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      Preparation and Characterization of Crosslinked Anion Exchange Membrane Using Electron Beam Irradiation

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      https://www.riss.kr/link?id=A107239455

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      다국어 초록 (Multilingual Abstract)

      The novel crosslinked anion exchange membrane with a high ion exchange capacityand stability was fabricated through a room temperature and solid-state radiation processing. Theanion-exchange membrane was prepared by solution casting method at the diff...

      The novel crosslinked anion exchange membrane with a high ion exchange capacityand stability was fabricated through a room temperature and solid-state radiation processing. Theanion-exchange membrane was prepared by solution casting method at the different compositionsof poly(diallyldimethylammonium chloride) and PVA substituted with methacryloyl group,and subsequently irradiated by electron beam to form 3D-network structure. From the variousanalytical results, the 3D-network crosslinked anion-exchange membrane exhibited not only ahigh ion exchange capacity (>1.7 meq·g-1) but a superior water stability (water uptake ≤ 30%)through a room temperature and quick radiation crosslinking process. Also, the prepared anionexchange membrane had better thermal stability compared to non crosslinked anion exchangemembrane (control).

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      참고문헌 (Reference)

      1 손준용, "전자선 조사로 제조된 Sulfonated Polystyrene/Trimethylolpropane Ethoxylate Triacrylate(SPS/TMPETA) 막의 가교제 함량에 따른 특성분석" 한국고분자학회 40 (40): 47-53, 2016

      2 Wang J, "Synthesis and characterization of cross-linked poly (arylene ether ketone) containing pendant quaternary ammonium groups for anion-exchange membranes" 415-416 : 205-212, 2012

      3 Maurya S, "Stability of composite anion exchange membranes with various functional groups and their performance for energy conversion" 443 : 28-35, 2013

      4 Bhattacharya A, "Radiation and industrial polymers" 25 : 371-401, 2000

      5 Choi J-H, "Preparation and charaterization of crosslinked poly(butylene adipate-co-terephthalate)/polyhedral oligomeric silsesquioxane nanocomposite by electron beam irradiation" 82 : 100-105, 2013

      6 Kariduraganavar MY, "Ion-exchange membranes : preparative methods for electrodialysis and fuel cell applications" 197 : 225-246, 2006

      7 Strathmann H, "Ion exchange membranes in the chemical process industry" 52 : 10364-10379, 2013

      8 Ran J, "Ion exchange membranes : new developments and applications" 522 : 267-291, 2017

      9 Nasef MM, "Ion Exchange Technology I: Theory and Materials" Springer 1-40, 2012

      10 Clough RL, "High-energy radiation and polymers : A review of commercial processes and emerging application" 185 : 8-33, 2001

      1 손준용, "전자선 조사로 제조된 Sulfonated Polystyrene/Trimethylolpropane Ethoxylate Triacrylate(SPS/TMPETA) 막의 가교제 함량에 따른 특성분석" 한국고분자학회 40 (40): 47-53, 2016

      2 Wang J, "Synthesis and characterization of cross-linked poly (arylene ether ketone) containing pendant quaternary ammonium groups for anion-exchange membranes" 415-416 : 205-212, 2012

      3 Maurya S, "Stability of composite anion exchange membranes with various functional groups and their performance for energy conversion" 443 : 28-35, 2013

      4 Bhattacharya A, "Radiation and industrial polymers" 25 : 371-401, 2000

      5 Choi J-H, "Preparation and charaterization of crosslinked poly(butylene adipate-co-terephthalate)/polyhedral oligomeric silsesquioxane nanocomposite by electron beam irradiation" 82 : 100-105, 2013

      6 Kariduraganavar MY, "Ion-exchange membranes : preparative methods for electrodialysis and fuel cell applications" 197 : 225-246, 2006

      7 Strathmann H, "Ion exchange membranes in the chemical process industry" 52 : 10364-10379, 2013

      8 Ran J, "Ion exchange membranes : new developments and applications" 522 : 267-291, 2017

      9 Nasef MM, "Ion Exchange Technology I: Theory and Materials" Springer 1-40, 2012

      10 Clough RL, "High-energy radiation and polymers : A review of commercial processes and emerging application" 185 : 8-33, 2001

      11 Hwang I-T, "Electron beam-induced crosslinking of poly(butylene adipate-co-terephthalate)" 268 : 3386-3389, 2010

      12 Kim H-S, "Electron beam-based fabrication of crosslinked hydrophilic carbon electrodes and their application for capacitive deionization" 9 : 9684-9691, 2019

      13 Strathmann H, "Electrodialysis, a mature technology with a multitude of new applications" 264 : 268-288, 2010

      14 Woo H-S, "EB-crosslinked polymer electrolyte membranes based on highly sulfonated poly(ether ether ketone)and poly(vinylidene fluoride)/triallyl isocyanurate" 15 : 781-789, 2015

      15 Khan MI, "Design of Anion exchange membranes and electrodialysis studies for water desalination" 9 : 1-14, 2016

      16 Zhang J, "Cross-linked poly(vinyl alcohol)/poly(diallyldimethylammonium chloride)as anion-exchange membrane for fuel cell applications" 240 : 359-367, 2013

      17 Varcoe JR, "Anion-exchange membranes in electrochemical energy systems" 7 : 3135-3191, 2014

      18 송주명, "12HPW/meso-SiO2 nanocomposite CSPEEK membranes for proton exchange membrane fuel cells" 한국공업화학회 36 : 132-138, 2016

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      2027 평가예정 재인증평가 신청대상 (재인증)
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