Synthesis of Porous Particles by Electrospray-Assisted Self-Assembly for Water-Repellent or Photocatalytic Surfaces

다국어 초록 (Multilingual Abstract)

In this study, an electrospray technique was used for the synthesis of macroporous ceramic particles, such as silica or titania, by a colloidal templating method. For this purpose, a suspension of polystyrene nanospheres was synthesized by dispersion polymerization for use as sacrificial templates. The feed solution containing a ceramic precursor and polymeric beads was injected through a metallic nozzle under a high electric field for nebulization of aerosol droplets as micro-reactors. Under ambient air conditions, the volatile components were evaporated from the droplets, and gelation of the precursor was completed simultaneously. The resulting supra-aggregates were then collected, and calcination was performed to form porous ceramic particles by removing the polymeric templates. As a demonstrative application, the porous particles of silica were deposited as a coating film for superhydrophobic surfaces with a high water contact angle larger than 150°. Furthermore, macroporous titania particles were used as photocatalytic particles in a wastewater system with first-order reaction kinetics.

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