We report the first X‐ray single crystal structures of hypochlorite (ClO−) and hypobromite (BrO−) salts, including hydrated sodium hypochlorite, a staple of the chlorine industry and ubiquitous bleaching and disinfection agent for almost 200 y...
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https://www.riss.kr/link?id=O108042860
2021년
eng
1433-7851
1521-3773
SCI;SCIE;SCOPUS
학술저널
Angewandte Chemie international edition
24400-24405 [※수록면이 p5 이하이면, Review, Columns, Editor's Note, Abstract 등일 경우가 있습니다.]
0
상세조회0
다운로드다국어 초록 (Multilingual Abstract)
We report the first X‐ray single crystal structures of hypochlorite (ClO−) and hypobromite (BrO−) salts, including hydrated sodium hypochlorite, a staple of the chlorine industry and ubiquitous bleaching and disinfection agent for almost 200 y...
We report the first X‐ray single crystal structures of hypochlorite (ClO−) and hypobromite (BrO−) salts, including hydrated sodium hypochlorite, a staple of the chlorine industry and ubiquitous bleaching and disinfection agent for almost 200 years. The structures, supported by variable‐temperature Raman spectroscopy on individual crystals and periodic density‐functional theory (DFT) calculations, provide insight into solid‐state geometry and supramolecular chemistry of hypohalite ions.
We fill a gap in fundamental and applied chemistry by providing the first X‐ray single crystal structure characterization of hypohalite ions, including sodium hypochlorite: the active component of liquid bleach, in use as a bleaching agent and sanitizer for at least two centuries.
Enantioselective Gel Phase Synthesis of Metal–Organic Materials