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      KCI등재 SCOPUS SCIE

      Decoupling effect of electrical and thermal properties of Bi2Te3-polypyrrole hybrid material causing remarkable enhancement in thermoelectric performance

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      https://www.riss.kr/link?id=A106442519

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      다국어 초록 (Multilingual Abstract)

      We provided a Bi2Te3-polypyrrole hybrid material, in which energy band junction and phonon scatteringeffects should appear at the interface of the two components. The hybrid material exhibited increases inelectrical resistivity and the Seebeck coeffic...

      We provided a Bi2Te3-polypyrrole hybrid material, in which energy band junction and phonon scatteringeffects should appear at the interface of the two components. The hybrid material exhibited increases inelectrical resistivity and the Seebeck coefficient due the energy band junction, thus retaining the powerfactor without loss, whereas showing a great reduction in thermal conductivity because of the phononscattering at the interface. This significant decoupling of electrical and thermal properties resulted inpredominantfigures of merit (ZTmax1.21 at 100 C and ZTave1.18 at 50–150 C) among n-type Bi2Te3or Bi2(Te,Se)3 materials previously reported.

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      참고문헌 (Reference)

      1 J. He, 357 : 2017

      2 P. Kumar, 46 : 285301-, 2013

      3 Z. Wang, 419 : 51-, 2013

      4 Z. G. Chena, 319 : 535-, 2012

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      7 Min Hong, "n -Type Bi 2 Te 3– x Se x Nanoplates with Enhanced Thermoelectric Efficiency Driven by Wide-Frequency Phonon Scatterings and Synergistic Carrier Scatterings" American Chemical Society (ACS) 10 (10): 4719-4727, 2016

      8 류병기, "Work Function of Bismuth Telluride: First-Principles Approach" 한국물리학회 72 (72): 122-128, 2018

      9 Ming He, "Towards high-performance polymer-based thermoelectric materials" Royal Society of Chemistry (RSC) 6 (6): 1352-, 2013

      10 Fang Wu, "Thermoelectric properties of I-doped n-type Bi 2 Te 3 -based material prepared by hydrothermal and subsequent hot pressing" Elsevier BV 27 (27): 203-207, 2017

      1 J. He, 357 : 2017

      2 P. Kumar, 46 : 285301-, 2013

      3 Z. Wang, 419 : 51-, 2013

      4 Z. G. Chena, 319 : 535-, 2012

      5 Q. Jiang, 9 : 7540-, 2014

      6 K. Xiong, 43 : 115303-115301, 2010

      7 Min Hong, "n -Type Bi 2 Te 3– x Se x Nanoplates with Enhanced Thermoelectric Efficiency Driven by Wide-Frequency Phonon Scatterings and Synergistic Carrier Scatterings" American Chemical Society (ACS) 10 (10): 4719-4727, 2016

      8 류병기, "Work Function of Bismuth Telluride: First-Principles Approach" 한국물리학회 72 (72): 122-128, 2018

      9 Ming He, "Towards high-performance polymer-based thermoelectric materials" Royal Society of Chemistry (RSC) 6 (6): 1352-, 2013

      10 Fang Wu, "Thermoelectric properties of I-doped n-type Bi 2 Te 3 -based material prepared by hydrothermal and subsequent hot pressing" Elsevier BV 27 (27): 203-207, 2017

      11 Mi-Kyung Han, "Thermoelectric Properties of Bi2Te3: CuI and the Effect of Its Doping with Pb Atoms" MDPI AG 10 (10): 1235-, 2017

      12 Chul Oh Yoon, "The effect of low-temperature conditions on the electrochemical polymerization of polypyrrole films with high density, high electrical conductivity and high stability" Elsevier BV 99 (99): 201-212, 1999

      13 S. Chen, "The Effect of Cu Addition on the System Stability and Thermoelectric Properties of Bi2Te3" Springer Science and Business Media LLC 43 (43): 1966-1971, 2014

      14 Jakeer Husain, "Synthesis, characterization, and electrical conductivity of polypyrrole/zinc oxide nanocomposites" Informa UK Limited 515 (515): 120-126, 2017

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      16 Mario Culebras, "Review on Polymers for Thermoelectric Applications" MDPI AG 7 (7): 6701-6732, 2014

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      19 B. Zhang, "Promising Thermoelectric Properties of Commercial PEDOT:PSS Materials and Their Bi 2 Te 3 Powder Composites" American Chemical Society (ACS) 2 (2): 3170-3178, 2010

      20 Pallavi Mavinakuli, "Polypyrrole/Silicon Carbide Nanocomposites with Tunable Electrical Conductivity" American Chemical Society (ACS) 114 (114): 3874-3882, 2010

      21 Andrea Briones Gonçalves, "Polymerization of pyrrole between the layers of α-Tin (IV) Bis(hydrogenphosphate)" Elsevier BV 114 (114): 119-124, 2000

      22 Jiao Wang, "Photoresponsive polypyrrole- TiO2 nanoparticles film fabricated by a novel surface initiated polymerization" Elsevier BV 146 (146): 239-244, 2008

      23 Yichao Jia, "Photoelectrochemical properties of polypyrrole/TiO2 nanotube arrays nanocomposite under visible light" Elsevier BV 258 (258): 6627-6631, 2012

