Removal of Sr²⁺ using high-surface-area hydroxyapatite synthesized by non-additive in-situ precipitation

다국어 초록 (Multilingual Abstract)

<P><B>Abstract</B></P> <P>Owing to their high-risk factor, many attempts have been made to remove radionuclides from water. Sr<SUP>2+</SUP> ions are the target of removal by synthesized hydroxyapatite in this research. A facile method for synthesizing high-surface-area hydroxyapatite by in-situ precipitation using excess diammonium phosphate solution and without any additive was developed. The highest surface area achieved using this method was 177.00 m<SUP>2</SUP>/g, and the synthesized hydroxyapatite was also mesoporous. The effects of different pH, temperatures, and ion concentrations during synthesis on the properties of the hydroxyapatite were assessed, and it was found that a low temperature and high pH were optimal for synthesizing high-surface-area hydroxyapatite. The maximum strontium removal capacity of 28.51 mg/g was achieved when the pH-7.5 solution was used. This performance is competitive in comparison with previously developed synthesized materials. Synthesized hydroxyapatite could effectively remove radioactive strontium from an aqueous solution for nuclear waste management.</P> <P><B>Highlights</B></P> <P> <UL> <LI> Hydroxyapatite was produced an using in-situ precipitation without an additive. </LI> <LI> It had a high surface area of 177 m<SUP>2</SUP>/g and mesopores with a Ca/P ratio of 1.67. </LI> <LI> Its maximum removal capacity of strontium was 28.51 mg/g at pH 7.5. </LI> <LI> It can remove radioactive strontium from an aqueous solution. </LI> </UL> </P> <P><B>Graphical abstract</B></P> <P>[DISPLAY OMISSION]</P>