<P>A Pd(II)-catalyzed reaction engaging alkenyl β-keto esters is reported that leads to the formation of 1-naphthols and an unexpected generation of arylpalladium(II) species. Interception of the in situ generated arylpalladium(II) species ...
http://chineseinput.net/에서 pinyin(병음)방식으로 중국어를 변환할 수 있습니다.
변환된 중국어를 복사하여 사용하시면 됩니다.
https://www.riss.kr/link?id=A107674789
2012
-
SCOPUS,SCIE
학술저널
11308-11311(4쪽)
0
상세조회0
다운로드다국어 초록 (Multilingual Abstract)
<P>A Pd(II)-catalyzed reaction engaging alkenyl β-keto esters is reported that leads to the formation of 1-naphthols and an unexpected generation of arylpalladium(II) species. Interception of the in situ generated arylpalladium(II) species ...
<P>A Pd(II)-catalyzed reaction engaging alkenyl β-keto esters is reported that leads to the formation of 1-naphthols and an unexpected generation of arylpalladium(II) species. Interception of the in situ generated arylpalladium(II) species in a Mizoroki–Heck reaction, together with additional mechanistic studies, provided strong evidence in support of the first <I>aromatization-driven</I> β-carbon elimination process. A single Pd catalyst served to promote a series of both C–C bond forming and cleavage events in an unprecedented manner.</P><P><B>Graphic Abstract</B>
<IMG SRC='http://pubs.acs.org/appl/literatum/publisher/achs/journals/content/jacsat/2012/jacsat.2012.134.issue-28/ja304616q/production/images/medium/ja-2012-04616q_0002.gif'></P><P><A href='http://pubs.acs.org/doi/suppl/10.1021/ja304616q'>ACS Electronic Supporting Info</A></P>