Cd^II MOFs Constructed Using Succinate and Bipyridyl Ligands: Photoluminescence and Heterogeneous Catalytic Activity

다국어 초록 (Multilingual Abstract)

Four $Cd^{II}$ MOFs, $[Cd_2({\mu}-succinate)_2(H_2O)_2]{\cdot}H_2O$ (1A), $[Cd_2({\mu}-succinate)_2({\mu}-4,4^{\prime}-bpy)_2]{\cdot}H_2O$ (1B), $[\{Cd_2({\mu}-succinate)_2\}({\mu}-bpa)_2\{Cd(H_2O)_2\}(NO_3)_2]{\cdot}H_2O$ (2), and $[Cd({\mu}-succinate)({\mu}-bpp)_2]{\cdot}2H_2O$ (3), with various bipyridyl ligands (4,4'-bipyridine (4,4'-bpy), 1,2-bis(4-pyridyl)ethane (bpa), and 1,3-bis(4-pyridyl)propane (bpp)) were prepared, and their structures were determined using X-ray crystallography. The structures and dimensionalities of $Cd^{II}$-(succinate) compounds varied depending on the auxiliary ligands. Heterogeneous catalytic activity for transesterification reactions, photoluminescence and the thermal stabilities of these compounds were also examined.

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