      24 Naoki Toshima, "Organic–Inorganic Nanohybrids as Novel Thermoelectric Materials: Hybrids of Polyaniline and Bismuth(III) Telluride Nanoparticles" Springer Science and Business Media LLC 40 (40): 898-902, 2011

      25 Joseph R. Sootsman, "New and Old Concepts in Thermoelectric Materials" Wiley 48 (48): 8616-8639, 2009

      26 Cham Kim, "Morphological characteristics in polycrystalline tungsten diselenide regulating transport properties lead to predominant thermoelectric performance" Elsevier BV 722 : 183-189, 2017

      27 H. J. Goldsmid, "Introduction to Thermoelectricity" Springer 2009

      28 Panagiotis Dallas, "Interfacial polymerization of pyrrole and in situ synthesis of polypyrrole/silver nanocomposites" Elsevier BV 48 (48): 2007-2013, 2007

      29 Dong Hwan Kim, "Influence of powder morphology on thermoelectric anisotropy of spark-plasma-sintered Bi–Te-based thermoelectric materials" Elsevier BV 59 (59): 405-411, 2011

      30 Yu-Chuan Liu, "In situ cyclic voltammetry-surface-enhanced Raman spectroscopy: studies on the doping–undoping of polypyrrole film" Elsevier BV 374 (374): 85-91, 2000

      31 Haijun Song, "Improved Thermoelectric Performance of Free-Standing PEDOT:PSS/Bi2Te3 Films with Low Thermal Conductivity" Springer Science and Business Media LLC 42 (42): 1268-1274, 2013

      32 Biao Xu, "Highly Porous Thermoelectric Nanocomposites with Low Thermal Conductivity and High Figure of Merit from Large-Scale Solution-Synthesized Bi 2 Te 2.5 Se 0.5 Hollow Nanostructures" Wiley 56 (56): 3546-3551, 2017

      33 D. Li, "High thermoelectric performance of n-type Bi 2 Te 2.7 Se 0.3 via nanostructure engineering" Royal Society of Chemistry (RSC) 6 (6): 9642-9649, 2018

      34 Yongming Li, "High performance resistive switching memory organic films prepared through PPy growing on graphene oxide substrate" Springer Science and Business Media LLC 26 (26): 9001-9009, 2015

      35 Y. Zhang, "High Yield Bi 2 Te 3 Single Crystal Nanosheets with Uniform Morphology via a Solvothermal Synthesis" American Chemical Society (ACS) 13 (13): 645-651, 2013

      36 Kunihisa Kato, "Fabrication of Bismuth Telluride Thermoelectric Films Containing Conductive Polymers Using a Printing Method" Springer Science and Business Media LLC 42 (42): 1313-1318, 2013

      37 Wenshou Wang, "Epitaxial Growth of Shape-Controlled Bi 2 Te 3 −Te Heterogeneous Nanostructures" American Chemical Society (ACS) 132 (132): 17316-17324, 2010

      38 Renshuang Zhai, "Enhancing Thermoelectric Performance of n-Type Hot Deformed Bismuth-Telluride-Based Solid Solutions by Nonstoichiometry-Mediated Intrinsic Point Defects" American Chemical Society (ACS) 9 (9): 28577-28585, 2017

      39 Sang Il Kim, "Enhancement of Seebeck Coefficient in Bi$_{0.5}$Sb$_{1.5}$Te$_{3}$ with High-Density Tellurium Nanoinclusions" IOP Publishing 4 (4): 091801-, 2011

      40 S. Sumithra, "Enhancement in Thermoelectric Figure of Merit in Nanostructured Bi2Te3 with Semimetal Nanoinclusions" Wiley 1 (1): 1141-1147, 2011

      41 Lei Yang, "Enhanced Thermoelectric Performance of Nanostructured Bi 2 Te 3 through Significant Phonon Scattering" American Chemical Society (ACS) 7 (7): 23694-23699, 2015

      42 H. J. Goldsmid, "Electronic Refrigeration" Pion Limited 1986

      43 Fang Wu, "Effects of Different Morphologies of Bi2Te3 Nanopowders on Thermoelectric Properties" Springer Science and Business Media LLC 42 (42): 1140-1145, 2013

      44 K. M. F. Shahil, "Crystal symmetry breaking in few-quintuple Bi2Te3 films: Applications in nanometrology of topological insulators" AIP Publishing 96 (96): 153103-, 2010

      45 Nidhi Dubey, "Conducting polymers: Efficient thermoelectric materials" Wiley 49 (49): 467-475, 2011

      46 Jannick Duchet, "Chemical synthesis of polypyrrole: structure–properties relationship" Elsevier BV 98 (98): 113-122, 1998

      47 S. Machida, "Chemical synthesis of highly electrically conductive polypyrrole" Elsevier BV 31 (31): 311-318, 1989

      48 G. A. Slack, "CRC Handbook of Thermoelectrics" CRC Press 1995

      49 Fengjiao Liu, "A micro-Raman study of exfoliated few-layered n-type Bi2 Te2.7Se0.3" Springer Science and Business Media LLC 7 (7): 16535-16531, 2017

      50 H. Fritzsche, "A general expression for the thermoelectric power" Elsevier BV 9 (9): 1813-1815, 1971

      51 Fredrick Kim, "3D printing of shape-conformable thermoelectric materials using all-inorganic Bi2Te3-based inks" Springer Science and Business Media LLC 3 (3): 301-309, 2018

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