE3)" 212 : 223-235, 2018

      23 Y. Pei, "A Multicomponent Blend as a Diesel Fuel Surrogate for Compression Ignition Engine Applications" 137 (137): 111502-, 2015

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