Synthesis and Characterization of Organosilane Electrolyte Containing Silphenylene

다국어 초록 (Multilingual Abstract)

Organosilicon compound containing silphenylene unit as an eletrolyte for the application of lithium-ion batteries was synthesized by hydrosilylation method between 1,4-bis(dimethylsilylhydro)benzene and 3-[2-(2-methoxyethoxy)ethoxy]-1- propene. As-prepared new organosilicon compounds containing spacer such as propyl group with ethylene glycol are synthesized to improve thermal stability and to promote conductivity. The products are characterized by spectroscopic analysis.

참고문헌 (Reference)

1 U. Lauter, "Vinyl-substituted silphenylene siloxane copolymers : novel high-temperature elastomers" 32 : 3426-3431, 1999

2 X. Yang, "Synthesis and properties of silphenylene-containing epoxy resins with high UV-stability" 48 : 692-700, 2011

3 X. Zuo, "Synthesis and characterization of siloxane resins derived from silphenylene-siloxane copolymers bearing benzocyclobutene pendant groups" 46 : 7868-7881, 2008

4 M. Sajjad, "Study of the effect of the concentration, size and surface chemistry of zirconia and silica nanoparticle fillers within an epoxy resin on the bulk properties of the resulting nanocomposites" 61 : 274-285, 2012

5 N. A. A. Rossi, "Silicon-containing liquid polymer electrolytes for application in lithium ion batteries" 58 : 267-272, 2009

6 M. S. Ding, "Physicochemical properties of non-aqueous solvents and electrolytes for lithium battery applications" 16 : 183-214, 2009

7 K. Amine, "Novel silane compounds as electrolyte solvents for Li-ion batteries" 8 : 429-433, 2006

8 X. Wang, "Nonflammable trimethyl phosphate solvent-containing electrolytes for lithium-ion batteries: I. fundamental properties" 148 : A1058-A1065, 2001

9 X. Wang, "Nonflammable trimethyl phosphate solvent-containing electrolytes for lithium-ion batteries : II. the use of an amorphous carbon anode" 148 : A1066-A1071, 2001

10 고경국, "New Synthetic Method of Perfluoro-Silanes for the Stable Electrolyte of Lithium Ion Battery Application" 기초과학연구원 10 (10): 171-174, 2017

11 B. Scrosati, "History of lithium batteries" 15 : 1623-1630, 2011

12 Y. E. Hyung, "Flameretardant additives for lithium-ion batteries" 119-121 : 383-387, 2003

13 M. Lewin, "Fire Retardancy of Polymers:The Use of Intumescence" Athenaeum Press 3-, 1998

14 K. Xu, "Evaluation of fluorinated alkyl phosphates as flame retardants in electrolytes for Li-ion batteries : II. performance in cell" 150 : A170-A175, 2003

15 K. Xu, "Evaluation of fluorinated alkyl phosphates as flame retardants in electrolytes for Li-ion batteries : I. physical and electrochemical properties" 150 : A161-A169, 2003

16 M. S. Ding, "Effects of tris(2, 2, 2-trifluoroethyl)phosphate as a flameretarding cosolvent on physicochemical properties of electrolytes of LiPF6 in EC-PC-EMC of 3 : 3 : 4weight ratios" 149 : A1489-A1498, 2002

17 S. L. Levan, "Effects of Fire Retardant Treatments on Wood Strength: A Review" 22 : 113-131, 1990

18 X. L. Yao, "Comparative study of trimethyl phosphite and trimethyl phosphate as electrolyte additives in lithium ion batteries" 144 : 170-175, 2005

19 S. S. Zhang, "A review on electrolyte additives for lithium-ion batteries" 162 : 1379-1394, 2006

20 Q. Wang, "4-isopropyl phenyl diphenyl phosphate as flame-retardant additive for lithium-ion battery electrolyte" 8 : A467-A470, 2005